Chevron Ron95 Media Workshop Presentation

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Downstream Technology

RON95 Media M di Workshop W k h

Greg Engeler Product Engineering Manager, Asia-Pacific June 2009

© Chevron 2009

Contents:  What is Octane Number?  Octane grade d d differences ff  Product stewardship p  Caltex with Techron  Technology advances and future fuels

© Chevron 2009

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Introduction When most drivers think about petrol, it is to remember to fill up and maybe to check the price. Since petrol almost always y performs p well,, drivers forget g what a sophisticated p product it really is. More thought would reveal a demanding set of performance expectations: p  An engine that starts easily when cold, warms up rapidly, and

runs smoothly under all conditions.

 An engine that delivers adequate power without knocking. knocking  A vehicle that provides good fuel economy and generates low

emissions.

 petrol that does not add to engine deposits or contaminate or

corrode the fuel system.

Although proper vehicle design and maintenance are necessary, petrol plays an important role in meeting these expectations. © Chevron 2009

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Volatility Driveability describes how an engine starts, warms up and runs. It is the assessment of a vehicle’s response to the accelerator relative to what the driver expects. accelerator, expects Driveability problems include: hard starting, backfiring, rough idle, poor throttle response and stalling.  The key petrol characteristic for good driveability is volatility

– the petrol’s tendency to vaporize.  Volatility is important because liquids and solids don’t don t burn;

only vapors burn. In cold weather, petrol is blended to vaporize easily. This allows an engine to start quickly and run smoothly until it is warm.  In warm weather, petrol is blended to vaporize less easily in

the vehicle to prevent vapor lock or other hot-fuel handling problems p ob e s and a d minimize e evaporation, e apo at o , which c contributes co t butes to air a pollution. © Chevron 2009

Starts easily, warms up rapidly, runs smoothly

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The correct distillation profile is achieved by blending at the refinery Petrol is a mixture of hundreds of hydrocarbons, many of which have different boiling points. Thus petrol boils over a range of temperatures, unlike a pure compound e.g. water, that boils at a single temperature.

Front-end volatility is adjusted to provide: 

easy cold starting



easy hot starting



freedom from vapor lock



low evaporation and running-loss emissions

Midrange volatility is adjusted to provide: 

rapid warm-up and smooth running



good short-trip fuel economy



good power and acceleration



protection against carburetor icing and hot stalling

Tail-end volatility is adjusted to provide:

© Chevron 2009



good fuel economy after engine warm-up



f freedom d from f engine i deposits d it



minimal fuel dilution of crankcase oil



minimal volatile organic compound (VOC) exhaust emissions

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Anti-knock performance Knock-free engine performance is as important as good driveability.  Octane number is a measure of a petrol’s antiknock

performance – its ability to resist knocking as it burns in the combustion chamber.  There are two laboratory test methods to measure the octane

number of a petrol. One yields the Research octane number (RON); the other, the Motor octane number (MON).  RON correlates best with low speed, mild-knocking

conditions; MON correlates best with high speed and hightemperature knocking conditions and with part-throttle operation.  For a given petrol, RON is always greater than MON. The

d e e ce between difference bet ee the t e two t o is s called ca ed the t e se sensitivity s t ty o of the t e petrol. © Chevron 2009

Delivers adequate power without knocking

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Knocking or pinging is the sound of abnormal combustion  Normal combustion in a spark-ignition internal combustion engine is

initiated by a spark.

 The flame front fans out from the spark p p plug g and travels across the

combustion chamber rapidly and smoothly until almost all the fuel is consumed.

 When combustion is abnormal, the last part of the unburned mixture

ignites spontaneously and burns very rapidly rapidly, causing the pressure in the cylinder to rise rapidly. This creates the characteristic knocking sound.

 Occasional light knocking doesn’t hurt an engine.  Heavy y or prolonged p g knocking g can result in:

• • • • •

Objectionable noise Loss of power Overheating of engine parts Knock-induced surface ignition Engine damage

Knock occurs because the petrol’s octane number is below the antiknock requirement of the engine at that moment. Generally, the situation involves high-load conditions, like hard acceleration or climbing a grade. © Chevron 2009

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© Chevron 2009

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Octane satisfaction curves  In many countries programs

Octane Satisfaction Curve (1993, 128 vehicles) 98

103

97

102

96

101

95

100

94

99

Anti-Knock k Index (R+M)/2

92

US Premium

91 90 89 88 87 86

98 97 96

US Mid-grade

95 94 93 92

US Regular

91

85

90

84

89

83

88

82

87

81

86

80

85

79

84

78 83 0% 10% 20% 30% 40% 50% 60% 70% 80% 90% 100 %

Percent Satisfied © Chevron 2009

Source: Coordinating Research Council

 Laboratories’ determined the Research Octa ane NUmber (RO ON)

93

were conducted to determine octane requirement of representative car models. d l lowest octane number that would allow a vehicle to operate knock-free under standard conditions.

 This data was used to

determine d i aggregate octane satisfaction requirement for a vehicle population.

 These programs ceased with

the widespread adoption of knock sensors.

The Coordinating Research Council (CRC) is a non-profit organization. The Sustaining Members of CRC are the American Petroleum Institute (API), the Society of Automotive Engineers (SAE) and a group of automobile manufacturers (Chrysler, Ford, General Motors, Honda, Mitsubishi, Nissan, Toyota, and Volkswagen).

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95R is the main grade sold in Europe, but 91R is popular in many countries EU Fuel Sales by RON Grade

US Fuel Sales by RON Grade

75%

7%

84%

9%

15% 10%

91R

~92R ~94/95R

95R 98R

Pool average RON ~ 95.0

Japan Fuel Sales by RON Grade

Aus Fuel Sales by RON Grade

75%

85% 5%

15%

20%

89 90R 89-90R

© Chevron 2009

91R 95R

>=96R Pool average RON ~ 91.2

~97/98R

Pool average RON ~ 92.9

Pool average RON ~ 92.2

98R Downstream Technology

10

Vehicles are designed and calibrated for a certain octane value  When a customer uses petrol with an octane level lower

than that required, knocking may result  Modern engines equipped with knock sensors can

handle lower octane levels by retarding the spark timing;



however, fuel consumption, driveability and power may suffer

 Using petrol with an octane rating higher than that

recommended may not improve the vehicle’s performance.

© Chevron 2009

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EU fuel & emission standards for SI passenger cars Petrol Emission Standards (EU)

Petrol sulfur content 4

1000

800 3

Removing sulfur destroys octane g/km g

mg/kg m

600 2

400

1 200

0

0 Euro 1

Euro 2

Euro3

Euro 4

E Euro 1

CO © Chevron 2009

E Euro 2

NOx

E Euro3 3

HC+NOx

E Euro 4

HC

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Product Life Cycle Product Stewardship is a C b i Combustion comprehensive Re-process Re-blend Disposal risk Recycle management system for identifying, End understanding, User and d managing i potential SHE and Product Resellers Integrity risks of our products with everyone involved throughout the Contract Customer entire Life Cycle. © Chevron 2009

Idea

Research

Process Design

Competitors Imports

Marketing

Refining

Buy/Sell Partners Transport Marine & pipeline

Transport

Caltex trucks Third party trucks Rail

Terminals Caltex & Industry

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Product Life Cycle

Combustion C b i Re-process Re-blend

Product/Process/ Project Development Process

Idea Disposal Recycle

Process Design

Competitors Imports

End User Marketing

Product Integrity Program

Research

Refining

Suppliers

Transport

Resellers

Marine & pipeline Transport

Emissions, Recycle, Disposal © Chevron 2009

Contract Customer

Caltex trucks Third party trucks Rail

Terminals Caltex & Industry

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Product Stewardship It’s not only about Safety, Health, Environment & Risk. It’s also about delivering on the customer’s expectation of the Caltex brand…  genuine products  fit for purpose  all the time

Customers expect us to design, develop, manufacture, & deliver products that are fit for the intended application

© Chevron 2009

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The automakers challenge: Motorists expect modern vehicles must deliver:  More power  Enhanced performance  Lower emissions  Better fuel economy

The automakers achieve this through improvements in technology: gy  Turbo-charging  Variable valve timing  Electronic throttle control  Improved injector design  Advanced catalyst systems © Chevron 2009

Emission durability requirements place additional pressure on automakers Downstream Technology

16

Fuel quality is becoming increasingly important… Fuel quality can be an enabler for the introduction of new technologies:  Lower sulfur levels can enable new after-treatment

technologies (catalysts)  Higher octane fuels can enable higher compression

more fuel efficient vehicles  High h detergency d fuels f l can enable bl accurate & precise

fuel delivery to the combustion process over the life of the vehicle and so help assist the autos meet performance, fuel economy & emissions goals …without the right fuel, the engine won’t perform as well as it was designed to perform. © Chevron 2009

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High quality fuel contains effective deposit control additives “Combustion of even good quality gasoline can lead to deposit formation. Such deposits will increase engineout emissions and affect vehicle performance. High quality fuel contains deposit control additives to significantly reduce deposit formation.” Source: World-Wide Fuel Charter  European Automobile

Manufacturers Association  US Alliance of Automotive

Manufacturers  Japan Automobile

Manufacturers Association © Chevron 2009

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What is Techron ? ®

Caltex petrol contains our technologically advanced, specially formulated and patented synthetic fuel system cleaning ingredient ingredient, Techron Techron.  Techron is exclusive to Caltex, Chevron & Texaco. The

Techron formulation has evolved over almost 30 years of research & development. development  Unlike many of our competitors, the Techron ingredient is in

all grades of petrol

Caltex with Techron is unbeatable at cleaning vital engine parts in y p your car’s fuel system y so your y car and you y can perform at your best. © Chevron 2009

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Caltex with Techron is unbeatable at cleaning vital engine parts in your car’s fuel system. Fuel Injectors: Fuel injectors j are designed g to accurately meter fuel to the engine and to deliver it in a precise pattern of fine droplets. Because the fuel passages are small, small injectors and engine operation are highly sensitive to small amounts of deposits in the critical regions where the fuel is metered and atomized.

Fuel System Cut-away:

Intake Valve

Fuel Injector

Intake Valves: Intake valves are like metal doors in the engine that open and close at specific times in the combustion cycle. By opening and closing, these doors control the air and fuel mixture entering your engine. © Chevron 2009

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Fuel injector clean-up in only one tank full! Caltex with Techron cares for your car by removing injector tip deposits. In fact, only one tank full can clean fuel injectors and on-going use will maintain a clean fuel system.

with Inferior Fuel Fine spray p y burns efficiently! y

© Chevron 2009

Dirty y injector j gives g poor p combustion and delivers poor vehicle performance. Downstream Technology

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Clean intake valves are essential for efficient engine operation Caltex with Techron is unbeatable at cleaning vital engine parts in your car’s fuel system so your car can perform at its best. Deposits form on intake valves when components of the fuel, or even an improperly formulated f l additive fuel dditi package k itself, break down due to the high temperatures encountered inside your engine.

Intake valves after just 16,000 km

®

Caltex with Techron

Lower quality fuel

Your car will perform at its best when vital engine parts are kept clean. © Chevron 2009

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How does the customer benefit from the unbeatable cleaning power of Techron? Caltex with Techron is unbeatable at cleaning vital engine parts in your car’s fuel system. A great way to protect and maintain your engine’s performance is by using Caltex with Techron. The cleaning power of Techron removes performanceperformance robbing deposits, and delivers 5 key benefits:  Restores lost power and acceleration (pick-up) (pick up)  Improves fuel economy  Reduces exhaust emissions  Delivers smooth performance  Enhances E h reliability li bilit © Chevron 2009

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Benefit #1: Power and Pick-up

with Techron - the “clean-up cycle” l ” – at the h completion l off the test, 75% of the lost power had been restored due to the unbeatable cleaning power of Techron ! ®

6% powe er loss

97% 96% 95% % 94%

Dirtty-Up

 The fuel was switched to petrol

98%

% of Origiinal Power

100 hours of operation on an inferior retail petrol – this is the “dirty-up” cycle – there was a 6% power loss due to th di the dirty t valves l

99%

pow wer restored d

 The valves were subjected to

Clean-up

The unbeatable cleaning power of Caltex with Techron helps restore lost power and pick-up caused by deposit b ild build-up. 100%

93% 92% 91% 90%

Start of Test 1994 Ford Ranger

Inferior Petrol with Retail Petrol Techron

ASTM D6201 100 h cycle © Chevron 2009

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Benefit #2: Reduces exhaust emissions Caltex with Techron is unbeatable at removing performance-robbing deposits from vital engine parts.

The chart on the right shows clean intake valve give lower exhaust emissions.

Exhaust em missions, g/km

It is well known that injector blockage and intake valve deposits contribute to emissions.

Intake valve deposits increase emissions 0.25

Cleaner Emiissions

Your car will use less fuel and that's good for you and good for the environment.

0.20

0.15

0.10

0.05

Cl Cleaner V Valves l 0.00 6

7

8

9

10

Valve rating (10 = clean) Hydrocarbons

Carbon Monoxide/10

Nitrogen Oxides

Source: SAE 922259 © Chevron 2009

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Benefit #3: Enhances reliability The unbeatable cleaning power of Caltex with Techron helps keep your car healthy.

That’s why we partnered with the San Diego Yellow Cab Company to field test the unbeatable cleaning power of petrol with Techron. h

This field test logged over 130 million kilometres!

Toyota Camry 2.2L IVD Keep Clean 3 Cab Average, 80 000km

10

Intake e Valve Rating (10 = clean)

If you want to test automotive performance under “real world” conditions, it doesn’t get more real than the demands put on a taxi cab.

9

8

No Techron 7

6

5 0

20 000

40 000

60 000

80 000

Distance Traveled (km) © Chevron 2009

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Benefit #4: Improves fuel economy Caltex with Techron cares for your car by removing performance-robbing deposits. A clean engine will use less fuel and that's good for all of us.  Your car will perform at its best when vital engine parts

are kept clean.  The unbeatable cleaning power of Caltex with Techron

 A clean engine burns fuel more completely meaning

more energy from every drop of fuel, resulting in improved distances traveled from every tank.

© Chevron 2009

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Averag ge

restores fuel economy lost from deposit build up in the fuel system.

27

Benefit #5: Delivers smooth performance Caltex with Techron is unbeatable at cleaning vital engine parts in your car’s fuel system so your car can perform at its best.  A clean engine provides for a smoother

performance by ensuring optimum combustion reducing misfires (partial combustion, combustion events) and enhancing y driveability.  A car with a clean fuel system is more

p than a car with a recurring g responsive misfire. © Chevron 2009

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Key messages: Caltex with Techron is unbeatable at cleaning up deposits on critical engine parts in a car’s fuel system and keeping them clean. clean ®

Removing these fuel system deposits helps:  restore lost power & acceleration (pick-up)  improves fuel economy  reduce emissions  enhance reliability  deliver smoother performance p

Best of all, the unbeatable cleaning power of Techron is available in all grades of Caltex petrol! © Chevron 2009

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Global transport fuel perspectives  Growing fuel demand globally,

especially in China and India  Increasing demand for cleaner fuels

and technologies  Need to improve energy efficiency  Need to diversify supply & integrate

sustainable resources  Increasing expectations

surrounding climate change

© Chevron 2009

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Customer acceptance Energy companies will provide fuels to meet customer demands. For a customer to demand an alternative fuel, they want to see three criteria fulfilled:  Equal or improved driving performance, safety, reliability and

comfort  Equal or lower vehicle and fuel costs  Improved fuel economy and environmental benefits

Photo: BMW © Chevron 2009

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Outlook for Advanced Petrol Engine Technology  Downsized, turbocharged, and supercharged

engines  Increasing use of Direct Injection

• • • •

Multiple injection strategies Optimized homogeneous fuel/air mixture formation Better control over fuel/air mixture stratification Better control over catalyst light-off and heating

 Variable valve actuation and cylinder

d deactivation i i  Higher compression ratios  Heat recovery from all engine and vehicle

components  Use of advanced automatic transmissions to

reduce frictional losses and improve fuel consumption  Increasing use of mild to heavy hybridisation, © Chevron 2009

including “start-stop” and regenerative braking

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Carbon intensity will become increasingly important  Cellulosic Ethanol

© Chevron 2009



Cellulose is the main structural component of green plants



Provides the opportunity to explore a variety of feedstocks



Can help avoid the foodversus-fuel debate



However, chemical bonds in cellulose ll l are more d difficult ff l to break down



Land use change issues are critical Downstream Technology

33

© Chevron 2009

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