Prepared By P.ANITHA
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Contents What is E-Nose Components Working Principle Sensors Available Data Analysis Difference between human nose and E-Nose Application Conclusion Reference
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Electronic Nose Developed in early 1980’s. Electronic Nose is a smart instrument that is designed to
detect and discriminate among complex odors using an array of sensors. It is a device that combines gas sensors, electronics and
pattern recognition software to sense odors present in the environment, their type and in some cases concentration.
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Components of ENose Chemical Sensing System An array of several different sensing elements Odors samples are sensed and patterns named and
kept in the database Database trains the pattern recognition system
Goals Configures the recognition system Automatic identification of chemicals
Example Spectrometer
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Components of ENose Pattern recognition system Analyze complex data Recognize patterns Unknown chemicals can be rapidly identified in the
field
Example Artificial neural networks
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Working Principle
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Working Principle Chemical sensor Odor samples are exposed to gas sensors The sensor array “sniffs” the vapors from a sample and provides a set of measurements Pattern Recognizer Recognize new patterns The pattern recognizer compares the pattern of the measurements to stored patterns for known materials Perform qualitative or quantitative analysis
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Working Principle Output When stabilization is reached the e-nose emits a
signal and the substance is identified,results are shown in a pc
A cleaning process is to be done for each time A small pump drives “ clean ” synthetic air
through the chamber until the sensors and the chamber itself are clean and ready to start. After that a micro-electro-valve switches to inject air coming through the inlet hose, which will be near the odor source. 10/24/09
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Algorithms Backpropagation-trained Feed-forward networks Fuzzy ARTmaps Kohonenos self-organizing maps (SOMs) Learning vector quantizers (LVQs) Hamming networks Boltzmann machines Hopfield networks
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Different types of sensors Metal Oxide Sensors Whose resistances vary with the type and quantity of gas absorption Surface Acoustic Wave sensors whose acoustic properties are modified by gas
absorption
Conducting Polymers odor sensitive substances whose resistance change upon gas absorption 10/24/09
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Data Analysis Principal Component Analysis Multilayer Perception SIMCA Partial Least square Principal component regression Cluster analysis
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PCA Reduces the high multidimensionality of a
complex data set into two or three variables –the principal components Contain the majority of the information necessary to discriminate the samples More of a Statistical Method Store all Data as an m x n matrix (A)
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Artificial Neural Network The most powerful type of data processing
technique being employed in Electronic Nose instruments ANNs are self-learning; the more data presented, the more discriminating the instrument becomes ANNs allow the Electronic Nose to function in the way a brain functions when it interprets responses from olfactory sensors in the human nose 10/24/09
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How Neural Nets Will Benefit the Electronic Nose Sensor responses drift over time Change with concentration Sample Depletion
Relate the “Pattern” of the data Find the data that is the closest Determine the odor
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Why is an Electronic Nose Better? Trained human ‘sniffers’ are expensive Individuals vary Hazardous Chemicals Can be done in real time for long periods
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Problems where E-Nose help Best suited for matching complex samples with
subjective endpoints such as odor or flavor The E-Nose can match a set of sensor responses to a calibration set produced by the human taste panel or olfactory panel routinely used in food science Example when has milk turned sour when is a batch of coffee beans optimally roasted
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Analogy Between the Electronic Nose and the Biological Nose Inhaling ⇒ Pump Mucus ⇒ Filter Olfactory Epithelium ⇒ Sensors Binding With Proteins ⇒ Interaction Enzymatic Reactions ⇒ Reaction Cell Membrane Depolarized ⇒ Signal Nerve Impulses ⇒ Circuitry & Neural Network
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Difference Human Nose
Electronic Nose
array of hundreds of
sensors organic sensors broad band capability trainable to new odors data acquisition in the brain analysis by true Neural Network processing; pattern recognition 10/24/09
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array of a few tens of sensors thin film polymer based
sensors broad band capability polymers selected to respond to particular compounds trainable to new analytes data acquisition by computer data analysis by computational methods and pattern recognition
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Limits to Human Nose Fatigue Odor adaptation Insensitivity to some species Toxicity of some contaminants
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Advantages of E-nose Portable High Reliability Identify simple molecules
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Limits of E-Nose Difficulty in maintaining an exhaustive database of
different fingerprints of chemicals. It may be very difficult to analyze a complex mixture of different chemicals. The precision of the device while analyzing similar smell is controversial. Insensitivity to some species High cost Time Delay
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Applications Food Industry Medicine Environment Cosmetic, perfumery Chemistry Etc.,
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Food Industry Application This is currently the biggest market for
electronic noses: Inspection of food to test for ripening/rotting. Testing of packaging materials for odour containment. Verifying if orange juice is natural. Grading whiskey and controlling fermentation.
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Medicine Sensitive `noses' may help clinicians by
examining Breath odours:
Abnormal breath can be indicative of
gastrointestinal problems, sinus problems, infections, diabetes and liver problems.
Body fluids: The smell of urine and blood can help in the diagnosis of
liver and bladder problems
Wounds: early diagnosis of wound infection considerably improves healing rate 10/24/09
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Environmental Monitoring Monitoring of factory emissions, air quality
and household odours. Detection of oil leaks. Analysis of toxic wastes and fuel mixtures.
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Cosmetic, perfumery Quantification monitoring with E-Nose (SAS-
FMS) - Evaluation of fragrances in shampoo Chemistry Paper odors Oxidized oils odors Solvents from paint or plastics
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Conclusions The enose offers some clear advantages over
other techniques currently in use to determine odur levels It is particularly useful in routine operations due to its ease of use and rapid response rate Humans are not well suited for repetitive or boring tasks that are better left to machines The E-nose has the interesting ability to address analytical problems that have refractory to traditional analytical approaches 10/24/09
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References
http://www.asctbhopal.com/Technovista07/FEVERTONICS/5/elec%20smell% A paper presentation on ANN for enoseby Y.Sarika and N.Sambhavi The Electronic Nose: aquick and dirty introduction Electronic Nose by Sree Sailaja EN by Paisan Doungjak The Electronic Nose & its potential by Miss Asha Joseph,Dr. Peter
Lykos Applications and Advances in Electronic-Nose Technologies by Alphus D. Wilson 1, Manuela Baietto http://www.pdfcoke.com/doc/6775979/Enose http://cns-web.bu.edu/pub/laliden/WWW/Papers/nose.html
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