Syllabus_chem_hons__150211_final New.docx

B.Sc. CHEMISTRY (Hons.) CURRICULUM (2015 batch)

SCHEME AND SYLLABUS

DEPARTMENT OF CHEMISTRY

B.Sc. CHEMISTRY (Hons.) CURRICULUM

OBJECTIVES:

The course contents have been proposed as per suggestions of the faculty members of department of Chemistry, Manipal University Jaipur. The syllabus contents are duly arranged in such a manner so that the importance is given to requisite intellectual and laboratory skills. (i) To teach the fundamental concepts of Chemistry and their applications. (ii) To make students aware of advantages of eco-friendly chemical processes and impact of chemistry on health and environment. (iii) To enthuse the students for the subject and make them capable of accepting any challenges in chemistry. (iv) To make students aware of advantages of eco-friendly chemical processes and impact of chemistry on health and environment. (v) To motivate students to do good research work in chemistry and opt for research career. (vi) To educate the students with respect to skills and knowledge to practice chemistry and imbibe the concept of sustainable developments.

ELIGIBILITY OF THE CANDIDATES: Candidates who have passed (10+2) examination of any recognized Board or its equivalent examination with minimum of 45% marks with Physics, Chemistry, Mathematics or Biology as core subjects.

2

Course Structure of the B.Sc. (Hons) Chemistry Programme (2015-2018) Major course: Chemistry; Subsidiary: Science/Bio technology; Ancillary: Physics I Semester

Sr.No.

Mathematics/Bio

Exam Duration (Hrs)

Course Code

Course Name

L

T

P

1

CY1112

Inorganic ChemistryI

2

1

0

2

CY1113

Organic chemistry –I

2

1

3

CY1114

Physical Chemistry-1

2

4

CY1132

Chemistry (Hons.) Laboratory-1

5

MA 1111

6

Relative Weightage (%)

C Theor y

Pract ical

CW S

MTE

ET E

3

3

-

10

-

40

50

0

3

3

-

10

-

40

50

1

0

3

3

-

10

-

40

50

-

0

0

2

1

0

2

-

60

-

-

40

Differential Calculus and Integral Calculus

3

1

0

4

4

-

10

-

40

50

-

BS1156

Basic Biology

2

1

0

3

3

-

10

-

40

50

-

7

BS1141

Basic Biology Lab

0

0

2

1

-

2

-

60

-

-

40

8

CS 1102

Fundamental of Computers

2

0

0

2

-

-

10

-

40

50

-

9

EN 1101

General English

2

1

0

3

3

0

10

-

40

50

-

10

CS1132

Fundamental of Computers Laboratory

0

0

2

1

-

2

-

60

-

-

40

Total

15

6

6

24

3

PRS

PRE

II Semester

Sr.No .

Course Code

1. 1 CY1212

Exam Duration (Hrs)

Course Name

L

T

Inorganic Chemistry-II

3

1

P

0

Relative Weightage (%)

C Th eor y

Pra ctic al

CW S

PR S

MT E

ETE

PR E

4

3

-

10

-

40

50

-

2.

2CY1213

Organic Chemistry-II

3

1

0

4

3

-

10

-

40

50

-

3.

3CY1214

Physical Chemistry-II

3

1

0

4

3

-

10

-

40

50

-

4.

CY1231

Chemistry (Hons.) Laboratory-II

0

0

2

1

2

-

60

-

-

40

5.

MA 1211

Algebra

3

1

6.

6VE1201

Value Education

2

0

7.

7CY1120

Environmental Science

2

8.

PY 1211

Oscillations and wave Optics

9.

8PY 1231

4

3

-

10

-

40

50

-

0

2

3

-

10

-

40

50

-

1

0

3

3

-

10

-

40

50

-

2

1

0

3

3

-

10

-

40

50

-

Optics Lab

0

0

2

1

-

3

-

60

-

-

40

Total

18

6

4

26

4

0

III Semester

Exam Duration (Hrs)

Sr. No.

Course Code

Course Name

L

T

P

1

CY 1313

Inorganic ChemistryIII

3

1

0

2

CY 1315

Organic ChemistryIII

3

1

3

CY 1316

Physical Chemistry

3

4

CY1331

Chemistry (Hons.) laboratoryIII

5

CY 1332

8 7

C

Relative Weightage (%)

T he or y

Practica l

CW S

PR S

MT E

ET E

PR E

4

3

-

10

-

40

50

-

0

4

3

-

10

-

40

50

-

1

0

4

3

40

50

0

0

4

2

-

Computer application in Chemistry

0

0

4

2

MA 1311

Differential Equations

3

1

0

4

MA 1312

Solid Geometry and Vector Calculus

3

1

0

4

Total

15

5

8

24

5

10 2

-

60

-

-

40

2

-

60

-

-

40

3

-

10

-

40

50

-

3

1

10

-

40

50

-

IV Semester

Sr.No.

Exam Duration (Hrs)

Course Code

Course Name

1

CY 1413

Inorganic Chemistry -IV

2

CY 1414

Organic Chemistry-IV

3

CY 1415

4

L

3

T P

Relative Weightag e (%)

C Theo ry

Practic al

CW S

PR S

MT E

ET E

PR E

1 0

4

3

-

10

-

40

50

-

3

1 0

4

3

-

10

-

40

50

-

Physical Chemistry

3

1 0

4

3

-

10

-

40

50

-

CY 1431

Chemistry (Hons.) Laboratory-IV

0

0 4

2

0

2

-

60

-

-

40

5

MA 1411

Linear Programming Problems and its application

3

1 0

4

3

-

10

-

40

50

-

5

MA1412

Dynamics

3

1 0

4

3

-

10

-

40

50

-

6

*****

Open Elective

3

0 0

3

3

-

10

-

40

50

-

Total

18

5 4

25

6

V Semester

Sr.N o.

Course Code

Exam Duration (Hrs)

Course Name

L

T

P

1 CY 1513

Chemistry of Biomolecul es

3

1

0

2 CY 1514

Quantum Chemistry and its Application to Molecular Spectroscop y

3

1

3 CY 1515

Green Chemistry

2

4 CY 1516

Nuclear and Analytical Chemistry

5 CY 1531

Relative Weightage (%)

C Theor y

Practica l

CW S

PR S

4

3

-

10

-

40

50

-

0

4

3

-

10

-

40

50

-

1

0

3

3

-

10

-

40

50

-

2

1

0

3

3

-

10

-

40

50

-

Chemistry (Hons.) LaboratoryV

0

0

4

2

-

2

-

60

-

40

6 CY1570

Seminar

0

0

4

2

-

-

-

60

-

-

40

5 MA 1511

Real Analysis

3

1

0

4

3

-

10

-

40

50

-

6 MA 1512

Numerical Analysis and Probability Theory

3

1

0

4

3

-

10

-

40

50

-

Total

16

6

8

26

7

MT E

ET E

PR E

VI Semester

Exam Duration (Hrs)

Sr. No.

Course Code

Course Name

L

T P

1

CY 1613

Organic 3 Spectroscopy

1 0

2

CY 1614

Molecular Statistics and photo chemistry

3

1

0

3

CY 1615

Organometallic Chemistry and Industrial Chemistry

2

1

4

CY 1631

Chemistry (Hons.)Laborat ory-VI

0

5

CY 1670

Project

6

MA 1611

7

MA 1612

Relative Weightage (%)

C Theor y

Practica l

CW S

PR S

MT E

ET E

PR E

3

-

10

-

40

50

-

4

3

-

10

-

40

50

-

0

3

3

-

10

-

40

50

-

0

6

3

-

40

0

0

6

3

-

-

-

60

-

-

40

Complex Analysis

3

1

0

4

3

-

10

-

40

50

-

Discrete Mathematics Structure

3

1

0

4

3

-

10

-

40

50

-

Total

14

5 12

25

4

2

60

L = Number of Lectures hrs/week

T= Number of Tutorials hrs/week

P = Number of practical hours/week

C= Number of Credits.

CWS: Class Work Sessionals

PRS: Practical Sessionals

MTE: Mid-Term Exam

ETE: End Term Exam

PRE: End Term Practical Exam

8

CY1112

Inorganic Chemistry-I

[3 1 0 4]

Atomic Structure: Schrodinger’s wave equation, significance of Ψ and Ψ2, four quantum numbers and their significance, radial and angular probability, shapes of s, p, d and f orbitals, fundamental properties of atoms such as atomic volume, the sizes of atoms, ionization energy, electron affinity and their periodic trends; Electronegativity and Polarity of bond: Electronegativity, different scales and methods of determination, dipole moments, percentage of ionic character form dipole moment and electronegativity difference; Valence Bond theory and Molecular Orbital Theory: Valence bond (VB) approach, molecular orbitals (MO) approach of bonding (LCAO Method) bonding in homo-nuclear and heteronuclear molecules; The Periodic Table and Chemical Periodicity: The relationship between chemical periodicity and electronic structure of the atom, the long form of the periodic table, classification of elements in s, p, d and f block of elements, diagonal behaviour between elements; Acids-bases: various definitions of acids and bases, a generalized acid-base concept, measurement of acid-base strength, Lewis interactions, Pearson’s HSAB concept. Text Books: 1. J. D. Lee, Concise Inorganic Chemistry, Blackwell Science, 2008. 2. J. E. Huheey , E. A. Keiter and R. L. Keiter, Inorganic Chemistry: Principles of Structure and Reactivity, Pearson India, 2008. 3. D. Shriver and P. Atkins, Inorganic Chemistry, Oxford University Press, 2011. Reference Books: 1. F. A. Cotton, G. Wilkinson, C. A. Murillo and M. Bochmann, Advanced Inorganic Chemistry, Wiley India, 2007. 2. C. Housecroft and A. G. Sharpe, Inorganic Chemistry, Pearson India, 2012.

CY1113

Organic Chemistry-I

[3 1 0 4]

Structure and Bonding: Hybridization, bond lengths and bond angles, bond energy, van der Waals interactions, resonance, hyperconjugation, aromaticity, inductive and field effects, hydrogen bonding; Mechanism of Organic Reactions: Curved arrow notation, drawing of electron movements with arrows, half-headed and double-headed arrows, electrophiles and nucleophiles, reactive intermediates: carbocations, carbanions, free radicals, carbenes, arynes and nitrenes, isotope effects, kinetic and stereochemical studies; Stereochemistry of Organic Compounds: Concept of isomerism, optical isomerism, molecular chirality, enantiomers, stereogenic center, relative and absolute configuration, Sequence rules, D & L and R & S systems of nomenclature, geometric isomers, E & Z system of nomenclature, Newman projection and Sawhorse formulae, Fischer 9

and flying wedge formulae; Alkanes and Cycloalkanes: IUPAC nomenclature of branched and unbranched alkanes, methods of synthesis of alkanes, physical properties and chemical reactions of alkanes, nomenclature of cycloalkanes, methods of synthesis of cycloalkanes; Baeyer’s strain theory and its limitations; Alkenes, Cycloalkenes, Dienes and Alkynes: Nomenclature, synthesis and reactions of alkenes, cycloalkenes, dienes and alkynes. Text Books: 1. R. T. Morrison, R. N. Boyd and S. K. Bhattacharjee, Organic Chemistry, Pearson India, 2011. 2. T. W. G. Solomons and C. B. Fryhle, Organic Chemistry, Wiley India, 2012. 3. P. Sykes, A Guidebook to Mechanism in Organic Chemistry, Pearson India, 2003. 4. I.L. Finer, Organic Chemistry, Volume I, Pearson India, 2002. 5. I.L. Finer, Organic Chemistry, Volume II, Pearson India, 2002. Reference Books: 1. F. A. Carey and R. J. Sundberg, Advanced Organic Chemistry: Structure And Mechanisms (Part A), Springer India Private Limited, 2007. 2. F. A. Carey and R. J. Sundberg, Advanced Organic Chemistry: Reaction And Synthesis (Part B), Springer India Private Limited, 2007. 3. M. B. Smith, J. March, March's Advanced Organic Chemistry: Reactions, Mechanisms and Structure, Wiley India, 2012.

CY1114

Physical Chemistry-I

[3 1 0 4]

Equation of State: Kinetic molecular theory of gases, derivation of kinetic gas equation, imperfection in real gases, the compressibility of real gases, isotherms of real gases, equations of state, van der Waal’s equation, liquification of gases, critical phenomenon, P-V isotherms of carbon dioxide, principle of continuity of state; .Properties of Liquids: The Kinetic molecular description, intermolecular forces in liquids, density and methods for its measurements, vapour pressure and its determination, surface tension and its determination, viscosity and measurement of viscosity; The First Law of Thermodynamics: Thermodynamic terms and basic concepts, intensive and extensive properties, state functions and differentials, thermodynamic processes, reversibility, irreversibility, various statements of first law, internal energy (U) and enthalphy (H); Thermochemistry: The reaction enthalpy, standard enthalpies, Hess’s law and reaction enthalpies, Kirchoff’s equation, relation between H and U for reactions, calorimetric measurements, varieties of enthalpy changes. Text Books: 1. P. Atkins and J. De Paula, Atkins' Physical Chemistry, Oxford University Press, 2011. 2. P. C. Rakshit, Physical Chemistry, Sarat Book Distributors, 2004. 10

3. T. Engel and P. Reid, Physical Chemistry, Pearson India, 2013. Reference Book: 1. G. W. Castellan, Physical Chemistry, Narosa Publishing House, 2004. 2. G. M. Barrow, Physical Chemistry, McGraw-Hill International, 1973. 3. R. J. Silbey, R. A. Albert and M. G. Bawendi, Physical Chemistry, Wiley India, 2006.

CY1132

Chemistry(Hons.)laboratory I

[0 0 2 1]

Determination of some physical parameters: Calibration of thermometer, determination of melting points and boiling points of some organic compounds; Distillation: Simple distillation of ethanol-water mixture, distillation of nitrobenzene and aniline; Crystallization: Crystallization of some organic and inorganic compound. Text Books: 1. A. I. Vogel, Elementary Practical Organic Chemistry: Small Scale Preparations Part 1, Pearson India, 2010. 2. A. I. Vogel, Elementary Practical Organic Chemistry: Qualitative Organic Analysis Part 2, Pearson India, 2010. 3. A. I.Vogel, Elementary Practical Organic Chemistry: Quantitative Organic Analysis Part 3, Pearson India, 2010. 4. B. Vishwanathan and P.S. Raghavan, Practical Physical Chemistry, Viva Books, 2012.

CY1212

Inorganic Chemistry-II

[3 1 0 4]

Hydrogen: Position in the periodic table, isotopes, industrial production, properties, reactions and isotopes; The s-block elements: Production and uses of alkali and alkaline earth metals, chemical reactivity, structure and properties of oxides, halides and hydroxides, coordination complexes; The p-block elements I: Chemical reactivity of B, Al, Ga, In and Tl, compounds of boron and aluminum, chemical reactivity and group trends of C, Si, Ge, Sn and Pb, allotropes of carbon, compounds of Si, Ge, Sn and Pb; Ionic bond: Factors affecting the stability of ionic compounds, lattice energy, Born Lande equation and its applications, Madelung constant, Born-Haber cycle, Fazan’s rules, ionic radii, factors affecting the radii of ions, Structure of crystal lattices, predictive power of thermochemical calculations on ionic compounds; Intermolecular forces and metallic bond: Van der Waals forces (Keesom, Debye & London Interactions). Structure of metals, valence bond and band model; Perfect and 11

imperfect crystals: Intrinsic and extrinsic defects, point defects, line and plane defects, vacancies-Schottky and Frenkel defects. Thermodynamics of Schottky and Frenkel defect, band theory, band structure of metals, nnsulators and semiconductors, intrinsic and extrinsic semiconductors, doping semiconductors, p-n junctions, High temperature super conductors. Text Books: 1. J. D. Lee, Concise Inorganic Chemistry, Blackwell Science, 2008. 2. J. E. Huheey , E. A. Keiter and R. L. Keiter, Inorganic Chemistry: Principles of Structure and Reactivity, Pearson India, 2008. 3. D. Shriver and P. Atkins, Inorganic Chemistry, Oxford University Press, 2011. 4. N. N. Greenwood and A. Earnshaw, Chemistry of the Elements, Elsevier, 2010. Reference Books: 1. F. A. Cotton, G. Wilkinson, C. A. Murillo and M. Bochmann, Advanced Inorganic Chemistry, Wiley India, 2007 2. C. Housecroft and A, G. Sharpe, Inorganic Chemistry, Pearson India, 2012.

CY1213

Organic Chemistry-II

[3 1 0 4]

Arenes and Aromaticity: Nomenclature of benzene and derivatives, Kekule structure, carbon-carbon bond lengths of benzene, resonance structure, MO picture, Aromatic electrophilic substitution, activating and deactivating substituents, orientation and ortho/para ratio; Alkyl and Aryl Halides:Nomenclature and classes of alkyl halides, methods of formation, chemical reactions and mechanisms; Alcohols: Classification and nomenclature of monohydric, dihydric and trihydric alcohols, methods of formation and reactions of alcohols; Phenols: Nomenclature, structure and bonding of phenols, synthesis and reactions of phenols, physical properties and acidic character; Ethers and Epoxides: Nomenclature of ethers and methods of their preparation, physical properties, chemical reactions, cleavage and autoxidation, synthesis of epoxides, acid and base catalyzed ring opening of epoxides. Text Books: 1. R. T. Morrison, R. N. Boyd and S. K. Bhattacharjee, Organic Chemistry, Pearson India, 2011. 2. T. W. G. Solomons and C. B. Fryhle, Organic Chemistry, Wiley India, 2012. 3. P. Sykes, A Guidebook to Mechanism in Organic Chemistry, Pearson India, 2003. 4. I.L. Finer, Organic Chemistry, Volume I, Pearson India, 2002. 12

5. I.L. Finer, Organic Chemistry, Volume II, Pearson India, 2002. Reference Books: 1. F. A. Carey and R. J. Sundberg, Advanced Organic Chemistry: Structure And Mechanisms (Part A), Springer India Private Limited, 2007. 2. F. A. Carey and R. J. Sundberg, Advanced Organic Chemistry: Reaction And Synthesis (Part B), Springer India Private Limited, 2007. 3. M. B. Smith, J. March, March's Advanced Organic Chemistry: Reactions, Mechanisms and Structure, Wiley India, 2012.

CY1214

Physical Chemistry-II

[3 1 0 4]

Partial Molar Properties and Fugacity: Partial molar properties, chemical potential of a perfect gas, dependence of chemical potential on temperature and pressure, Gibbs-Duhem equation, real gases, fugacity, Clausius Clapeyron equation and its application to solid-liquid, liquid-vapour and solid-vapour equilibria; Thermodynamics of Simple Mixtures: Thermodynamic functions for mixing of perfect gases, chemical potential of liquids. Raoult’s law, Henry’s law; Physical Transformation of Pure Materials: First and second order phase transitions, attainment of low temperature and energetics of refrigeration, adiabatic demagnetization; Phase Equilibria: Phase rule and its thermodynamic derivation, one component systems, two component systems, eutectics, freezing mixtures, ultra purity, zone refining; Chemical Equilibrium: Direction of spontaneous change in a chemical reaction, extent of reaction, stoichiometric coefficients, equilibrium constant in terms of G. temperature and pressure dependence of equilibrium constant, homogeneous and heterogeneous equilibria; Thermodynamics of Electrolytic Solutions: Activities of ions in solutions, model of ions in a solution, qualitative idea of Debye-Huckel theory, ionic strength, mean ionic activity coefficient and the Debye-Huckel limiting law for activity coefficients; Colligative Properties: Solutions of non-volatile solutes, colligative properties, elevation in boiling point, depression in freezing point, osmosis and osmotic pressure; Electrochemical Cells: Interfacial potential difference, the electrodes, potential at interfaces, electrode potentials, galvanic cells, emf, direction of spontaneous reactions, measurements of solubility product, potentiometric titrations, pK and pH measurements. Text Books: 1. P. Atkins and J. De Paula, Atkins' Physical Chemistry, Oxford University Press, 2011. 2. P. C. Rakshit, Physical Chemistry, Sarat Book Distributors, 2004. 3. T. Engel and P. Reid, Physical Chemistry, Pearson India, 2013. Reference Book: 1. G. W. Castellan, Physical Chemistry, Narosa Publishing House, 2004. 2. G. M. Barrow, Physical Chemistry, McGraw-Hill International, 1973. 3. R. J. Silbey, R. A. Albert and M. G. Bawendi, Physical Chemistry, Wiley India, 2006. 13

CY1231

Chemistry (Hons.) Laboratory-II

[0 0 2 1]

Inorganic qualitative Analysis: Qualitative analysis of inorganic mixtures containing not more than six radicals including interfering radicals like phosphate, oxalate, tartrate; Inorganic quantitative Analysis: various volumetric analyses. Text Books: 1. G. Svehla and B. Sivasankar, Vogel's Qualitative Inorganic Analysis, Pearson India, 2012. 2. J. Mendham, R.C. Denney, M.J.K Thomas and D. J. Barne, Vogel's Quantitative Chemical Analysis, Pearson India, 2009.

CY1313

Inorganic Chemistry-III

[3104]

The p-Block Elements-II: Chemical reactivity and group trends of N, P, As, Sb & Bi, compounds of of N, P, As, Sb & Bi, some organometallic compounds; Oxygen, S, Se and Te Family: Chemical Reactivity, group trends and stereochemistry, dioxygen as a ligand , structure of O3 and H2O2, clathrate hydrates allotropic forms of S & Se, structures of halides, oxides and oxyacids of S, Se & Te, liquid SO2 and polyatomic cations of S, Se & Te; The Halogen Family: Chemical reactivity, group trends, chemistry of preparation of fluorine, hydrogen halides, HF as a solvent, inter-halogen compounds, polyhalide and polyhalonium ions, polyatomic cations of halogens, oxides and oxyacide of halogens; Noble gases: Chemical reactivity and group trends, Clathrate compounds; preparation, structure and bonding of noble gas compounds; Symmetry and group theory (Part I): Symmetry elements and symmetry operations, point groups, definitions of group, subgroup relation between orders of a finite group and its subgroup, group multiplication tables, conjugacy relation and classes; Schoenflies symbols, representation of groups, character of a representation; Symmetry and group theory (Part II): Properties of irreducible representations, the great orthogonality theorem and its importance. Character Tables, Symmetry criteria for optical activity, symmetry restrictions on dipole moment, and hybridization schemes of orbitals. Text Books: 1. J. D. Lee, Concise Inorganic Chemistry, Blackwell Science, 2008. 2. J. E. Huheey , E. A. Keiter and R. L. Keiter, Inorganic Chemistry: Principles of Structure and Reactivity, Pearson India, 2008 3. D. Shriver and P. Atkins, Inorganic Chemistry, Oxford University Press, 2011. 4. N. N. Greenwood and A. Earnshaw, Chemistry of the Elements, Elsevier, 2010. 14

Reference Books: 1. F. A. Cotton, G. Wilkinson, C. A. Murillo and M. Bochmann, Advanced Inorganic Chemistry, Wiley India, 2007 2. C. Housecroft and A, G. Sharpe, Inorganic Chemistry, Pearson, 2012. 3. F. A. Cotton, Chemical Applications of Group Theory, Wiley India, 2010.

CY1315

Organic Chemistry-III

[3 1 0 4]

Stereochemical principles, conformation, steric and stereoelectronic effects: Enantiomeric relationships, diastereomeric relationships, dynamic stereochemistry, prochiral relationships, conformations of acyclic molecules, cyclohexane derivatives, rings other than six membered, conformational effects on reactivity; Free radical reactions: Generation and characterization of free radicals, characteristics of reaction mechanisms involving electron transfer reactions; Carbanions and other nucleophilic carbon species and their reactions: Acidity of hydrocarbons, carbanions stability by functional groups, Generation of carbon nucleophiles by deprotonations, reactions involving carbanions; Aldehydes and Ketones: Nomenclature and structure of the carbonyl group; Synthesis of aldehydes and ketones, physical properties, of aldehydes and ketones reactions of aldehydes and ketones with mechanism, introduction to ∞, β -unsaturated aldehydes and ketones; Carboxylic Acids: Nomenclature, structure and bonding, physical properties, acidity of carboxylic acids, effects of substituents on acid strength. Preparation of carboxylic acids. Reactions of carboxylic acids; Carboxylic Acid Derivatives: Structure and nomenclature of acid chlorides, esters, amides (urea) and acid anhydrides, relative stability of acyl derivatives. Text Books: 1. R. T. Morrison, R. N. Boyd and S. K. Bhattacharjee, Organic Chemistry, Pearson India, 2011. 2. T. W. G. Solomons and C. B. Fryhle, Organic Chemistry, Wiley India, 2012. 3. P. Sykes, A Guidebook to Mechanism in Organic Chemistry, Pearson India, 2003. 4. I.L. Finer, Organic Chemistry, Volume I, Pearson India, 2002. 5. I.L. Finer, Organic Chemistry, Volume II, Pearson India, 2002. Reference Books: 1. F. A. Carey and R. J. Sundberg, Advanced Organic Chemistry: Structure And Mechanisms (Part A), Springer India Private Limited, 2007. 2. F. A. Carey and R. J. Sundberg, Advanced Organic Chemistry: Reaction And Synthesis (Part B), Springer India Private Limited, 2007.

15

3. M. B. Smith, J. March, March's Advanced Organic Chemistry: Reactions, Mechanisms and Structure, Wiley, 2012.

CY 1316

Physical Chemistry-III

[3 1 0 4]

Kinetic theory of gases and transport properties: Kinetic molecular theory of gases, kinetic energy and temperature, distribution of molecular speeds in an ideal gas, distribution in one dimension, distribution of speeds in three dimensions, derivation of Maxwell-Boltzmann distribution law, thermal conductivity, kinetic theory of thermal conductivity in gases; Thermodynamics of diffusion: Thermodynamic view of diffusion, relation between transport properties, Einstein relation, Nernst-Einstein relation, Stoke’s Einstein relation; Equilibrium Electrochemistry: Transport of ions in solution, conductivity, Kohlrausch’s law, Ostwald dilution law, mobilities of ions, transport number and its measurement, arrhenius theory of Conductivity, Debye-Huckel-Onsager theory of conductivity; Dynamic Electrochemistry: Processes at electrodes, double layer at the interface, non-equilibrium electrode potentials, over potential, derivation of Butler-Volmer equation, Tafel plot, applications of dynamic electrochemistry; Chemical Kinetics: Rate of reaction, rate constant and rate laws, the order of reaction, first, second and third and zero order reactions, half-lives; determination of reaction order, temperature dependence of reaction rates, reaction mechanism, rate-determining step approximation, steady-state approximation, explosive/branched chain reactions, catalysis, homogeneous catalysis, autocatalysis, oscillation reactions, bistability, enzyme catalysis, heterogeneous catalysis. Text Books: 1. P. Atkins and J. De Paula, Atkins' Physical Chemistry, Oxford University Press, 2011. 2. P. C. Rakshit, Physical Chemistry, Sarat Book Distributors, 2004. 3. T. Engel and P. Reid, Physical Chemistry, Pearson India, 2013. Reference Book: 1. G. W. Castellan, Physical Chemistry, Narosa Publishing House, 2004. 2. G. M. Barrow, Physical Chemistry, McGraw-Hill International, 1973. 3. R. J. Silbey, R. A. Albert and M. G. Bawendi, Physical Chemistry, Wiley India, 2006.

CY1331

Chemistry (Hons.) Laboratory-III

[0 0 2 1]

Treatment of Experimental Data: Accuracy, precision and error analysis; Liquids and Solutions: Determination of viscosity of different solvents and solutions; Thermochemistry: Determination of heat of reaction of various processes; Distribution Law: Determination of partition coefficient of a solute in 16

water and a non aqueous solvent; Surface Phenomena: Adsorption of some organic acids on charcoal; Colorimetery: Verification of Lambert-Beer law; Thin Layer and Column Chromatography: Determination of Rf value and purity of organic compounds by use of thin layer chromatography, separation of organic compound by column chromatography; Qualitative organic analysis: Text Books: 1. G. Svehla and B. Sivasankar, Vogel's Qualitative Inorganic Analysis, Pearson India, 2012 2. J. Mendham, R.C. Denney, M.J.K Thomas and D. J. Barne, Vogel's Quantitative Chemical Analysis, Pearson India, 2009. 3. A. I. Vogel, Elementary Practical Organic Chemistry: Small Scale Preparations Part 1, Pearson India, 2010. 4. B. Vishwanathan and P.S. Raghavan, Practical Physical Chemistry, Viva Books, 2012. 5. F. Alexander, Practical Physical Chemistry, Hardpress Publishing, 2013. 6. A. I.Vogel, Elementary Practical Organic Chemistry: Quantitative Organic Analysis Part 3, Pearson India, 2010.

CY1332

Computer Application in Chemistry

[3 1 0 4]

Computer programming: Constants, variables, bits, bytes, binary and ASCII formats, arithmetic expressions, hierarchy of operations, inbuilt functions, elements of the BASIC language, BASIC keywords and commands, logical and relative operators, strings and graphics, Compiled versus interpreted languages. Debugging. Simple programs using these concepts. conceptual background of molecular modelling, potential energy surfaces, elementary ideas of molecular mechanics and practical MO methods; Use of computational tools to plot and analyze data. Text Book: 1. T. Engel and P. Reid, Physical Chemistry, Chapter on Computational Chemistry. Pearson India, 2013. Reference Books: 1. S. M. Venit, Programming in Basic: Problem solving with structure and style. Jaico Publishing House, 1996. 2. J. H. Noggle, Physical chemistry on a Microcomputer, Little Brown & Co. 1985.

17

CY1413

Inorganic Chemistry-IV

[3 1 0 4]

Chemistry of 2nd and 3rd row d-block elements: Comparison of the chemistry of elements of second and third row series with that of elements of the first transition series. Mo-Mo and Re-Re quadrupole bonds. Chemistry of complexes of Rh(III), Pt(II) and Pd(II); Chemistry of f-block elements: Chemistry of Lanthanide elements, their isolation from one another, their coordination chemistry; Coordination Compounds: Various definitions, types of ligands, The Chelate and Macrocylic effects, Multidentate ligands, isomerism in coordination compounds, nomenclature, stability of coordination compounds, stability constants and chelate effect; Theories for bonding in complexes: Valence bond theory for bonding in coordination compounds. Concept of multiple bonding and back bonding; Crystal field theory: The splitting of d-orbitals in different fields, Consequences, factors affecting and applications of orbital splitting, crystal field stabilization energy (CFSE), magnetic properties, spectrochemical series and colour of transition metal complexes. Jahn-Teller effect in octahedral and tetrahedral complexes. Evidence of covalence and adjusted crystal field theory. Molecular orbital treatment of octahedral, tetrahedral and square planar complexes. Text Books: 1. J. D. Lee, Concise Inorganic Chemistry, Blackwell Science, 2008. 2. J. E. Huheey , E. A. Keiter and R. L. Keiter, Inorganic Chemistry: Principles of Structure and Reactivity, Pearson India, 2008 3. D. Shriver and P. Atkins, Inorganic Chemistry, Oxford University Press, 2011. 4. N. N. Greenwood and A. Earnshaw, Chemistry of the Elements, Elsevier, 2010. Reference Books: 1. F. A. Cotton, G. Wilkinson, C. A. Murillo and M. Bochmann, Advanced Inorganic Chemistry, Wiley India, 2007 2. C. Housecroft and A, G. Sharpe, Inorganic Chemistry, Pearson, 2012.

CY1414

Organic Chemistry-IV

[3 1 0 4]

Organic Compounds of Nitrogen: Preparation, Chemical reactions and Mechanisms of nucleophilic substitution of nitroalkanes and nitroarenes in difffrent media, Picric acid, Halonitroarenes, Stereochemistry of amines, Separation of a mixture of primary, secondary and tertiary amines, Gabriclphthalimide reaction, Hoffmann bromamide reaction; Organosulphur Compounds: Nomenclature, structural features, methods of formation and chemical reactions of thiols, thioethers, sulphonic acids, sulphonamides and sulphaguanidine; Heterocyclic Compounds: Introduction (pyrrole, furan, 18

thiophene and pyridine), Mechanism of electrophilic and nucleophilic substitution reactions, Comparison of basicity, five and six-membered heterocycles. Preparation and reactions of indole, quinoline and isoquinoline with special reference to Fischer indole synthesis, Skraup synthesis and Bischler-Napieralski synthesis. Mechanism of electrophilic substitution reactions of indole, quinoline and isoquinoline; Fats, Oils and Detergents: Natural fats, edible and industrial oils of vegetable origin, common fatty acids, glycerides, hydrogenation of unsaturated oils. Saponification value, iodine value, acid value. Soaps, synthetic detergents; Synthetic Dyes: Colour and constitution (electronic concept), Classification of dyes. Chemistry and synthesis of Methyl orange, Congo red, Malachite green, Crystal violet, Phenolphthalein, Fluorescein, Alizarin and Indigo. Text Books: 1. R. T. Morrison, R. N. Boyd and S. K. Bhattacharjee, Organic Chemistry, Pearson India, 2011. 2. T. W. G. Solomons and C. B. Fryhle, Organic Chemistry, Wiley India, 2012. 3. P. Sykes, A Guidebook to Mechanism in Organic Chemistry, Pearson India, 2003. 4. I.L. Finer, Organic Chemistry, Volume I, Pearson India, 2002. 5. I.L. Finer, Organic Chemistry, Volume II, Pearson India, 2002. Reference Books: 1. F. A. Carey and R. J. Sundberg, Advanced Organic Chemistry: Structure and Mechanisms (Part A), Springer India Private Limited, 2007. 2. F. A. Carey and R. J. Sundberg, Advanced Organic Chemistry: Reaction and Synthesis (Part B), Springer India Private Limited, 2007. 3. M. B. Smith, J. March, March's Advanced Organic Chemistry: Reactions, Mechanisms and Structure, Wiley, 2012.

CY1415

Physical Chemistry- IV

[3 1 0 4]

Surface Chemistry: Bulk phases and interfacial region, types of interfaces; Surface tension and interfacial tension, Surface tension of solutions, Gibbs adsorption equation and its thermodynamic derivation, Surfactants, Surface films on liquids; X-ray diffraction: Definition of space lattice, unit cell. Miller indices, Symmetry elements in crystals. X-ray diffraction by crystals. Bragg equation. Dimension and contents of unit cell; Adsorption: Adsorption of gases on solids, chemisorption and physi-sorption, desorptoin. Adsorption isotherms; Colloids: The colloidal state, preparation of colloidal dispersions, dialysis, ultrafiltration, physical & optical properties, ultra-microscope, Electro kinetic phenomena. Zeta potential. Precipitation of sols by electrolytes, Hardy Schulz rules, other methods of precipitation. Emulsions, Association colloids/colloidal surfactants/micelle systems; Macromolecules: Introduction, nomenclature and classifications of 19

macromolecules, Addition and condensation polymerization, Molecular weight heterogeneity, number average and weight average molecular weights, Determination of molecular weights. Text Books: 1. P. Atkins and J. De Paula, Atkins' Physical Chemistry, Oxford University Press, 2011. 2. P. C. Rakshit, Physical Chemistry, Sarat Book Distributors, 2004. 3. T. Engel and P. Reid, Physical Chemistry, Pearson India, 2013. Reference Book: 1. G. W. Castellan, Physical Chemistry, Narosa Publishing House, 2004. 2. G. M. Barrow, Physical Chemistry, McGraw-Hill International, 1973. 3. R. J. Silbey, R. A. Albert and M. G. Bawendi, Physical Chemistry, Wiley India, 2006.

CY1431

Chemistry (Hons.) Laboratory-IV

[0 0 2 2]

Physical Chemistry: Treatment of experimental data: Recording of experimental data. Significant number, accuracy and precision, error analysis; Liquids and Solutions: (i) To determine surface tensions of solutions of amyl alcohol in water at different concentrations and to calculate surface excess, (ii) To determine refractive index and molar refractivity of some organic liquids; Thermichemistry: (i) To determine heat of neutralization of a strong acid by a strong base. (ii) To determine heat of ionization of a weak acid from heat of neutralization; Distribution Law: (i) To determine the equilibrium constant of the reaction I2+KI =KI3 by the partition method and the corresponding free energy change, (ii) To determine distribution coefficient between water and a non-aqueous solvent of a solute which associates or dissociates in one of the solvents; Colorimetery: (i) To determine the composition of a complex by Job’s method of continuous variations (Ferric-salicylate Complex), (ii) To titrate copper with EDTA photometrically. Inorganic Chemistry: (i) Gravemetric Methods, Estimation of Ba2+ as BaSO4 and Ni2+ as Nickel dimethylglyoxime Complex and Co2+ gravimetrically. Determination of two metal ions, Cu-Ni and Cu-Fe. (ii) Preparation of anhydrous stannous chloride, (iii) Complexometric titrations involving EDTA for quantitative determination of individual cation/mixture of cations, (iii) Chromatography: Separation of cations and anions by Paper Chromatography Text Books: 1. B.P. Levitt, Findlays Practical Physical Chemistry, Longman Group Ltd. 2003. 20

2. B.D. Khosla, V.C. Garg and A. Gulati, Senior Practical Physical Chemistry, R. Chand & Co. 2005. 3. G. Svehla and B. Sivasankar, Vogel's Qualitative Inorganic Analysis, Pearson India, 2012. 4. R.C. Das and R.C. Behera, Experimental Physical Chemistry, Tata McGraw Hill Publishing Co. Ltd. 2001.

CY1513

Chemistry of Biomolecules

[3 1 0 4]

Carbohydrates: Classification and nomenclature, Monosaccharides, mechanism of ozone formation, interconversion of glucose and fructose, Configuration of monosaccharides, Conversion of glucose into mannose. Formation of glycosides, ethers and esters, Cyclic structure of D(+)-glucose, mutarotation, Structures of ribose and deoxyribose. An introduction to disaccharides and polysaccharides; Amino Acids, Peptides, Proteins Nucleic Acids, Lipids, Terpines and Terpeniods: Classification, structure and stereochemistry of amino acids. Acidbase behavior, isoelectric point and electrophoresis. Preparation and reactions of α-amino acids. Structure and nomenclature of peptides and proteins. Classification of proteins, Classical peptide synthesis, solidphase peptide synthesis, Structures of peptides and proteins. Protein denaturation, Nucleic acids. Text Books: 1. D.L. Nelson, M.M. Cox, Lehninger’s Principles of Biochemistry, W. H. Freeman, 2011. 2. J.M. Berg, J.L. Tymoczko, and L. Stryer, Biochemistry, W. H. Freeman, 2009.

CY1514

Quantum Chemistry and its Application to Molecular Spectroscopy

[3 1 0 4]

Elementary Quantum Chemistry: Historical background, classical ideas of energy and particle trajectory. Blackbody radiation and Planck’s hypothesis of quantization of energy, photoelectric effect, De Broglie’s relation Heisenberg’s uncertainty principle, Schrödinger-wave equation, concept of wave function (ψ) physical significance of ψ and ψ2, normalization, Free particle, particle in a one dimensional box, translational energy, energy levels, quantization of energy, wave functions for particle in a box, in a three dimensional box, Operators, Postulates of quantum mechanics, time dependent Schrödinger equation, expectation values, and applications of particle in a box model, Vibrational motion, classical onedimensional harmonic oscillator. Quantum mechanical harmonic oscillator, rotational motion, spherical harmonics, applications to diatomic molecule (rigid rotator). Schrödinger equation for hydrogen-like atoms, elementary discussion of 21

its solution, wave functions for hydrogen atom, electron spin, concept of spin orbitals, spectral selection rules for one-electron atoms, spectrum of hydrogen atom; Molecular spectroscopy: Electromagnetic radiation, absorption coefficient, Einstein coefficient, transition moment and oscillator strength and Lasers. Microwave absorption, rotational Spectra, rotational Raman Spectra, infrared absorption, Vibrational spectra of diatomic molecules; UV-Visible and Nuclear Spectroscopy: Visible-Ultraviolet Absorption, Electronic spectra: Electronic energy levels of molecules, selection rules for electronic spectra of molecules, Frank-Condon principle, Beer-Lambert Law, electronic spectra of polyatomic molecules, Photoelectron spectroscopy. Text Books: 1. I.N. Levine, Quantum Chemistry, Oxford University Press , 2000. 2. P. Atkins and J. De Paula, Atkins' Physical Chemistry, Oxford University Press, 2011. 3. I.N. Levine, Physical Chemistry, McGraw Hill Education (India) Private Limited, 2011. 4. D.C. McQuarre, Physical Chemistry, University Science Books, 2005. 5. A.K. Chandra, Introductory Quantum Chemistry, McGrew Hill Education (Indial) Pvt. Ltd. 2009. 6. C.N. Banwell and E. M. McCash, Fundamentals of Molecular Spectroscopy, , McGrew Hill Education (Indial) Pvt. Ltd. 2013.

CY1515

Green Chemistry

[2 1 0 3]

Principles of Green chemistry-I: (i) Prevention of waste/byproducts. (ii) Maximum incorporation of materials used in process in to the final product (Atom economy): Green metrics (iii) Prevention/Minimization of hazardous/toxic products (iv) Designing safer chemicals-different basic approaches (v) selection of appropriate auxiliary substances (solvents, separation agents etc). (vi) Energy requirements for reactions-use of microwave, ultrasonic energy; Principles of Green chemistry-II: (vii) Selection of stating materials-use of renewable

starting materials. (vii) Avoidance of unnecessary derivation-careful use of blocking/protection groups (ix) use of catalytic reagents (wherever possible) in preference to stoichiometric reagents (x) Designing biodegradable products (xi) prevention of chemical accidents. (xii) Strengthening/development of analytical techniques to prevent and minimize the generation of hazardous substances in chemical processes. Development of accurate and reliable sensor and monitors for real time in process monitoring. Example of Green synthesis/reaction, The chemistry behind Green Chemistry, Future trend in green chemistry, biomimetic, multifunctional reagents, combinatorial green chemistry, biomass conversion, emission control, biocatalysts. 22

Text Books: 1. F. A. Carey and R. J. Sundberg, Advanced Organic Chemistry: Reaction and Synthesis (Part B), Springer India Private Limited, 2007. 2. M. B. Smith, J. March, March's Advanced Organic Chemistry: Reactions, Mechanisms and Structure, Wiley, 2012. 3. V.K. Ahluwalia, Green Chemistry: Greener Alternatives to Synthetic Organic Transformations, Narosa Publishing House, 2011.

CY1516

Nuclear & Analytical Chemistry

[2 1 0 3]

Nuclear Chemistry: Introduction to Atomic Nucleus, Radioactive Decay; α, β and γ, Nuclear Stability, Liquid drop Model and Shell model, Nuclear Reactions, Nuclear Fission and Fusion; Elementary Concepts of Analytical Chemistry: Qualitative and quantitative analysis, concepts important to quantitative analysis classification of methods for quantitative analysis, choice of method for analysis, sampling and theories of sampling, Preparation of samples for analysis, calibration standards, solution concentration in terms of various conventions, simple equilibrium calculations; Volumetric and Gravimetric Methods of Analysis: Theory of volumetric and gravimetric methods of analysis, equivalent points, standard solutions, Primary and Secondary standards, end point detection, optimum conditions for precipitation, washing and filtration of precipitates, Determination of inorganic salts in mixtures, Introduction to DSC, TGA, DTA; Acid-Base Equilibria: Preparation of standard solutions of acids and bases, mono and poly functional acids and bases and their pH titration curves, typical applications of neutralization titrations in elemental analysis; Precipitation Equilibria: Solubility of precipitates, effect of competing equilibria on solubility of precipitates, separation of ions by control of concentration of precipitating reagents, effect of electrolyte concentration on solubility, solubility product; Complexation Equlibria: Complexation, Formation constants, EDTA equilibria, Use of indicators, Applications of complexometric equilibria; Principles of automation: Instrumental parameters for automation; Atomic X-ray spectrometry: Fundamentals. Brief description of instrumentation. X-ray fluorescence methods and applications. Quantitative X-ray florescence analysis. Coating and film thickness measurements. Electron probe microanalysis. X-ray absorption spectrometry; Solvent Extraction and Ion-Exchange Separation: Basic principles of solvent extraction, solvent extraction of metals, extraction process, separation efficiency of metal chelates, ion-exchange processes, ionexchange resins, techniques and applications of ion-exchange separation; Atomic Spectrometric Methods: Emission spectroscopy, Flame emission spectrometry Plasma emission spectrometry, Distribution between ground and excited states, Atomic absorption spectrophotometry. Text Books: 1. H. J. Arnikar, Essentials of Nuclear Chemistry, Wiley-Blackwell, 1987. 23

2. G. Friedlander, J.W. Kennedy, E.S. Macias and J.M. Miller, Nuclear and Radiochemistry, Wiley India, 1981. 3. G.D. Christian, Analytical Chemistry, John Wiley 2004. 4. D.A. Skoog, D.M. West, F.J. Holler, S.R. Crouch, Fundamentals of Analytical chemistry, Brooks/Cole, 2004. 5. D.A. Skoog., Principles of Instrumental Analysis, Holt-Saunders International edition 2004.

CY1531

Chemistry (Hons.) Laboratory-V

[0 0 2 2]

Physical chemistry practical Conductometry: (i) To study the effect of concentration of electrolyte on specific and molar conductance of a strong and weak electrolyte, (ii) Determination of degree of dissociation and dissociation constant of weak acid, (iii) Conductometeric titration of a strong acid, a weak acid, mixture of a strong and weak acid and a dibasic acid with alkali, (iv) To compare the relative strengths of weak acids like acetic acid and monochloroacetic acid by conductivity measurements; Potentiometry: (i) Potentiometric titration of monobasic acids (HCl & CH3COOH) with NaOH, (ii) Determination of mean ionic activity coefficient of hydrochloric acid at different concentrations, (iii) To study the effect of ionic strength on mean ionic activity coefficient of hydrochloric acid in a given solution and verify Debye-Huckel limiting law; Polarimetry: (i) To determine the specific and molecular rotations of an optically active substance, (ii) To determine the composition of an unknown solution with a polarimeter, (iii) Chemical Kinetics: (i) To study the kinetics of hydrolysis of methyl acetate in the presence of hydrochloric acid, (ii) To study the effect of ionic strength (primary salt effect) on the kinetics of a reduction of toluidine blue with sodium sulfite; (iii) Determination of Molecular Masses by Cryoscopy: (i) To determine the molecular weight of a non-volatile substances by a cryoscopic method; (ii) pH-metry: (i) To titrate a strong acid against a strong base pHmetrically, (ii) To titrate a weak acid against a strong base and determine the ionization constant of the weak acid. Inorganic Chemistry Practicals (i) Preparation and characterization of K3[Cr(C2O4)3] 3H2O and NH4[Cr(NH2)2 (NCS)4]. H2O and their charactersation by conductivity, (ii) Strong acid-strong base titration in a non-acqueous solvent using visual, conductometric/potentiometric methods, (iii) Study of reactions of the elements of first transition series: (a) Titanium, (b) Vanadium, (c) Chromium, (d) Manganese, (iv) Synthesis and characterization of any suitable inorganic/organometallic compounds involving the use of techniques available in the department, (v) Ion exchange separation of oxidation states of vanadium.

24

Organic Chemistry Practicals Multistep preparations and estimations: (i) Preparation of p-bromoaniline from acetanilide (protection, aromatic electrophilic substitution and deprotection), (ii) Preparation of anthranilic acid from phthalic anhydride (nucleophilic addition of Hoffman degradation), (iii) Preparation of o-chlorobenzoic acid from anthranilic acid (diazotization and Sandmeyer reaction), (iv) Preparation of benzopinacol from benzophenone (photoreduction), (v) Preparation of benzopinacolone from benzopinacol (pinacol – pinacolone rearrangement), (vi) Preparation of triphenyl methane from benzopinacolone (nucleophilic cleavage of C-C bond), (vii) Preparation of triphenylmethyl bromide from triphenyl methane (free radical bromination by use of NBS), (viii) Preparation of 1,5-Diphenyl-1,4-pentadiene-3one from benzaldehyde and acetone (cross aldol condensation), (ix) Preparation of E/Z-a-phenylcinnamic acid from benzaldehyde and phenylacetic acid (Perkin reaction), (x) Preparation of 1,3,5-tribromobenzene from aniline (diazotization, aromatic electrophilic substitution and deamination), (xi) Preparation of 2,5dihydroxy acetophenone from hydroquinone (Fries reaction), (xii) Preparation of 3,5-diethoxycarbonyl-2,4-dimethylpyrrole from ethylacetoacetate (Knorr synthesis), (xiii) To estimate the strength of given glucose solution (Fehling method), (xiv) To estimate acid value, iodine value and soaponification value of a given oil, (xv) To estimate percentage of sulphur in given organic compound by Messenger’s method. Text Books: 1. D. J. Woollins, Inorganic Experiments, Wiley-VCH, 2003 2. J. Bassett, R.C Denney, G.H Jeffery, J. Mendham, Vogel’s Textbook of Quantitative Inorganic Analysis (revised), Orient Longman,2003. 3. R. J. Angelici, Synthesis and techniques in inorganic chemistry, SGS series London, 1999. 4. G. Pass, Practical Inorganic Chemistry, Chapman & Hall London, 1968 5. M. A. Malati, Experimental Inorganic/Physical Chemistry, Horwood Publishing, Chichester, 1999

CY1613

Organic Spectroscopy

[3 1 0 4]

Electromagnetic Spectrum & Absorption Spectroscopy: Ultraviolet (UV) absorption spectroscopy–absorption laws (Beer-Lambert law), chromophore and auxochrome, bathochromic, hypsochromic, hyperchromic and hypochromic shifts, UV spectra of conjugated enes and enones. Infrared (IR) absorption spectroscopy – molecular vibrations, Hooke’s law, selection rules, intensity and position of IR bands, measurement of IR spectrum, fingerprint region, characteristic absorptions of various functional groups and interpretation of IR spectra of simple organic compounds; NMR Spectroscopy: Nuclear magnetic resonance (NMR) spectroscopy. Proton magnetic resonance, 1 H (1H NMR) spectroscopy, nuclear shielding and deshielding, chemical shift and molecular structure, spin-spin splitting and coupling constants, areas of signals, 25

interpretation of 1H NMR spectra of simple organic molecules such as ethyl bromide, ethanol, acetaldehyde, 1,1,2-tribromoethane, ethyl acetate, toluene and acetophenone basics of 13C NMR; Mass Spectroscopy: Introduction, instrumentation, Methods of ionization, separation. Fragmentation, McLafferty rearrangement, Problems pertaining to the structure elucidation of simple organic compounds using UV, IR and 1H NMR spectroscopic techniques. Text Books: 1. W. Kemp, Organic Spectroscopy, Palgrave Macmillan, 1991. 2. R.M. Silverstein, F.X. Webster, D. Kiemle, Spectrometric Identification of Organic Compounds, John Wiley & Sons, 2005. 3. D.L. Pavia, G.M. Lampman, G.S. Kriz, J.A. Vyvyan, Introduction to Spectroscopy, Cengage Learning, 2008.

CY1614

Molecular statistics and Photochemistry

[3 1 0 4]

Statistical Thermodynamics: Types of statistics, Molecular energy levels and the Boltzmann distribution, Maxwell distribution, configurations and weights, most probable configuration, the molecular partition function, physical interpretation of the partition function. The canonical ensemble, canonical partition function and its relation to molecular partition function for independent particles, the statistical entropy, entropy and partition function, entropy of a monoatomic gas, Factorization of partition function, calculation of translational, rotational vibrational and electronic contributions, the overall partition function; Photochemistry: General principles about light absorption, electronic transition, Jablonski diagram, intersystem crossing, singlet and triplet states, Fluorescence, Phosphorescence, Quantum yield, Brief introduction and description of photochemical reactions of simple carbonyl compounds, alkenes and aromatic compounds, Barton Reaction, Norrish type I reactions and Norrish type II reactions, Hofmann-Loffler-Freytag reaction. Text Books: 1. T. Engel and P. Reid, Thermodynamics, Statistical Thermodynamics, & Kinetics, Pearson India, 2007. 2. B.R. Puri, L.R. Sharma and M.S. Pathania, Principles of Physical Chemistry, Vishal Publishing Co., 2013.

CY1617

Organometallic Compounds and Industrial Chemistry

[3 1 0 4]

Organometallics: Definition and classification of organometallic compounds, EAN rule. Organometallic compounds of Mg and Li–Use in synthesis of organic 26

compounds, preparation of Grignard reagent and organo lithium compound, importance of organometallic chemistry in modern times, definition and terminologies, preparation of metal carbonyls, binary carbonyls, mixed metal polynuclear carbonyls, metal-olefin complexes: Zeises salt, Ferrocene, Hapticity (η) of organometallic ligands, Simple examples of fluxional molecules, Coordinative unsaturation, and homogeneous catalysis by organometallic compounds, and polymerization of alkenes (Ziegler-Natta catalysis); Bonding and Structure: Molecular hydrogen compounds, metal-hydrogen interactions with C-H groups, carbonyl halides, Metal nitrosyl compounds, nitrosyl carbonyls. Dinitrogen and dioxygen complexes, tertiary phosphines as ligand; Organotransition metal Chemistry: Synthesis, structure and bonding aspects of complexes of two, three, four and six electrons cyclic and acyclic ligands. Alkyl and aryls of Transition metals, transition metal-carbon multiple bonds; alkylidene complexes and alkylidyne complexes. Water and its treatment: Sources of water, impurities in water, hardness of water and hardeness removal; Coal Chemicals: Ultimate and proximate analysis of coal and their significance, coking of coal by high temperature (By-product coke-oven) and low temperature process. Plastics and Rubber:Classification of plastics, manufacture, properties and uses of nylon 6 and nylon 6 6. manufacture of natural rubber from latex, introduction about synthetic rubbers; Sugar Industry: Extraction of juice from sugar cane. Manufacture and refining of sugar. Uses of molasses and bagasse.Cellulose Industry:Study of raw materials for the manufacture of paper. Manufacture of wood pulp by different (soda, sulphite and sulphate) processes. Multistage bleaching of wood pulp. Conversion of pulp into thin paper by Fourdrinier machine.Petroleum Industry: Composition and classification of crude petroleum. Refining of petroleum and brief introduction regarding each refining product. Thermal and catalytic cracking of petroleum products. Significance of octane number and cetane number. Paints Industry: Introduction, classification of paints, manufacture of paints, requirements of a good paint.

Text Books 1. F. A. Cotton, G. Wilkinson, C. A. Murillo and M. Bochmann, Advanced Inorganic Chemistry, Wiley India, 2007 2. C. Housecroft and A, G. Sharpe, Inorganic Chemistry, Pearson India, 2012 3. B.D. Gupta and A. J. Elias, Basic Organometallic Chemistry, University Press, 2010. 4. A.G. Massey, Main Group Chemistry, Ellis Horwood,1999. 5. J. A. Kent, Riegel’s Handbook of Industrial Chemistry, CBS, 1997.

27

CY 1631

Chemistry (Hons.) Laboratory-VI

[0 0 2 2]

Physical Chemistry: Conductometry: (i) Determination of the solubility of a sparingly soluble substance, determination of the degree of hydrolysis of NH4Cl and CH3COONa, (ii) To study the kinetics of saponification of ethyl acetate by sodium hydroxide; Potentiometry:Potentiometric titrations of diabasic acid, oxalic acid and malonic acid with base. (iii) To determine potentiometerically the solubility and solubility product of a sparingly soluble salt; Polarimetry: (i) To study the kinetics of inversion of cane sugar by means of polarimetry; Chemical Kinetics: (i) To determine activation energy of a reaction by studying its temperature dependence, (ii) To study the reaction between potassium iodide and potassium peroxodisulphate; pH-metry: (i) To titrate a weak base against a strong acid and determine the ionization constant of the weak base. Inorganic Chemistry: (i) Strong acid-strong base titration in a non-aqueous solvent using visual, conductometric/potentiometric methods, (ii) Study of reactions of the elements of first transition series: a) Iron, b) Cobalt, c) Nickel, d) Copper, (iii) Preparation of chromium (II) acetate, Cr(CH2COO)2, H2O (Use of inert atmosphere technique) and measurement of its magnetic susceptibility; (iv) Preparation and Identification of any suitable inorganic/organometallic compounds involving the use of techniques available in the department; Qualitative Analysis: To perform qualitative analysis of a given binary mixture (i) Separation by ether, sodium hydroxide, sodium bicarbonate and dil. Hydrochloric acid, (ii) Test for elements (Other than C,H,O), (iii) Functional group determination, (iv) Melting point, derivative preparation TLC for checking the purity and effectiveness of separation. Text Books: 1. G. Svehla and B. Sivasankar, Vogel's Qualitative Inorganic Analysis, Pearson India, 2012 2. J. Mendham, R.C. Denney, M.J.K Thomas and D. J. Barne, Vogel's Quantitative Chemical Analysis, Pearson India, 2009. 3. A. I. Vogel, Elementary Practical Organic Chemistry: Small Scale Preparations Part 1, Pearson India, 2010. 4. B. Vishwanathan and P.S. Raghavan, Practical Physical Chemistry, Viva Books, 2012. 5. F. Alexander, Practical Physical Chemistry, Hardpress Publishing, 2013. 6. A. I.Vogel, Elementary Practical Organic Chemistry: Quantitative Organic Analysis Part 3, Pearson India, 2010.

28

SYLLABUS Mathematics [Subsidiary Course] MA1111

DIFFERENTIAL CALCULUS AND INTEGRAL CALCULUS

[3 1 0 4]

Differential Calculus: Differentiability and differentials. Successive differentiation and Leibnitz Theorem.Statement of Rolle's Theorem. Mean Value Theorem, Taylor and Maclaurin's Theorems, indeterminate forms. Limits and continuity of functions of two variables.Partial Differentiation: Definition of Partial derivatives. Euler’s Theorem on homogeneous functions, total derivative of composite & implicit functions, Errors and approximations, Applications.Asymptotes.Curvature, Concavity, convexity and points of inflection.ExtremePoints.Envelopes.Curve tracing, Tracing of Cartesian, Polar Curves, Integral Calculus: Instigation, Beta and Gamma Functions and its application. Application of Integral Calculus, Quadrature.Area and length of a curve.Arc length as a parameter.Multiple Integrals: Definitions, Double integrals, Triple Integral Text Books: 1. Shanti Nayaran, Differential Calculus, ShyamLal Charitable Trust, Delhi, 2002. 2. Shanti Nayaran, Integral Calculus, ShyamLal Charitable Trust, Delhi, 2002. 3. N. Piskunov, Differential Calculus & Integral Calculus, Vol. 1 and II, Mir Pub., 1981. References: 1. C.B. Thomas, Calculus and Analytical Geometry, Narosa Pub., Delhi, 1996. 2. N. Piskunov, Differential Calculus & Integral Calculus, Vol. 1 and II, Mir Pub., 1981. 3. R.Courant, and JohnF.,Introduction to Calculus and Analysis, Volume I, Springer, 2000. MA1211

ALGEBRA

[3 1 0 4]

Algebra: Algebraic structure, Definition of a group with examples and simple properties. Subgroups.Cyclicgroups.Cosetdecomposition.Lagrange’s theorem and its consequences.Fermat’s and Euler’s theorems.Homomorphism and Isomorphism. Normal subgroups: Quotient groups. The fundamental theorem of homomorphism.Permutationgroups.Even and odd permutations.The alternating groups An.Cayley’stheorem.Introduction to rings, subrings, integral domains and fields. 29

Text Book: I. N. Heristein, Topics in Algebra, Wiley Eastern Ltd., New Delhi, 1975. References: H. S. Hall and S. R. Knight, Higher Algebra, Elibron.com, 1999.

MA1311

DIFFERENTIAL EQUATIONS

[3 1 0 4]

General Linear Higher order differential equations: First order and first degree differential equation. Linear homogeneous and non-homogeneous equations with constant coefficients, inverse differential operators and method of variation of parameters.Solution of Cauchy’s homogeneous linear equations, solution of simple simultaneous linear differential equations.Linear equations and equations reducible to linear form. First order higher degree equations solvable for x, y, p. Clairaut's form and singular solutions. Orthogonal trajectories.Linear differential equations with constant coefficients.Homogeneous linear ordinary differential equations.Linear differential equations of second order.Transformation of the equation by changing the dependent variable and the independent variable. Text Books: 1. Simmons, Differential Equations, Tata McGraw-Hill Education, 2006. 2. B. S. Grewal, Higher Engineering Mathematics, Khanna Publishers, Delhi, 2006. 3. E. Kreyzig, Advanced Engineering Mathematics, Wiley Eastern, 2006. References: 1. D.Murray, Introductory Course in Differential Equations for students in classical and engineering colleges. Longmans, Green, 1898. 2. Boyce and Diprima, Elementary Differential Equations and Boundary Value Problems, Wiley, 9th Edition, 2008. MA1312

SOLID GEOMETRY AND VECTOR CALCULUS

[3 1 0 4]

Solid Geometry: Sphere. Cone.Cylinder. Centralconicoids, Ellipsoids, Hyperboloid of one and two sheet, paraboloids, plane sections of conicoids. Generating lines.Reduction of second degree equations to normal form; classification of quadrics.VectorCalculus : Vector differentiation. Total differential, Gradient, Divergence and curl, Directional derivatives.Vector integration: Path, line, surface, and volume integrals. Line integrals of linear differential forms, integration of total differentials, conservative fields.Theorems of Green, Gauss, Stokes, and problems based on these.

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Text Books: 1. Marsden, J., and Tromba, Vector Calculus., 5th Edition, W. H. Freeman,2003. 2. G.F. Simmons, Introduction to Topology and Modern Analysis, Krieger Publishing Company, 2003. 3. Kreyszig, Advanced Engineering Mathematics, 8th Edition, Wiley India Pvt. Ltd., 2010. References: 1. S. L.Loney, Elements of Coordinate Geometry, Scholarly Publishing Office, University of Michigan Library, 2005. 2. Shanti Narayan, Analytical Geometry, S. Chand, 2010. 3. R.Bell,Elementary Treatise on Coordinate Geometry of Three Dimensions, Third Edition Mac Millan & Co, Ltd, 1963.

MA1411

LINEAR PROGRAMMING PROBLEMS & ITS APPLICATIONS

[3 1 0 4]

The Linear programming problem.Mathematical Formulation of the Problem.Types of solutions.Linear programming in matrix notation.Graphical solution of linear programming problems.-Some Exceptional Cases.General Linear Programming Problem (General L.P.P) – Slack and Surplus Variables, Theory and application of the simplex method of solution of a linear programming problem, Charne's M-technique. The two phase method. Transportation & Assignment Problems. Text Book: G.Hadley, Linear Programming ,Narosa Publishing House, 1995. References: 1.S. I.Gass, Linear Programming, Methods and Applications(4th edition), Mc Graw- Hill, New York, 1975. 2.S. D. Sharma, Operation Research, Kedarnath and Ram Nath Publication, 1972.

MA1412

DYNAMICS

[3 1 0 4]

Kinematics: Radial, Transverse, tangential, normal velocities and accelerations, simple harmonic motion; Repulsion from a fixed pint, Motion under inverse square, Law, Hooke’s law, Horizontal and vertical elastic strings. Motion of a projectile on an inclined plane. Work energy and impulse, conservation of li near momentum, uniform circular motion, motion on a smooth curve in a vertical plane, motion on the inside of a smooth vertical circle, Cycloidal motion, Motion in the resisting medium: Resistance varies as velocity and acquire of velocity. Central forces.Stability of nearly circular orbits.Motion under the inverse square law.Kepler’slaws.Time of describing an arc and area of any orbit.Slightly

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disturbed orbits.Tangential and normal accelerations.Motion of a particle on a smooth curve.Principle of conservation of energy. References: 1. A. S.Ramsey,Dynamics (Part I)., The English Language Book Society and Cambridge University Press, 1962. 2. J.Kar, M.t Hydrostatics. , Globe Library, 2nd Edition, 1957. 3. W. H.Besant, A. S.Ramsey, A Treatise on Hydromechanics (Part I). , G. Bell and Sons, Ltd, London, 1960. MA1511

REAL ANALYSIS

[3 1 0 4]

Real Numbers: Real numbers as a complete ordered field. Limit point, Bolzano Weierstrass theorem, closed and open sets, union and intersection of such sets, concept of compactness, Heine Borel theorem, connected sets. Real Sequences, Limit and convergence of a sequence, monotonic sequences, Cauchy’s sequence, subsequence, Cauchy’s general principle of convergence. Improper integrals Convergence of improper integrals and their properties, convergence of Beta and Gamma functions. Differentiation and integration of a function under the sign of integral.Infinite Series: Definition regarding convergence, divergence of infinite series. Tests: Comparison test, ratio test, Cauchy’s root test, Raabe’s test, logarithmic test, integral test, Cauchy’s condensation test, Gauss’s test, with proofs, alternating series, Leibnitz’s theorem, absolute and conditional convergence. Taylor’s and Maclaurin’s expansion of functions. Text Books: 1. Walter Rudin, Principles of Mathematical Analysis, McGraw-Hill, 1976 2 S.Shastri, Real Analysis, Springer, 2010 3. Shanti Narayan,Elements of Real Analysis, S. Chand Limited, 2003

References: A. N.Kolmogorov, and S. V.Fomin, Elements of the Theory of Functions and Functional Analysis, Vol 1, Dover,New York, 1961. MA1512

NUMERICAL ANALYSIS AND PROBABILITY

[3 1 0 4]

THEORY Numerical Analysis : Differences, Relation between differences and derivatives, Differences of a polynomial, Newton’s formulae for forward and backward interpolation, Divided difference, Newton’s divided difference, Interpolation formula, Lagrange’s interpolation formula. Central differences, Gauss’s, Stirling’s and Bessel’s interpolation formulae. Numerical Differentiation.Derivatives from interpolation formulae. Numerical Integration, Newton – Cote’s formula, Trapezoidal rule, Simpson’s one- third rule, Simpson’s three – eighth rule and Gauss’s quadrature formulae. Numerical solution of algebraic and transcendental equations. Bisection method, RegulaFalsi Method, Method of iteration, Newton 32

Raphson Method, Gauss elimination and Iterative method for solving linear algebraic and transcendental equations. Solution of ordinary differential equations of first order with initial and boundary conditions using Picard’s and modified Euler’s method. Probability Theory: Definitions, Sample space, events, algebra of events, joint & conditional probability, dependent events.Bernoulli’s trials, Probability &Baye’s theorem. Discrete & continuous distributions, Probability distribution & probability densities: Binomial, Poisson, normal and uniform distribution & density functions.Correlation& Regression Correlation & regression: Linear regression, Rank correlation, Method of least squares Fitting of straight lines & second degree parabola. Text Books: 1. G. Haribhaskaran, Numerical Methods, Laxmi Publications, Delhi, 2008. 2. B. S. Grewal, Higher Engineering Mathematics, Khanna Publishers, Delhi, 2006. Reference Books: 1. E. Kreyzig, Advanced Engineering Mathematics, Wiley Eastern, 2006. 2. Srimanta Pal, Numerical Methods, Oxford university Press, Delhi 2012. MA1611

COMPLEX ANALYSIS

[3 1 0 4]

Calculas:Limits, Continuity, differentiability, Complex plane, connected and compact sets, Statement of Jordan curve theorem. Extended complex plane, and stereographic projection. Complex valued function, the extended plane. Analytic functions, CR equations (Cartesian and polar form), Harmonic functions, construction of an analytic function, conformal mappings, Bilinear transformation and its properties. Power series: absolute convergence, Cauchy Hadamard theorem, radius of convergence, analyticity of sum function of a power series. Complex integration, complex line integrals, Cauchy’s integral theorem, Indefinite integral, fundamental theorem of Integral calculus for complex functions, Cauchy’s integral formula, Analyticity of the derivative of analytic function, Liouville’s theorem, Poisson’s Integral formula, Morera’s theorem, Taylor’s and Laurent’s series. Maximum modulus principle.Singularities, Brach points, Meromorphic functions and Entire functions, Reimann’s theorem, Cauchy-Weierstrass theorem. Text Book: 1. R.V. Churchill, J.W.Brown, Complex Variables and Applications, 5thedn., McGraw Hill Series, 2000. References: 1. J. B. Conway, Functions of one complex variable, Springer International Student edition, Narosa Publishing House, New Delhi, 2000.

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MA1612

DISCRETE MATHEMATICS STRATURE

[3 1 0 4]

Propositional Calculus: Logical connectives, Truth tables, Tautologies and contradictions, Contrapositive, Logical equivalences and implications, De Morgan’s Laws, Normal forms, Rules of inference, Arguments, Validity of arguments. Predicate Calculus: Free and bound variables, Quantifiers, Theory of inference, The rules of universal specification and generalization, Validity of arguments. Set Theory: Types of relations on sets and their properties, Relational matrix and the graph of a relation, Partitions, Equivalence relations, Poset, Hasse diagram. Definitions & Classification of functions, Characteristic function of a set, Hashing functions, Recursive functions, Permutation functions. Combinatorics: Discrete numeric function, Basic counting principles, Generating functions, Recurrence relations, Inclusion and exclusion principle, Euler’s  function and its applications to Cryptography. Graph Theory:Graphs :Definition and examples of graphs,Incidence and degree, Handshaking lemma, Isomorphism Sub-graphs, Weighted Graphs, Eulerian Graphs, Hamiltonian Graphs Walks, Paths and Circuits. Trees : Definition and properties of trees Pendent vertices, centre of a tree Rooted and binary tree, spanning trees, minimum spanning tree algorithms Fundamental circuits, cutsets and cut vertices, fundamental cutsets, the four color theorem Directed Graphs :Types of digraphs, directed paths and connectedness, Euler digraphs, Directed trees, Text Books: 1. Trembly J.P and Manohar R, Discrete Mathematical Structures with Applications to Computer Science, Tata McGraw–Hill Pub. Co. Ltd, New Delhi, 2003. 2. Ralph. P. Grimaldi, Discrete and Combinatorial Mathematics: An Applied Introduction, Fourth Edition, Pearson Education Asia, Delhi, 2002. 3. T. Veerarajan, Discrete Mathematics, Tata McGraw Hill, 2010. References: 1. J. A.Bondy& U. S. R. Murty, Graph Theory with Applications, MacMillan, 1976. 2. G. R. E.Polya, Tarjan& D. R. Woods, Notes on Introductory Combinatorics, BirkHauser, 1983. 3. M. N. S.Swamy, & K. Tulsiram, Graph, Networks and Algorithms, John Willey, 1981. 4. Bernard Kolman, Robert C. Busby, Sharan Cutler Ross, Discrete Mathematical Structures, Fourth Indian reprint, Pearson Education Pvt Ltd., New Delhi, 2003.

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SYLLABUS Physics [Ancillary Course] PY 1211

Oscillations and Wave Optics

[2 1 0 3]

Oscillations Potential well and periodic oscillations, harmonic oscillations, differential equation and its solution, kinetic and potential energy, examples of simple harmonic oscillations, spring and mass system, simple and compound pendulum, torsional pendulum, LC circuit, oscillations of two masses connected by a spring. Motion of two coupled oscillators, normal modes, N coupled oscillators, damped harmonic oscillator, power dissipation, quality factor, driven harmonic oscillator, transient and steady states, power absorption, resonance in systems with many degrees of freedom. Wave Optics Interference: The principle of superposition. Two-silt interference, coherence requirement for the sources, Localized fringes; thin films and applications, Fringes of equal inclination, Newton’s Ring Experiment, Michelson interferometer and its application for precision determination of wavelength, wavelength difference and the width of spectral lines. Diffraction: Fresnel and Fraunhoffer diffraction, Fraunhoffer diffraction due to single silt, Diffraction due to N parallel silts, intensity distribution, plane diffraction grating, reflection grating and blazed gratings. Resolving power of a grating and its comparison with resolving power of prism, Raleigh criterion, resolving power of telescope and microscopic systems, outline of phase contrast microscopy Polarization: Double refraction and optical rotation, phase retardation plates, double image prism, Rotation of plane of polarization, origin of optical rotation in liquids and in crystals, Specific rotation, Polarimeters Lasers: Laser systems: Purity of a spectral line, coherence length and coherence time, spatial coherence of a source, Einstein’s A and B coefficients, Spontaneous and induced emissions, conditions for laser action, population inversion, spatial coherence and directionality, He- Ne Laser, Pulsed lasers and tunable lasers, Applications of Lasers

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References: 1. Khandelwal D P, Oscillations and Waves,Himalaya Publishing House, Bombay. 2. Ghosh R K; The Mathematics of Waves and Vibrations,,Macmillan, (1975) 3. Berkeley Physics Courses; Vol. III , Waves and Oscillations. 4. Jain H J; The Physics of Vibrations and Waves, Macmillan (1975) 5. Ghatak A K , Physical Optics, Mc-Graw Hill 6. Khandelwal D P, Optics and Atomic Physics, Himalaya Publishing House, Bombay, (1988) 7. Smith F and Thomson J H, Manchester Physics series; Optics, English Language Book Society and John Wiley, (1977) 8. Laud B B, Laser and Non-liner Optics, Wiley Eastern, (1985). 9. Smith and Thomson; Optics, John Wiley and Sons.

PY 1231 Optics Lab [0 0 4 2] 1. Interference Expt. Lloyd’s mirror 2. Interference at an air wedge 3. Newton’s Rings experiment. 4. Diffraction at a straight edge 5. Diffraction grating (Determination of wavelengths of the Hg spectral lines)Minimum deviation method 6. Diffraction grating - Normal incidence method. 7. L-B Photometer 8. Optical activity- Polarimeter. 9. Biprism Experiment. 10. Moduli of elasticity- Cornue’s fringes 11. Determination of Brewster’s angle and R.I of glass surface using spectrometer and a polaroid.

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