Sugaquat Bulletin

SUGA QUAT SERIES ®

UNIQUE CATIONIC CONDITIONERS

CTFA/INCI names are listed inside this bulletin Suga®Quat is covered under patent # US 6,881,710

benefits • Suga®Quats are “green” and are derived from renewable resources • Soft after feel • Low-Irritation Profile • No greasy build-up • Excellent wet comb properties • Controls fly-away hair • Biodegradable • Formulates in the presence of anionics • Supports viscosity in shampoos • Enhances preservation of formulations

applications • • • • • • • • • • •

Hair Conditioners 2 - in - 1 Shampoos Body Washes Facial Cleansers Wipes Clear Hair Rinse Styling Products Baby Products Hand Sanitizers Relaxers Shower Gels

introduction The Suga Quat Series of naturally derived conditioning quats, bring formulators new ingredients that for the first time provide excellent conditioning of hair and skin while being much milder than traditional quats. The new Suga®Quat Series offer the formulator naturally derived ingredients from renewable resources that are low in irritation to eyes and skin. ®

The Suga®Quat Series are also very substantive, providing both wet comb properties and fly-away control to hair while being non-greasy and not building up. Colonial Chemical has done a variety of conditioning tests and Rubine Dye tests to verify the performance of Suga®Quats in personal care formulations. Suga®Quats are substantive to hair and skin even in the presence of anionic surfactants. The Suga®Quat Series demonstrates very unique properties when compared to traditional cationic conditioning agents. Most notable is the significant reduction in eye irritation versus traditional quats as well as no skin irritation at all in our testing. The Suga®Quat Series are very compatible in anionic shampoo formulations making them an ideal choice for 2 in 1 shampoos. The Suga®Quat Series do not inhibit from the foam of the shampoo and in fact contribute to foaming properties. Useful over a broad pH range, Suga®Quat Series are stable in all types of personal care formulations. Some of the Suga®Quat Series have excellent microbial activity. This could make Suga®Quat products useful in preservative free and reduced preservative personalcare formulations. Suga®Quats are light color, low odor and easy to use in a variety of personal care formulations. If you are looking for natural, renewable resource derived conditioning agents, the Suga®Quat Series is where you need to look. If your formulations demands milder ingredients the Suga®Quat Series of products is where you need to look. Natural, safe and from renewable resources, Suga®Quats.

typical properties Property

TM-8610

L-1010

L-1210

Color, Gardner Activity Viscosity (as is)

<1 30.0 8

<1 30.0 16

1 30.0 106

pH (10% aqueous)

7.0

7.0

7.0

Ross-Miles Foam Height (1% active), mm Immed. 1 minute 5 minutes

145 130 125

145 135 130

160 145 145

Draves Wetting (1% active), seconds

3.4

4

9

soluble

cloudy (gel)

soluble

cloudy (gel) clear (gel) soluble

Compatibility, 5% active solution 5% active SLS 5% active DSLS

Soluble, all ratios Soluble, all ratios

Ratios from 3:2 to 1:5 Cloudy at 3:2 (thickens) Soluble, all ratios

Property

S-1010

S-1210

S-1218

Color, Gardner Activity Viscosity (as is)

<1 30.0 21.5

1+ 30.0 9800

<1 30.0

pH (10% aqueous)

7.0

7.0

7.0

Ross-Miles Foam Height (1% active), mm Immed. 1 minute 5 minutes

160 145 140

160 140 135

110 100 95

Draves Wetting (1% active), seconds

15

15

13

clear (gel) soluble soluble

cloudy (gel) soluble

cloudy (gel) clear (gel) soluble

Ratios from 3:2 to 1:5 Cloudy at 66:50 (thickens) Cloudy, all ratios. (thickens)

Cloudy at 50:42 (thickens) Cloudy at 2:1 (thickens)

Solubility, 10% active solution 50% NaOH 25% NaOH 25% H2SO4

Solubility, 10% active solution 50% NaOH 25% NaOH 25% H2SO4

Compatibility, 5% active solution 5% active SLS Soluble, all ratios 5% active DSLS Cloudy at 50:38 (thickens)

structure

soluble Cloudy at 1:1 Cloudy at 1:5 (thickens)

toxicological properties Eye

The evaluation of Suga®Quats as an eye irritant was performed using the chorioallantoic membrane technique. This test utilizes the inner membrane of a hen’s egg to gauge the irritation potential of a compound by visual observation of injurious changes in the membrane. Suga®Quat S-1210 was rated to be milder than a leading brand of baby shampoo.

Skin

A study was performed adhering to ICH Guideline E6 and 21 CFR parts 50 and 56. Fifty-seven (57) volunteers, males and females, ranging in age from 16 to 76 were subjected to a patch test. A 1″ by 1″ absorbent pad was moistened with 0.2 ml of liquid and applied to the backs of the subjects between the scapulae. The patch sites were inspected at 48 hours for gross changes. It was observed that there was a complete absence of skin change. The test sites were evaluated again at 72 hours. Once again the observation was negative skin changes. Under the condition of this test, the test materials, Colonial Suga®Quats, did not indicate a potential for dermal irritation.

CTFA/INCI names COLONIAL Suga®Quat TM-8610 COLONIAL Suga®Quat S-1010 Trimoniumhydroxypropyl Cocoglucosides Chloride Stearyldimoniumhydroxypropyl Decylglucosides Chloride COLONIAL Suga®Quat L-1010 COLONIAL Suga®Quat S-1210 Lauryldimoniumhydroxypropyl Decylglucosides Chloride Stearyldimoniumhydroxypropyl Laurylglucosides Chloride COLONIAL Suga®Quat L-1210 COLONIAL Suga®Quat S-1218 Lauryldimoniumhydroxypropyl Laurylglucosides Chloride Stearyldimoniumhydroxypropyl Laurylglucosides Chloride

f o r m u l a t i o n s super conditioner for damaged hair PHASE

COMPOUND

Wt. %

A A A A

Deionized Water Tetrasodium EDTA Glycerin 96% Guar Hydroxypropyl Trimonium Chloride Suga®Quat S-1210 Glyceryl Stearate Behenyl Alcohol Stearalkonium Chloride Siltech F-1000 Siltech FVC Kathon CG Fragrance Citric Acid (25% solution)

82.91 0.10 2.50 0.50

B B B B B B C D E

TOTAL

w i t h S u g a ®Q u a t S - 1 2 1 0

3.50 0.50 2.00 1.50 1.00 5.00 0.05 0.30 0.14 100.00

PROCEDURE:

Combine Phase A and heat to 75C. Heat Phase B to 75C. Slowly add Phase B to Phase A with agitation. Add Phase C. Cool to 30C and add remaining phases. Viscosity Target: 1,000-7,000 cps

TYPICAL PROPERTIES: Lab Control: pH: Viscosity:

Adjust pH to 4.5-5.5 as needed 5.18 1,200 cps – RVT #2 @ 20 RPM

If you need any additional formulations please contact Cindy at Colonial Chemical via Email [email protected]

antimicrobial properties A study was done to compare the performance of several of the Suga®Quat products against strains of bacteria, yeast and mold. This study by an outside microbiological laboratory is shown below. Suga®Quat S-1210 and S-1218 were seen to have broad-spectrum killing properties in this study; this makes these products useful in self preserved and preservative free system for personal care. Our own testing continues in this unique application area for validation of Suga®Quats in preservative free systems. We suggest any use of Suga®Quats in such applications be challenge tested for verification.

Suga®Quats ZONE INHIBITION STUDY – PROJECT #60720

8/2/06 BIO-CONTROL CONSULTANTS, INC.• 43 MOHICAN DRIVE • WESTFIELD, NJ 07090 PURPOSE: To determine the antimicrobial capability of two (2) Suga®Quat (alkyl polyglucoside) variations utilizing the zone inhibition technique. The test materials were evaluated for gross antimicrobial activity against a series of three (3) test organisms: Pseudomonas aeruginosa (Gram negative bacteria); Candida albicans (yeast) and Aspergillus niger (mold). Results of the assays are presented below. TEST SAMPLES: 1) Suga®Quat S-1210 13678D06 (2.0% and 1.0% concentrations). 2) Suga®Quat S-1218 RJC-02-081 (2.0% and 1.0% concentrations). COMBINED ACTIVITY SUMMARY SCORING:

1 = Excellent; 2 = Very Good; 3 = Good; 4 = OK (moderate); 6 = Poor; 8 = No Activity

TEST SAMPLE

Psa

1. 2.

Ca

Suga®Quat S-1210 1 Suga®Quat S-1218 1

An

Score

Comments

2 1

3 2

10 7

Excellent Psa; V Good Yeast; Good Mold Excellent Activity

Note: The lower the score, the greater the activity. COMMENTS • Suga®Quat S-1218 demonstrated very good antimicrobial activity against all three of the test organisms employed. This material compares favorably to the general antimicrobial profile of a commercial product known for antimicrobial activity at both the 1.0% and 2.0% concentrations. • Both Suga®Quat S-1210 and Suga®Quat S-1218 demonstrated excellent activity at the 2.0% level, however, significant differences were observed with yeast and fungal activity at the lower concentration. •

Overall, the Suga®Quats look very promising providing that the use concentration is maintained at a high enough level. This should not present an issue since the normal recommended formula use recommendation above a 2.0% concentration. Reported by:

John I. Yablonski Bio-Control Consultants, Inc.

WARRANTY No warranties beyond the guarantee that Colonial Chemical products are manufactured to specs are expressed or implied, since the use of material is beyond our control. Technical information contained herein is believed to be accurate. However, it is furnished without charge or obligation and is given and accepted at the recipient’s sole risk. No guarantee of the accuracy of the information is made and the products discussed are sold without conditions or warranties expressed or implied. Purchasers should make their own tests and determine suitability of the product for their particular purposes. Nothing contained herein shall be considered a recommendation for any use that may infringe upon patent rights. C O L O N I A L C H E M I C A L , I N C . • 225 Colonial Drive South Pittsburg, TN 37380 Phone: 423-837-8800 • Fax: 423-837-3888

© Copyright 2007, Colonial Chemical, Inc. All rights reserved.

COLONIAL CHEMICAL, INC. 225 Colonial Drive South Pittsburg, TN 37380 Phone: 423-837-8800 Fax: 423-837-3888 www.colonialchem.com