Prof. Mathuresh N. Jayaswal

Dr. Mathuresh Narayan Jayaswal Professor and Head, Department of Applied Chemistry, B S A Institute of Technology & Management, Alampur, Sohna Road, Faridabad, 121 004, Haryana, India. Phone: 09818932208, E-mail: [email protected] Address for correspondence: Plot No. 2120, First Floor, PLF, Sainik Colony, Sec. 49, Faridabad, 121 004 Haryana, India. Field of Interest Coordination Chemistry, Organometallic Chemistry, Inorganic Chemistry, Nano Chemistry/ Nano materials, Nuclear Decontamination, and Developing new chemicals and materials.

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SYNOPSIS More than fifteen experience in leading multidisciplinary R & D Project, process optimization and lab practices including supervising other researchers. Proficient in analyzing and interpreting research results and technical data. Deft at identifying potential in the design phase of the project, troubleshoot and solve problems associated with the process. Proven track record of participating in various research projects with real-time experience in planning, execution, and application of methodologies, documentation and presentation of findings. Successfully completed various projects such as “Decontamination technology development for nuclear research facilities”, “Synthesis of Nanophosphor by reverse micelle techniques”, “Synthesis of gold and silver complexes with mono and di-substituted ferrocenyl amine ligands” etc. Detail oriented with an analytical bent of mind and a positive attitude. Employment History

BSA Institute of Technology & Management, Faridabad, Haryana, India

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Dec’ 08-Continue

Assistant Professor

July 08-Nov’ 08

Head, Department of Applied Chemistry.

Shri Balwant Institute of Technology, Sonepat, Haryana, India

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Professor

Head, Department of Applied Science and Humanities, Academics and Exam Controller.

Amity School of Engineering & Technology, Lecturer Amity University, Uttar Pradesh, India  Involved in Teaching for B. Tech. and M. Tech (Nanotechnology).

Sep’07-July 08

Decontamination & Decommissioning, Visiting Scientist Korea Atomic Energy Research Institute, South Korea  Involved in Decontamination Technology Development for nuclear research facilities.

Oct’04-Sep’06

Luminescent Materials & Devices Group, Guest Researcher Apr’04-Sep’04 National Physical Laboratory, India  Developed the nano phosphors by Reverse Micelles Technique to enhance the Luminescence Properties. Department of Chemistry, Research Scientist Korea Advanced Institute of Science & Technology, South Korea

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Mar’03- Feb’04

Developed the economic procedure to get the high surface and quality of alkoxylation catalyst as a Nano material for narrow range ethoxylation reaction.

Departmento de Química Inorgánica, Post Doctoral Fellow Nov’01- Oct’02 Universidad de Zaragoza, Spain  Synthesis of gold and silver complexes with mono and di-substituted ferrocenyl amine ligands. Laboratoire de Chimie, Post Doctoral Fellow Universite de Franche-Comté, France.  TTF as assembling ligand for the construction of bimetallic transition metal complex.

Nov’00- Oct’01

Department of Chemistry, Kyungpook National University, South Korea.  Physico-chemical studies on multinuclear symmetrical thio-Schiff bases.

Aug’ 98- Jul’00

Post Doctoral Fellow biologically

important

transition

metal

complexes

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Subject Taught Chemical bonding, Organic Mechanism, Instrumental Methods for Analysis, Thermodynamics, Chemical Equilibrium, Phase rule, Water and its treatment, Lubrication and Lubricants, Fuel, Polymers and polymerization, Analytical Methods and Corrosion, Theory and Practical at B. Tech-I year level and Organometallic Reactions, Heterocyclic compounds, Role of Organometallic Chemistry in Catalyst, Metallic carbonyls and metallic nitrosyls, Porhpyrins etc. for M. Tech. Students. KEY RESULT AREAS          

Developing & carrying out independent, original research projects. Planning & conducting the work programme for own research contribution, using methodologies and techniques appropriate to the type of research. Reading published papers for the purpose of understanding the research area and perceiving where new contributions should be made. Participating in planning and strategy meetings along with re search heads and research teams. Writing scientific reports and papers for journals based on observations and experiments. Managing laboratory teams and responsible for environment Health and Safety standards. Determining the specifications and finding the economic source of raw materials. Experience in synthesis and characterization of organometallic, nano compounds/ precursors/ catalysts. Handling air sensitive materials with Schlenk-line and glove box technique. Designing and fabricating the new instruments for decontamination to nuclear facilities.

ACADEMIA Research Associate

Research Associate Post Doctoral Research

Dep. of Chemistry, I. I.T. Roorkee, Roorkee, India.

1998

Dep. of Chemistry, University of Pune, Pune, India. Dep. of Chemistry, R. D. University, Jabalpur, India.

1996 1995

Ph. D. /Applied Chemistry

Dep. of Chemistry, R. D. University, Jabalpur, India.

1994

M. Sc. /Organic Chemistry

Dep. of Chemistry, R. D. University, Jabalpur, India.

1991

B. Sc. /Bio-Sciences

Govt. Model Science Collage, R. D. University, Jabalpur, India.

1989

FELLOWSHIP AVAILED

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Brain-Pool Fellowship, Korea, from Oct’ 04 for 2 years. Post Doctoral Fellowship of BK21, Korea, started from Mar’ 03 for 1 year. Post doctoral fellowship of the Spanish Government, Spain, from Nov’ 01 for 1 year Post doctoral fellowship of the French Government, France from Nov’ 00 for 1 year. KNU-Post doctoral fellowship of Taegu, KOREA, from Aug’ 00 for 2 years. Research Associate-CSIR, India, started from Feb’ 96 for 2 years. AFFILIATIONS Life Member of Indian Council of Chemists. Membership No. 447. Life Member of Indian Science Congress. Membership No. 7049. Member of American Chemical Society. Membership No. 2280943. Member of Institution of Chemists. India, Membership No. 4442. Member of South African Chemical Society, Membership No.6037. Member of Korean Chemical Society. Membership No. S-19980825.

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Member of Rasayan Journal of Chemistry.

OTHER ASSIGNMENTS    

Worked as a Residential Warden for second year hostel (Kautley Bhawan) at Roorkee University. Served as an Exam Inspector to conduct the examination of R. D. University, Jabalpur for 4 years. Participated in several sports and cultural activities and NCC training at college and university level. Learned Korean traditional Martial Arts - HAPKIDO. PUBLICATIONS

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Development of instrument for the removal of hot particulate from the contaminated PFC solution. G-N Kim, Mathuresh Narayan, W-K Choi, C-H Jung, Journal of Membrane Science (Communicated). The development and performance evaluation of a cyclone train for the removal of hot particulate contaminated in a hot cell. G-N Kim, Mathuresh Narayan, W-K Choi, C-H Jung, Separation and Purification Technology (Communicated). Synthesis of gold and silver complexes with mono and di-substituted ferrocenyl amine ligands. Mathuresh N. Jayaswal, M Concepcion Gimeno, Antonio Laguna, Eur. J. Inorg. Chem (Manuscript under revision). The characterization of hot particulate and construction of cyclone-filter train for hot cell decontamination. G-N Kim, Mathuresh Narayan, C-H Jung, W-Z Oh. Journal of Ind. Eng. Chem. (2007) (Accepted). Photoluminescence shifts in silver-doped nanocrystalline Cd1−xZnxS. N. Karar, Mathuresh Jayaswal, S.K. Halder, Harish Chander. Journal of Alloys & Compounds. (2006). Separation of hot particulate from PFC decontamination solution for reuse by filtration equipment. G-N Kim, Mathuresh Narayan, H-J Won, W-K Choi, and C-H Jung. Journal of Industrial and Engineering Chemistry, 12, 4, 531-538 (2006). Synthesis of tetra-silylated tetrathiafulvalene derivatives TTF (SiR2H)4 (R = Me, Ph) novel assembling ligands for the construction of bimetallic transition metal complexes. F. Guyon, Mathuresh N. Jayaswal, H. N. Peindy, G. Herlem, M. Knorr, N. Avarvari, Synthetic Metals, Vol. 151, 3, 186-190 (2005). Novel bonding modes between tetrathiafulvalenes(TTFs) and transition metal centers: π-bonding and covalent TTFSiMe2-MLn coordination on platinum. Mathuresh N. Jayaswal, H.N. Peindy, F. Guyon, M. Knorr, M. Fourmigué, N. Avavari, European Journal of Inorganic Chemistry (2004) 2646-2651. Synthesis, magnetic and spectral studies of some novel lanthanum(III) chelates of potentially bi- and tetra-dentate pyrazolone based Schiff bases. R. C. Maurya, and Mathuresh N. Jayaswal, Univ. Journal, R. D. University, Jbp. India (1999) Spectral and thermogravimetric studies of some peroxo complexes of dioxomolybdenum(VI) and tungsten(VI). M. R. Maurya and Mathuresh N. Jayaswal, Journal of Chemical Research(S), (1998) 446-447. The coordination chemistry of dioxouranium (VI): Studies of some novel bi- and tri-nuclear dioxouranium(VI) complexes with pyrazolone based Schiff bases. R. C. Maurya, M. N. Jayaswal, R. Verma and P. Shukla, Synth. React. Inorg. Met-Org. Chem., 28, 1265 (1998). Dioxomolybdenum (VI) and dioxotungsten (VI) complexes of isomeric ONO donor ligands and the X-ray crystal structure of [MoO2(o-C6H4CH=NCH2C6H4O)(MeOH)]2.MeOH. M. R. Maurya, Mathuresh N. Jayaswal, V. G. Puranic, P. Chakraborty, S. Gopinathan and C. Gopinathan; POLYHEDRON, 16, (1997) 3977-3983. Dioxomolybdenum(VI) complexes of bidentate and tetradentate Schiff bases derived from 3-methyl-1phenyl-4-propionyl-5-pyrazolin-5-one and certain aromatic amines. R. C. Maurya, M. N. Jayaswal and R. Verma, Indian Journal of Chemistry Sec. A, 36A (1997) 406. Synthesis and spectral studies of novel dioxomolybdenum(VI) heterochelates involving some Schiff bases derived from 4-acetyl-3-methyl-1-phenyl-5- pyrazolin-5-one. R. C. Maurya, D. D. Mishra, M. N. Jayaswal and Suman Kovil. Synth. React. Inorg. Met-Org. Chem., 27(1), 77 (1997). Synthesis and physico-chemical studies of some of novel UO2(VI) complexes with pyrazolone based Schiff bases. R. C. Maurya, and M. N. Jayaswal; Proc. Nuclear and RADIOCHEMISTRY, Calcutta, India, 1997. Synthesis and characterization of cis-dioxomolybdenum(VI) Schiff bases complexes derived from 1-phenyl– 3-methyl-4-benzoyl-5-pyrazolone. N. S. Rao, M. N. Jayaswal, D. D. Mishra, R. C. Maurya and N. Nageswara Rao, POLYHEDRON; 12, (1993) 2045-2050. Synthesis and characterization of some mixed ligand complexes of copper(II), cobalt(II) with Schiff bases and heterocyclic organic compounds. R. C. Maurya, D. D. Mishra, S. Jain and M. Jayaswal, Synth.React.Inorg.Met-Org.Chem, 23, 1335 (1993).

PRESENTATIONS DELIVERED   

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Golden Jubilee Work Shop on KAERI Achievements, June 21-23, 06, COEX, Seoul, South Korea. Annual Meeting of the Korea Radioactive Waste Society, Apr’ 20-21, 06, Seoul, South Korea. Korea-China Joint Symposium on Radio waste management, Nov’ 17-18, 05, Kongju, South Korea. Symposium on Radio waste Disposal & Decontamination & Decommissioning, Oct’ 28-30, 05, S. Korea. Annual Meeting of the Korea Radioactive Waste Society, Apr’ 23-24, 05, Kwangju, South Korea. Symposium on Radio waste Disposal & Decontamination & Decommissioning, Oct’ 26-28, 04, S Korea. 92nd Annual Meeting of the Korean Chemical Society, Oct’ 16-17, 03, BEXCO, Pusan, South Korea. 91st Annual Meeting of the Korean Chemical Society, Apr’ 18-19, 03, COEX, Seoul, South Korea. Meeting of Korean Inorganic Chemistry, Aug’ 21-23, 2000. Pusan National Univ., Pusan, South Korea. 85th Annual Meeting of the Korean Chemical Society, Apr’ 20-22, 2000, Kookmin Univ., Seoul, South Korea. 9th Korea-Japan Joint Symposium on Organomet. & Coordina. Chem., Nov’17-20, 99, KIST, South Korea. 83rd Annual Meeting of the Korean Chemical Society, Apr’ 23-24, 99, Kyung Hee Univ., Seoul, Korea. 1st Korea-Italy Joint Symposium on Inorganic Chemistry, Nov’ 26-27, 98, Yonsei Univ., Seoul, South Korea. Symposium on Recent Trends Instrumental Techniques, Sep’ 18-20, 97, Univ. of Roorkee, Roorkee, India. 33rd Annual Convention of Chemist, Dec’ 26-28, 96, PSG College of Technology, Coimbotore, India. 11th Young Scientist Congress MPCST, 28 Feb’-02 Mar’ 96, Rani Durgawati Univ., Jabalpur, India. PERSONAL DETAILS Date of Birth Nationality Passport No. Civil Status

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8th July, 1968 Indian G 4801595 Married References

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Dr. Jung Chong-Hun, Director, Decontamination & Decommissioning R & D Project, Korea Atomic Energy Research Institute, Daejeon, 305600, South Korea. Fax: +82 42 864 0355, E.mail: [email protected] Tel: 82 42 868 8595.

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Dr. Harish Chander, Sc.F, Electronics and Materials Division, National Physical Laboratory, New Delhi-12, INDIA. Fax: +91 11 25726938, E.mail: [email protected] Tel: +91 11 25742610 ext. 2268.

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Prof. Joon Taik Park, Department of Chemistry, Korea Advanced Institute of Science and Technology, Taejon, 305-701, KOREA. Fax: +82-42-869-2810, E-mail: [email protected] Tel: +82-42-869-2826.

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Prof. Antonio Laguna, Departamento de Química Inorgánica - I.C.M.A. Universidad de Zaragoza, CSIC. E50009 Zaragoza, SPAIN. Fax: +34 976 761 187, E-mail : [email protected] Tel. +34 976 761 185.

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Prof. Michael Knorr, Labratoire de Chimie des Matériaux et Interfaces, Université de Franche-Comté, 25030, Besançon, FRANCE. Fax: +33 381 666 438, E-mail : [email protected] Tel. +33 381 666 270.

Annexure RESEARCH EXPERIENCE (As a Scientist) Title Place

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Decontamination technology development for nuclear research facilities. KAERI, Daejeon, South Korea

Since energy demand in the world has been increasing rapidly but gradually minimizing the resources of gas and oil and burning issues the increasing global efforts to reduce CO2 emission from all energy sectors, nuclear energy is becoming a vital to the welfare of the society and potential for an industrial growth tools for all the nations. However, nuclear industry has been expanded; the demand for nuclear fuel cycle service has continuously increased. After installation of nuclear facilities there has been a problem with decontamination technologies to cleanup hot particulate from the hot cell by easiest and economical way, cause a strong impetus to develop new ideas. Although, there are several ways and some instruments are available for this purpose but due to their peculiar design, size and other characteristic limitations, are not fit to remove the hot particulate from hot cell at Korea Atomic Energy Research Institute. More stringent environmental regulations

require improved hot particulates collection efficiency in nuclear hot cell creating a need for further research aimed to enrich the decontamination technology, especially for sub micron size fine or smaller particles. The project involved designing and fabricating new equipments. Filtered 2 new equipments including cyclone to collect the smaller size hot particulate & developed PFC filtration equipment to separate the fine particles from contaminated PFC solution to reuse for next and reduce the secondary waste.

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Synthesis of Nanophosphor by reverse micelle techniques. NPL, New Delhi, India

Nano phosphors are a new class of luminescent materials/semi conducting nano crystals, have great interest due to new and unusual structural, electronic and optical properties. Luminescent nano granular ZnS and CdS are more optically efficient with respect to similar bulk samples. Hence they are replacement materials in applications such as optical hetero-structures, solid-state solar window layers, photo conductors, field effect transistors, optical sensors, electro luminescent materials and other light emitting materials. The change of properties in silver-doped nano-granular cubic Cd1−xZnxS with different percentages of Cd (up to 40%) prepared by Reverse micelle method has been discussed. There was a strong modification of photoluminescence (PL) spectra and systematic PL peak shift with change of Cd concentration. The PL was attributed to transitions to silver from defect and other donor levels. Cd alloying variation in Cd 1−xZnxS and a related band structure change led to a shift in relative positions of the donor and acceptor levels and a consequent systematic change in the observed PL emission wavelength.

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Development of novel Nano Catalysts for Narrow Range Ethoxylation (NRE). KAIST, Daejeon, South Korea

An industrial project collaborated with Honnam Petro Chemical, Korea. Alcohol ethoxylates are most important non-ionic surfactants. The ethoxylation can be achieved by the reaction of an alcohol and ethylene oxide. Reaction can be influenced by the catalyst and by choice of the alkyl group of the alcohol too. When phenol or alkyl phenol is ethoxylated the ethoxylation distribution is narrow compared to the broad distribution curve obtained with the fatty alcohols, such as C 9-11 alcohol. By using the special catalyst a narrow distribution similar to that observed with phenols can be achieved for fatty alcohols. Generally, lower degree of ethoxylation gives higher amounts of free alcohol in the product. However, an object of the present study to provide an alkoxylation catalyst for producing an alkylene oxide adduct having a narrow alkylene oxide adduct distribution with only small amounts of unreacted material and by products. OTHER PROJECTS HANDLED (Post Doctoral work) Title Place

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Synthesis of gold and silver complexes with mono and di-substituted ferrocenyl amine ligands. Univ. of Zaragoza, Zaragoza, Spain

Ferrocene is a versatile building block for the synthesis of various ligands and metal complexes having different chemical and physical properties. Very important features are flexible of the bidentate ligands, permits the formation of gold(I) and gold(III) complexes with a number of different structural frameworks. Ferrocene derivatives can act as bridging ligands in di- or poly-nuclear derivatives, as chelating agents, through a new type of η2-interaction between the metal center and the cyclopentadienyl ring. Gold chemistry is currently attracting growing interest, due to their novel structures of the gold complexes and potential applications. Their potential use as anti-tumor agents is being investigated.

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TTF as assembling ligand for the construction of bimetallic transition metal complex. Univ. of French-Comte, Besancon, France

√ Two novel strategies for coordinating TTF to transition metal centers have been developed. The reaction of tetrathiafulvalene (TTF) or 3,4-dimethyltetrathiafulvalene (o-Me2TTF) with [Pt(η2-C2H4)(PPh3)2] leads to the Л complexes [Pt(η2-TTF)(PPh3)2] (1) and [Pt(η2-o-Me2TTF)(PPh3)2] (2), respectively. An X-ray crystallographic study performed on 2 confirmed that TTFs act as a Л acidic ligand. NMR studies revealed the existence, in solution, of equilibrium between free and complexed TTF. Dilithiation of o-Me2TTF and subsequent silylation with ClSiMe2H afforded 3,4-dimethyl- 3’,4’-(dimethylsilyl)tetrathiafulvalene (3), which has been structurally characterized. 3 reacts by oxidative addition across [Pt(η2-C2H4)(PPh3)2] to give [Pt{η2-o-(SiMe2)2TTFMe2}(PPh3)2] (4), in which the TTF ligand is covalently ligated to platinum via SiMe 2 bridges. The redox properties of 3 and 4 have been investigated by cyclic voltammetry. Strong cathodic shifts of the two redox processes were observed for 4, implying the TTF core. √ The HR2Si-functionalized tetrathiafulvalene (TTF) ligand TTF(SiR2H)4 (R=Me a; R=Ph b) have been synthesized and the molecular structure of a determined. The reactivity of the four Si–H bonds for oxidative addition reactions has been exploited. Thus, the bimetallic platinum–silicon complex [(PPh3)2Pt{(Me2Si)2TTF(SiMe2)2}Pt(PPh3)2] 3 incorporating TTF(SiMe2H)4 as bridging unit has been assembled by

oxidative addition across [Pt(PPh3)2(CH2=CH2)]. Electrochemical investigations by means of cyclic voltammetry reveals, for the complex 3, a strong cathodic shift of the two redox processes of the TTF core compared with those of a.

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Physico-chemical studies on multinuclear biologically important transition metal complexes with symmetrical thio-Schiff bases. Kyungpook National University, Taegu, South Korea

In the series of transition metals the molybdenum is versatile; it possesses a large number of stable and accessible oxidation states. Several chemical reactions are catalyzed by molybdenum coordination complexes. The biochemistry of molybdenum has remained for the most part obscure. Recently, there has been interest in the coordination chemistry of molybdenum in view of its special structure and biological effects. While awareness were of the occurrence of molybdenum in biological system to enhanced understandings of structures and their functional mechanistic properties.

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Ligand controlled the synthesis of tungsten complexes, their reactivity and catalytic properties. Pune University and IIT Roorkee, India

√ Dioxomolybdenum(VI) and dioxotungsten(VI) complexes of two isomeric Schiff bases derived from salicylaldehyde, 2-hydroxy-l-naphthaldehyde and o-hydroxybenzylamine or o-aminobenzylalcohol have been prepared and characterized. ~H NMR spectral data confirm the formation of [MO 2L] (M = Mo or W, LH 2 = ligand) types of complexes except the complex of dioxomolybdenum(VI) with the ligand salicylaldehyde- ohydroxybenzylamine (H2sal-OHYBA) which forms [MoO2(sal-OHYBA) • CH3OH]. An X-ray study of [MoO2(salOHYBA)" CH3OH] shows the presence of distorted octahedral geometry around molybdenum in which the tridentate ligand occupies meridional position where two anionic oxygens are mutually trans and are cis to the cis dioxo group. Generally the tungsten complex is more stable to decomposition than the molybdenum one within the same ligand. √ Molybdenum and tungsten are biologically important metals, the various aspects of the chemistry of molybdenum(VI) and tungsten(VI) peroxo complexes with organic ligands have been of considerable interest. These complexes serve as reactive intermediates in the catalytic oxidation of organic substrates. They are also important in biological processes involving oxidation or conversion of dioxygen species.4 In addition; these complexes have also been used as potential precursors for molybdenum and tungsten complexes in various oxidation states. Synthesis, spectral and thermal studies of diperoxo complexes of molybdenum(VI) and tungsten(VI) with 2-(2-pyridyl)-benzimidazole, 2-(3-pyridyl)benzimidazole and 2,6-bis(benzimidazol-2yl)pyridine are reported.

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Synthesis and physico-chemical studies of some coordination compounds with Schiff bases. R. D. University, Jabalpur, India.

Synthesis and characterization of new dioxomolybdenum(VI), dioxouranium(VI) and lanthanum(III) chelates with some Schiff bases derived from 5-pyrazolone derivatives viz., Acetyl-, Benzoyl-, Propionyl- or Nitrobenzoyl- chloride with certain amines, viz., o-, m-, p-anisidine/ phenetidine/ toluidine/ phenylenediamine and benzidine.The physical and chemical properties of these complexes were evaluated using different analytical techniques like elemental analysis, IR-, UV-Vis- and NMR- spectroscopy, electrical conductivity, TGA, cyclic voltammetry and magnetic susceptibility. Followed different synthetic routes such as: ligand exchange reaction method, metal exchange reaction method, amine exchange reaction method, in-situ method, direct synthesis method, oxidation of coordinated secondary amine, etc.

(Dr. Mathuresh Narayan Jayaswal)