ORGANIC CHEMISTRY
TARGET : JEE (Main + Advanced) 2016 NO. 31
Course : VIJETA (JP)
This DPP is to be discussed in the week (05-10-2015 to 10-10-2015)
DPP No. # 31 (JEE-MAIN) Total Marks : 60
Max. Time : 40 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.20
(3 marks, 2 min.)
[60, 40]
(D) (C) (D)
7. 14.
ANSWER KEY DPP No. # 31 (JEE-MAIN) 1. 8. 15.
(C) (B) (C)
2. 9. 16.
(C) (B) (A)
1.
The reagent ‘A’ for the following reaction would be fuEufyf[kr vfHkfØ;k esa vfHkdeZd 'A' gS %
O || (A) CH3 – C – OC 2H5
3. 10. 17.
(B) (C) (C)
4. 11. 18.
(C) (B) (D)
(B) CH3CHO
5. 12. 19.
6. 13. 20.
(C*) HCHO
(C) (B) (B)
(B) (B)
(D)
Sol.
2.
The correct statement about the following reaction is :
(A) The product is a dicarboxylic acid. (B) The product is an -keto acid. (C*) The product is a racemic mixture of -hydroxy acids. (D) The product is a mixture of two aromatic acids. Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005 Website : www.resonance.ac.in | E-mail :
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PAGE NO.- 1
fuEu vfHkfØ;k ds fy;s lgh dFku dkSulk gSA
(A) mRikn ,d f} dkcksZfDlfyd vEy gSA (C*) mRikn ,d -gkbMªksDlh vEy dk jsflfed
(B) mRikn (D) mRikn
feJ.k gSA
,d -fdVks vEy gSA nks ,jkseSfVd vEyksa dk feJ.k gSA
Sol.
It is Benzil-benzilic acid rearrangement reaction.
;g ,d csfUty&csUtkbfyd vEy iqUkfoZU;kl vfHkfØ;k gSA
(1) Ac O,AcONa
2 (A), Identify product (mRikn (2) H O
3.
2
(A)
4.
(B*)
dks igpkfu;s)
(C)
(D)
In the following conversion, (i) MeMgBr
NaOH / I
2 X Y (ii) H3O
H3O
the major products X and Y, respectively, are :
(A)
(B)
(C*)
(D)
fn;s x, ifjorZu esa eq[; mRikn (i) MeMgBr
NaOH / I
(ii) H3O
H3O
2 X Y
X
rFkk
(A)
Y Øe'k%
gS %
(B)
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PAGE NO.- 2
(C*)
(D)
Sol.
5.
Find the suitable reagents of the following reaction
fuEufyf[kr vfHkfØ;k esa mi;qDr vfHkdeZd gS %
(A) PhCHO / NaOH, LiAlH4 (C) CrO3 / H
; Al
(B) CrO3 /
O3 ; HBr / R2O2 ; PhCH2MgBr
2
, LiAlH4
(D*) PhCHO / NaOH, N 2H4 / KOH,
Sol.
6.
–
OH (A)
+ Product (A) is : mRikn (A) gS %
(A)
7.
(B)
(C*)
(D)
The product/s of the following reaction is
fuEufyf[kr vfHkfØ;k esa izkIr mRikn fuEu esa ls gksxk ?
PhCO H
3
Sol.
(A)
(B*)
(C)
(D)
(B) This is Baeyer Villiger oxidation and the methyl group is the weakest migrating group.
;g cs;j foyhtj vkDlhdj.k vfHkfØ;k gS vkSj esfFky lewg nqcZyre LFkkukUrfjr lewg gksrk gSA Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005 Website : www.resonance.ac.in | E-mail :
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PAGE NO.- 3
PhCO H
3
8.
The following product is obtained by using reactant/s ....... in a base catalysed condensation reaction {kkj mRizsjfd; la?kuu vfHkfØ;k esa fuEu mRikn dks izkIr djus ds fy, .......... vfHkdeZd dk mi;ksx djrs gSA
(A)
+
(C)
(B*)
+
(D)
+
Sol. The is a self claisen condensation reaction.
;g Loa; Dsystu la?kuu vfHkfØ;k gSA 9.
Above conversion can be carried out by :
mijksDr vUr%ifjorZu fdlds }kjk gksrk gS % (A) LiAlH4, H+, (C) (i) H+, (ii) OH–
10.
(B*) (i) OH– (conc.) (lkUæ), (ii) H + (D) (i) NaBH4 (ii) H+
CO HCl
P Anhydrous AlCl3
H3O Q R S.
Which is not true about above sequence of reaction. (A) Product R and S reacts with NaHCO3 solution with effervescence of CO2 gas. (B) P when reacts with NaCN and H2SO4, gives two optically active resolvable product. (C*) Q is formed by nucleophilic substitution reaction on P. (D) S is formed by evolution of H2O and CO2 from R. CO HCl
AlCl3
P
H3O Q R S.
mijksDr vfHkfØ;k ds lanHkZ esa dkSulk dFku xyr gSA (A) mRikn R rFkk S NaHCO3 foy;u ds lkFk fØ;k dj CO2 xSl nsxsaA (B) tc P dh NaCN ,oa H2SO4 ds lkFk fØ;k dh tkrh gS] rks nks izdkf'kd lfØ; i`FkDdj.kh; mRikn izkIr gksrs gSA (C*) mRikn Q, ;kSfxd P ij ukfHkdLusgh izfrLFkkiu vfHkfØ;k }kjk izkIr gksrk gSA (D) mRikn S, ;kSfxd R ls H2O rFkk CO2 ds fu"dklu ls izkIr gksrk gSA
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PAGE NO.- 4
CO HCl
CO HCl
Sol.
Anhydrous AlCl3
AlCl3
Ph CH CH COOH Ph CH CH COOH
Cinnamic Acid
11.
+ 2C2H5OH
–H2O – CO2
The product of following reaction is :
fuEu vfHkfØ;k dk mRikn gS& AC 2 O / ACONa / AC2O / ACONa / (Product) (mRikn) ( excess )
Sol.
(
(A)
(B*)
(C)
(D)
)
It is perkin reaction.
;g ifdZy vfHkfØ;k gSA
12. The compound (S) is : ;kSfxd (S) gSa %
(A)
(B)
(C*)
(D)
Sol.
13.
Which of the following compound on reaction with O3/Zn, H2O followed by aq. NaOH/ will form
fuEu esa ls dkSulk ;kSfxd O3/Zn, H2O ls fØ;k djkus ds i'pkr~ NaOH/ ls fØ;k djkus ij
(A)
(B*)
(C)
cukrk gSA
(D)
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PAGE NO.- 5
O3 / Zn
Sol.
14.
+ (C6H5)3P = CH2 product (mRikn )
(A) Sol.
OH
(B*)
(C)
(D)
It is witting reactions.
;g fofVZx vfHkfØ;k gSA 15.
An aldehyde X (C11H10O), which does not undergo self aldol condensation, gives benzaldehyde and two moles of Y on ozonolysis. compound Y, on oxidation with silver ion gives oxalic acid. The compounds X and Y, are respectively : ,d ,fYMgkbM X (C11H10O), tks Lor% ,YMksy la?kuu ugha n'kkZrk ysfdu vkstksuh vi?kVu ij csUtSfYMgkbM vkSj nks eksy Y nsrk gSA ;kSfxd Y, flYoj vk;u ds lkFk vkWDlhdj.k ij vkWDtSfyd vEy nsrk gSA ;kSfxd X o Y Øe'k% gS %
(A)
(B)
(C*)
(D)
Sol.
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PAGE NO.- 6
16.
1–Ethylcyclopent–1–ene on reductive ozonolysis followed by aq. NaOH/ gives 1–,fFkylkbDyksisUV–1–bZu dk vipk;d vkstksuhvi?kVu djus ds i'pkr~ tyh; NaOH/ ls
(A*)
O / Zn
Sol.
17.
(B)
3
(C)
fØ;k djus ij nsrk gSA
(D)
(i ) H
OH
(ii)
Compound ‘A’ (molecular formula C4H10O) is treated with KMnO 4 solution to form product ‘B’ (molecular formula C4H8O). B does not form shining silver mirror on warming with amonical AgNO 3 . When B is reacted with 2,-4 DNP, yellow precipitate of C is obtained. Identify the structure of C. ;kSfxd ‘A’ (v.kqlw=k C4H10O) KMnO4 foy;u ds lkFk vfHkd`r djus ij mRikn ‘B’ (v.kqlw=k C4H8O) cukrk gSA B veksfud`r AgNO3 ds lkFk xeZ djus ij pedhyk jtr niZ.k ugha nsrk gSA tc ;kSfxd B dks 2,-4 DNP ds lkFk vfHkd`r fd;k tkrk gS ] rks ihyk vo{ksi C izkIr gksrk gSA C dh lajpuk gS %
(A) CH3CH2CH2CH = N.
(B)
(C*)
(D)
1. . NaOH / 1 . dil NaOH / Final product is :
18.
vafre mRikn gSA
(A)
Sol.
(B)
(C)
(D*)
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PAGE NO.- 7
H / Ni
NaNO2 / HCl / H2 O KCN / H (W) 2
19.
The compound W is ;kSfxd (W) gS
(A)
(B)
(C)
(D*)
Sol.
20.
(1) Zn (B) PhCHO + BrCH2CO2 Et ( 2) HO (A) ( H O) 2
Product of (B) of the above reaction is : mijksDr vfHkfØ;k esa mRikn (B) gksxk % (A) Ph – CH = CH – CH3 (C) Ph – CH = CH – CH2 – OH
2
(B*) Ph – CH = CH – CO 2Et (D) Ph – CH = CH – CH3
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PAGE NO.- 8