Tabla De Los Datos Para 760mmhg Para La Mezcla Metanol.docx

Tabla de los datos para 760mmHg para la mezcla metanol/agua ideal. Ec. Antoine (°C) Ti

(mm Hg) P1i0

P2i0

Raoult/Dalton (-)

(mm Hg)

(-)

(cal °C/mol)

X1

P

y1

hl

Hv

Relación de Equilibrio K1

K1

K2

K2

volatilidad

f (x)



1/(y-x)

Referencia p/graficar

64.574

760.013 182.6218 0.999977

760.00000

0.999994

1252

9667

1.00002

1.00002 0.24029

0.24029

4.16168 56429.858

0.999977

65.000

772.861 186.1434 0.978081

760.00000

0.994631

1258

9681

1.01692

1.01692 0.24493

0.24493

4.15196

60.420

0.978081

66.000

803.73 194.6368 0.928205

760.00000

0.981613

1273

9717

1.05754

1.05754 0.25610

0.25610

4.12938

18.724

0.928205

67.000

835.618 203.4562 0.880382

760.00000

0.967978

1288

9752

1.09950

1.0995 0.26771

0.26771

4.10711

11.416

0.880382

68.000

868.55 212.6116 0.834511

760.00000

0.953704

1303

9789

1.14283

1.14283 0.27975

0.27975

4.08515

8.390

0.834511

69.000

902.554 222.1132 0.790497

760.00000

0.938772

1317

9826

1.18757

1.18757 0.29225

0.29225

4.06349

6.744

0.790497

70.000

937.657 231.9712 0.748250

760.00000

0.923159

1332

9865

1.23376

1.23376 0.30523

0.30523

4.04212

5.717

0.748250

71.000

973.884 242.1965 0.707684

760.00000

0.906845

1347

9903

1.28143

1.28143 0.31868

0.31868

4.02105

5.021

0.707684

72.000

1011.26 252.7998 0.668720

760.00000

0.889806

1363

9943

1.33061

1.33061 0.33263

0.33263

4.00026

4.523

0.668720

73.000

1049.83 263.7921 0.631281

760.00000

0.872019

1378

9984

1.38135

1.38135 0.34709

0.34709

3.97975

4.154

0.631281

74.000

1089.6 275.1849 0.595295

760.00000

0.853462

1393

10025

1.43368

1.43368 0.36209

0.36209

3.95951

3.873

0.595295

75.000

1130.61 286.9896 0.560694

760.00000

0.834110

1408

10068

1.48764

1.48764 0.37762

0.37762

3.93954

3.657

0.560694

76.000

1172.88 299.2179 0.527412

760.00000

0.813938

1423

10111

1.54327

1.54327 0.39371

0.39371

3.91983

3.490

0.527412

77.000

1216.46 311.8820 0.495389

760.00000

0.792922

1439

10155

1.60061

1.60061 0.41037

0.41037

3.90039

3.361

0.495389

78.000

1261.36 324.9940 0.464566

760.00000

0.771036

1454

10201

1.65969

1.65969 0.42762

0.42762

3.88119

3.263

0.464566

79.000

1307.63 338.5664 0.434888

760.00000

0.748253

1469

10247

1.72056

1.72056 0.44548

0.44548

3.86225

3.191

0.434888

80.000

1355.28 352.6119 0.406303

760.00000

0.724546

1485

10294

1.78327

1.78327 0.46396

0.46396

3.84355

3.142

0.406303

81.000

1404.36 367.1435 0.378761

760.00000

0.699889

1500

10342

1.84784

1.84784 0.48308

0.48308

3.82510

3.114

0.378761

82.000

1454.89 382.1744 0.352214

760.00000

0.674254

1516

10392

1.91433

1.91433 0.50286

0.50286

3.80687

3.105

0.352214

83.000

1506.91 397.7180 0.326618

760.00000

0.647611

1531

10442

1.98277

1.98277 0.52331

0.52331

3.78889

3.115

0.326618

84.000

1560.45 413.7881 0.301931

760.00000

0.619931

1547

10494

2.05322

2.05322 0.54446

0.54446

3.77112

3.145

0.301931

85.000

1615.54 430.3985 0.278112

760.00000

0.591185

1563

10547

2.12571

2.12571 0.56631

0.56631

3.75359

3.194

0.278112

86.000

1672.22 447.5634 0.255122

760.00000

0.561342

1578

10601

2.20029

2.20029 0.58890

0.58890

3.73627

3.266

0.255122

87.000

1730.52 465.2974 0.232926

760.00000

0.530371

1594

10657

2.27700

2.27700 0.61223

0.61223

3.71917

3.362

0.232926

88.000

1790.48 483.6151 0.211487

760.00000

0.498241

1610

10713

2.35589

2.35589 0.63634

0.63634

3.70228

3.487

0.211487

89.000

1852.13 502.5315 0.190774

760.00000

0.464919

1625

10771

2.43701

2.43701 0.66123

0.66123

3.68560

3.648

0.190774

90.000

1915.51 522.0618 0.170755

760.00000

0.430372

1641

10831

2.52041

2.52041 0.68692

0.68692

3.66912

3.852

0.170755

91.000

1980.65 542.2215 0.151400

760.00000

0.394567

1657

10891

2.60612

2.60612 0.71345

0.71345

3.65285

4.112

0.151400

92.000

2047.6 563.0264 0.132680

760.00000

0.357469

1673

10954

2.69421

2.69421 0.74082

0.74082

3.63678

4.449

0.132680

93.000

2116.39 584.4924 0.114569

760.00000

0.319043

1689

11017

2.78472

2.78472 0.76907

0.76907

3.62089

4.891

0.114569

94.000

2187.05 606.6358 0.097041

760.00000

0.279253

1704

11082

2.87769

2.87769 0.79820

0.79820

3.60520

5.488

0.097041

95.000

2259.62 629.4731 0.080071

760.00000

0.238065

1720

11149

2.97319

2.97319 0.82825

0.82825

3.58970

6.329

0.080071

96.000

2334.15 653.0212 0.063635

760.00000

0.195439

1736

11217

3.07125

3.07125 0.85924

0.85924

3.57439

7.587

0.063635

97.000

2410.67 677.2971 0.047712

760.00000

0.151340

1752

11287

3.17194

3.17194 0.89118

0.89118

3.55925

9.650

0.047712

98.000

2489.22 702.3182 0.032280

760.00000

0.105727

1768

11358

3.27529

3.27529 0.92410

0.92410

3.54430

13.615

0.032280

99.000

2569.85 728.1021 0.017319

760.00000

0.058563

1784

11431

3.38138

3.38138 0.95803

0.95803

3.52952

24.246

0.017319

100.000

2652.58 754.6666 0.002810

760.00000

0.009808

1800

11506

3.49024

3.49024 0.99298

0.99298

3.51491

142.899

0.002810

100.197

2669.14 759.9934 0.000003

760.00000

0.000012

1803

11521

3.51202

3.51202 0.99999

0.99999

3.51205 #########

0.000003

Tabla de los datos para 760mmHg para la mezcla metanol/agua no ideal. (°C) Ti

Ec. Antoine (mm Hg) P1i0

P2i0

(-) X1_supuesta

Ec. Van Laar (-) (-)

1

2

Raoult m (mm Hg)

(-)

(-)

(cal °C/mol)

P

X1_calculada

y1

hl

Hv

64.574

760.013 182.6218 0.999970 1.00000 1.74347 760.00022

0.999970

0.999987

1252

9667

65.000

772.861 186.1434 0.971236 1.00029 1.70939 760.00014

0.971236

0.987957

1257

9690

66.000

803.73 194.6368 0.905008 1.00334 1.63291 759.99991

0.905008

0.960276

1271

67.000

835.618 203.4562 0.840529 1.00994 1.56133 760.00006

0.840529

0.933345

68.000

868.55 212.6116 0.777868 1.02042 1.49464 760.00004

0.777868

69.000

902.554 222.1132 0.717135 1.03511 1.43283 759.99995

70.000

K1 1.00002

K2

volatilidad

f (x)



1/(y-x)

Referencia p/graficar

0.418942

2.38701

59054.9656

0.999970

1.01722

0.418673

2.42962

59.8051

0.971236

9742

1.06107

0.418189

2.53729

18.0938

0.905008

1284

9794

1.11043

0.417977

2.65667

10.7740

0.840529

0.907120

1297

9845

1.16616

0.418128

2.78901

7.7368

0.777868

0.717135

0.881551

1310

9896

1.22927

0.418749

2.93557

6.0822

0.717135

937.657 231.9712 0.658485 1.05436 1.37591 760.00013

0.658485

0.856576

1324

9945

1.30083

0.419963

3.0974849

5.0482

0.658485

71.000

973.884 242.1965 0.602117 1.07849 1.32392 759.99988

0.602117

0.832130

1337

9993

1.38201

0.421907

3.27562

4.3476

0.602117

72.000

1011.26 252.7998 0.548273 1.10774 1.27688 759.99974

0.548273

0.808138

1351

10041

1.47397

0.424729

3.47038

3.8481

0.548273

73.000

1049.83 263.7921 0.497220 1.14222 1.23476 760.00002

0.497220

0.784518

1364

10089

1.57781

0.428581

3.68148

3.4807

0.497220

74.000

1089.6 275.1849 0.449223 1.18188 1.19752 760.00006

0.449223

0.761180

1378

10136

1.69444

0.433605

3.90779

3.2056

0.449223

75.000

1130.61 286.9896 0.404513 1.22643 1.16500 759.99960

0.404513

0.738030

1392

10183

1.82449

0.439926

4.14727

2.9983

0.404513

76.000

1172.88 299.2179 0.363253 1.27538 1.13697 760.00000

0.363253

0.714971

1406

10230

1.96825

0.447632

4.39701

2.8432

0.363253

77.000

1216.46 311.8820 0.325505 1.32802 1.11308 759.99991

0.325505

0.691906

1421

10276

2.12564

0.456777

4.65356

2.7292

0.325505

78.000

1261.36 324.9940 0.291227 1.38356 1.09295 759.99993

0.291227

0.668740

1435

10323

2.29628

0.467371

4.91320

2.6489

0.291227

79.000

1307.63 338.5664 0.260278 1.44115 1.07612 759.99966

0.260278

0.645383

1450

10370

2.47959

0.479393

5.17235

2.5967

0.260278

80.000

1355.28 352.6119 0.232443 1.49997 1.06215 759.99961

0.232443

0.621750

1466

10417

2.67485

0.492797

5.42789

2.5687

0.232443

81.000

1404.36 367.1435 0.207460 1.55931 1.05060 759.99985

0.207460

0.597765

1481

10464

2.88135

0.507526

5.67724

2.5621

0.207460

82.000

1454.89 382.1744 0.185047 1.61855 1.04108 760.00006

0.185047

0.573358

1497

10512

3.09844

0.523518

5.9185036

2.5753

0.185047

83.000

1506.91 397.7180 0.164923 1.67723 1.03325 759.99950

0.164923

0.548463

1513

10560

3.32557

0.540713

6.15035

2.6073

0.164923

84.000

1560.45 413.7881 0.146824 1.73497 1.02681 760.00041

0.146824

0.523027

1529

10609

3.56227

0.559056

6.37194

2.6581

0.146824

85.000

1615.54 430.3985 0.130505 1.79151 1.02153 759.99932

0.130505

0.496992

1545

10659

3.80823

0.578505

6.58287

2.7286

0.130505

86.000

1672.22 447.5634 0.115751 1.84665 1.01719 759.99953

0.115751

0.470315

1562

10709

4.06316

0.599022

6.78299

2.8204

0.115751

87.000

1730.52 465.2974 0.102371 1.90028 1.01363 760.00136

0.102371

0.442951

1578

10760

4.32692

0.620578

6.97240

2.9362

0.102371

88.000

1790.48 483.6151 0.090197 1.95231 1.01072 760.00144

0.090197

0.414855

1595

10812

4.59943

0.643156

7.15136

3.0802

0.090197

89.000

1852.13 502.5315 0.079085 2.00273 1.00834 759.99974

0.079085

0.385989

1611

10864

4.88068

0.666740

7.32021

3.2584

0.079085

90.000

1915.51 522.0618 0.068912 2.05151 1.00640 760.00032

0.068912

0.356319

1628

10918

5.17063

0.691322

7.47935

3.4794

0.068912

91.000

1980.65 542.2215 0.059569 2.09866 1.00483 759.99935

0.059569

0.325806

1645

10972

5.46938

0.716899

7.62922

3.7561

0.059569

92.000

2047.6 563.0264 0.050964 2.14422 1.00357 759.99943

0.050964

0.294418

1662

11028

5.77699

0.743472

7.77029

4.1075

0.050964

93.000

2116.39 584.4924 0.043016 2.18822 1.00257 759.99858

0.043016

0.262121

1679

11084

6.09358

0.771046

7.90300

4.5640

0.043016

94.000

2187.05 606.6358 0.035656 2.23069 1.00178 759.99922

0.035656

0.228885

1696

11141

6.41925

0.799627

8.02781

5.1752

0.035656

95.000

2259.62 629.4731 0.028823 2.27169 1.00117 759.99997

0.028823

0.194675

1714

11200

6.75417

0.829225

8.14516

6.0295

0.028823

96.000

2334.15 653.0212 0.022464 2.31127 1.00072 760.00006

0.022464

0.159461

1731

11259

7.09850

0.859855

8.25546

7.2994

0.022464

97.000

2410.67 677.2971 0.016533 2.34948 1.00039 760.00032

0.016533

0.123211

1748

11320

7.45241

0.891529

8.35913

9.3740

0.016533

98.000

2489.22 702.3182 0.010989 2.38638 1.00017 759.99853

0.010989

0.085891

1765

11381

7.81610

0.924266

8.45655

13.3508

0.010989

99.000

2569.85 728.1021 0.005797 2.42200 1.00005 759.99808

0.005797

0.047476

1782

11444

8.18972

0.958078

8.54807

23.9930

0.005797

100.000

2652.58 754.6666 0.000926 2.45640 1.00000 760.00235

0.000926

0.007939

1800

11508

8.57340

0.992981

8.63401

142.5929

0.000926

100.197

2669.14 759.9934 0.000001 2.46304 1.00000 759.99922

0.000001

0.000009

1803

11521

8.65026

0.999992

8.65033 130714.4594

0.000001

Tabla de los datos para 585mmHg para la mezcla metanol/agua ideal. Ec. Antoine (°C) Ti

(mm Hg) P1i0

P2i0

Raoult/Dalton (-)

(mm Hg)

(-)

(cal °C/mol)

X1

P

y1

hl

Hv

Relación de Equilibrio K1

K1

K2

volatilidad

f (x)

K2



1/(y-x)

58.140

586.586 135.9149 0.996480

585.00000

0.999182

1127

9543

1.00271

1.00271 0.23233

0.23233

4.31584

370.110

59.000

607.644 141.4970 0.951423

585.00000

0.988250

1140

9573

1.03871

1.03871 0.24188

0.24188

4.29439

27.154

60.000

632.92 148.2320 0.901131

585.00000

0.974948

1155

9609

1.08192

1.08192 0.25339

0.25339

4.26980

13.547

61.000

659.069 155.2376 0.852988

585.00000

0.960988

1170

9645

1.12661

1.12661 0.26536

0.26536

4.24555

9.259

62.000

686.114 162.5225 0.806884

585.00000

0.946349

1185

9682

1.17284

1.17284 0.27782

0.27782

4.22165

7.170

63.000

714.077 170.0956 0.762717

585.00000

0.931007

1200

9720

1.22065

1.22065 0.29076

0.29076

4.19809

5.942

64.000

742.985 177.9661 0.720390

585.00000

0.914938

1216

9759

1.27006

1.27006 0.30422

0.30422

4.17487

5.140

65.000

772.861 186.1434 0.679811

585.00000

0.898118

1231

9799

1.32113

1.32113 0.31819

0.31819

4.15196

4.581

66.000

803.73 194.6368 0.640893

585.00000

0.880521

1246

9839

1.37390

1.3739 0.33271

0.33271

4.12938

4.173

67.000

835.618 203.4562 0.603554

585.00000

0.862121

1262

9881

1.42841

1.42841 0.34779

0.34779

4.10711

3.867

68.000

868.55 212.6116 0.567718

585.00000

0.842892

1277

9923

1.48470

1.4847 0.36344

0.36344

4.08515

3.634

69.000

902.554 222.1132 0.533311

585.00000

0.822807

1293

9966

1.54283

1.54283 0.37968

0.37968

4.06349

3.454

70.000

937.657 231.9712 0.500264

585.00000

0.801839

1308

10011

1.60283

1.60283 0.39653

0.39653

4.04212

3.316

71.000

973.884 242.1965 0.468511

585.00000

0.779958

1324

10056

1.66476

1.66476 0.41401

0.41401

4.02105

3.211

72.000

1011.26 252.7998 0.437991

585.00000

0.757135

1340

10103

1.72866

1.72866 0.43214

0.43214

4.00026

3.133

73.000

1049.83 263.7921 0.408644

585.00000

0.733342

1355

10150

1.79457

1.79457 0.45093

0.45093

3.97975

3.080

74.000

1089.6 275.1849 0.380416

585.00000

0.708547

1371

10199

1.86256

1.86256 0.47040

0.47040

3.95951

3.048

75.000

1130.61 286.9896 0.353253

585.00000

0.682719

1387

10249

1.93266

1.93266 0.49058

0.49058

3.93954

3.035

76.000

1172.88 299.2179 0.327107

585.00000

0.655826

1402

10300

2.00493

2.00493 0.51148

0.51148

3.91983

3.042

77.000

1216.46 311.8820 0.301929

585.00000

0.627836

1418

10353

2.07942

2.07942 0.53313

0.53313

3.90039

3.068

78.000

1261.36 324.9940 0.277674

585.00000

0.598715

1434

10406

2.15618

2.15618 0.55555

0.55555

3.88119

3.115

79.000

1307.63 338.5664 0.254301

585.00000

0.568430

1450

10461

2.23526

2.23526 0.57875

0.57875

3.86225

3.183

80.000

1355.28 352.6119 0.231769

585.00000

0.536945

1465

10518

2.31672

2.31672 0.60276

0.60276

3.84355

3.277

81.000

1404.36 367.1435 0.210040

585.00000

0.504224

1481

10575

2.40061

2.40061 0.62760

0.62760

3.82510

3.399

82.000

1454.89 382.1744 0.189077

585.00000

0.470232

1497

10635

2.48699

2.48699 0.65329

0.65329

3.80687

3.557

83.000

1506.91 397.7180 0.168846

585.00000

0.434932

1513

10695

2.57591

2.57591 0.67986

0.67986

3.78889

3.758

84.000

1560.45 413.7881 0.149314

585.00000

0.398284

1529

10757

2.66743

2.66743 0.70733

0.70733

3.77112

4.017

85.000

1615.54 430.3985 0.130450

585.00000

0.360251

1545

10821

2.76160

2.7616 0.73572

0.73572

3.75359

4.352

86.000

1672.22 447.5634 0.112225

585.00000

0.320794

1561

10886

2.85849

2.85849 0.76507

0.76507

3.73627

4.795

87.000

1730.52 465.2974 0.094610

585.00000

0.279871

1577

10953

2.95815

2.95815 0.79538

0.79538

3.71917

5.398

88.000

1790.48 483.6151 0.077579

585.00000

0.237441

1593

11021

3.06065

3.06065 0.82669

0.82669

3.70228

6.255

89.000

1852.13 502.5315 0.061106

585.00000

0.193463

1609

11092

3.16603

3.16603 0.85903

0.85903

3.68560

7.555

90.000

1915.51 522.0618 0.045167

585.00000

0.147894

1625

11163

3.27438

3.27438 0.89241

0.89241

3.66912

9.735

91.000

1980.65 542.2215 0.029740

585.00000

0.100690

1641

11237

3.38573

3.38573 0.92687

0.92687

3.65285

14.094

91.500

2013.9 552.5423 0.022211

585.00000

0.076462

1650

11275

3.44256

3.44256 0.94452

0.94452

3.64479

18.433

92.000

2047.6 563.0264 0.014801

585.00000

0.051807

1658

11313

3.50017

3.50017 0.96244

0.96244

3.63678

27.023

92.500

2081.76 573.6757 0.007509

585.00000

0.026721

1666

11351

3.55857

3.55857 0.98064

0.98064

3.62881

52.050

93.000

2116.39 584.4924 0.000331

585.00000

0.001199

1674

11390

3.61775

3.61775 0.99913

0.99913

3.62089 1152.800

Tabla de los datos para 585mmHg para la mezcla metanol/agua no ideal. Ec. Antoine (°C)

(mm Hg)

Ti

P1i0

P2i0

Ec. Van Laar (-)

(-)

(-)

X1_sup

g1

g2

Raoult m (mm Hg) P

1

1.743 47357 1.709 39037 1.632 90703 1.561 33142 1.494 63791 1.432 82533 1.375 91149 1.092 94871 1.041 07869 1.010 71923 1.001 78013 1.000 17413

585.0 00137 585.0 01134 585.0 01642 585.0 01863 585.0 01552 585.0 02021 585.0 02228 585.0 00026 585.0 01276 585.0 0149 585.0 02787 585.0 06158

uesta

58.07 462 58.49 315 59.47 5 60.45 61 61.43 65 62.41 63 63.39 55 71.21 65 75.12 701 81.00 425 86.90 29 90.85

585.0 106 595.1 58252 619.5 42985 644.7 37313 670.7 62534 697.6 41809 725.3 9608 981.8 77938 1135. 90511 1404. 57076 1724. 78652 1970. 76892

135.4 98276 138.1 84007 144.6 62933 151.3 93153 158.3 82565 165.6 39646 173.1 72359 244.4 59667 288.5 18954 367.2 06354 463.5 50089 539.1 56851

0.999 97 0.971 236 0.905 008 0.840 529 0.777 868 0.717 135 0.658 485 0.291 227 0.185 047 0.090 197 0.035 656 0.010 989

1.000 29005 1.003 33725 1.009 93968 1.020 41674 1.035 10981 1.054 3628 1.383 56217 1.618 55293 1.952 31413 2.230 69171 2.386 37736

(-)

(-)

(cal °C/mol)

X1_cal culada 0.9999 6961 0.9712 3284 0.9050 0374 0.8405 2451 0.7778 6453 0.7171 3083 0.6584 8077 0.2912 2698 0.1850 4617 0.0901 9637 0.0356 5518 0.0109 8752

y1

hl

Hv

K1

K2

volatili f (x) dad a 1/(y-x)

0.999 98749 0.988 38252 0.961 63812 0.935 56441 0.910 11288 0.885 24295 0.860 90186 0.676 28839 0.581 55956 0.422 79364 0.234 50364 0.088 34309

1125. 72763 1131. 50893 1145. 03802 1158. 519 1171. 96606 1185. 39823 1198. 83713 1310. 45335 1371. 34477 1467. 96774 1568. 28863 1636. 41101

9540. 74534 9563. 03782 9614. 6958 9665. 44878 9715. 35964 9764. 48226 9812. 8832 10185 .2908 10372 .8961 10672 .4416 11004 .7021 11249 .0488

1.000 01789 1.017 65764 1.062 57916 1.113 06619 1.170 00941 1.234 41604 1.307 39782 2.322 2036 3.142 76674 4.687 44677 6.576 83534 8.039 22878

0.403 82497 0.403 7777 0.403 79565 0.404 05835 0.404 65634 0.405 69549 0.407 29732 0.456 72114 0.513 45347 0.634 43005 0.793 8001 0.921 78643

2.476 36465 2.520 34139 2.631 47747 2.754 71646 2.891 36558 3.042 71573 3.209 93478 5.084 51088 6.120 84041 7.388 43748 8.285 2539 8.721 3573

57171 .7168 58.32 08601 17.65 84486 10.52 23936 7.561 72951 5.948 55879 4.940 30002 2.596 98851 2.521 98823 3.006 64496 5.028 97593 12.92 75655

Refer encia p/graf icar 0.999 97 0.971 236 0.905 008 0.840 529 0.777 868 0.717 135 0.658 485 0.291 227 0.185 047 0.090 197 0.035 656 0.010 989

93.02 31

2117. 99605

584.9 96177

0.000 001

2.463 04177

1

585.0 00809

8.253E -07

8.917 4E-06

1674. 13546

11392 .1249

8.917 44534

0.999 99208

8.917 51594

12630 3.366

0.000 001