WELCOME
Why Focus on MAHAC Process Industry Complexity
of Reactions Diversity and spread Domino/Cascade effects-Offsite High Inventories, Nature of materials Severity of impact
Benefits-from Chemical Spectrum Audio
Cassettes Bubble gum Cooking Gas Detergents Fertilisers Leather chemicals Masking tapes
Paints Perfumes Petrochemicals Pharmaceuticals Plastics Semiconductors Tyres
Activity Flow Chart-Project conception
Engineering Design Technology Options/Selection Layout Planning /Layout Construction Trial Runs Stabilisation Perfecting Operation Validation
Hazards Every
activity has an element of Hazard Hazard leads to Risk Risk Leads to Consequence Consequence impacts vary Weather/Environment factors influence gravity Safe guards and Controls mitigate/ minimise impact
Risk Analysis Since
Hazard is inherent, Risk analysis is essential Broadly there are 5-steps to Risk Analysis
“HSE UK Leaflet”-ADAPT TO SPECIFIC NEED “Step 1 Identify the hazards Step 2 Decide who might be harmed and how Step 3 Evaluate the risks and decide on precautions Step 4 Record your findings and implement them Step 5 Review your assessment and update if necessary”
Step 1-Hazard Identification General applicable Raw Material Pipe/ Tanker receipt Pump Transfer Storage Line out to Production Block
Hazard Sources-Illustrated examples Equipment
related Process related Controls related Natural causes Security related issues:-Arson, Vandalism, IEDs
Piping Leaks
from Valves Flanges, Gaskets, Drains/Vents Disconnection of Earthing/Bonding Fatigue /Metallurgical failures
Tanker truck
Excess pressure build up in the tanker Improper earthing/bonding Leakage/spill Hot parts of the truck Run downs and Spread Physical impacts Movement during loading
Pumps Seal/gland Electrical
leaks
Panels =Sparking /arcing/flashovers Loss of integrity of FLP fittings Short circuit
Storage
Containment failure Leaks/Overflow in Tank area Storage Nozzle/Pipe connection leaks Instantaneous release of liquid/Vapour Continuous release of liquid/Vapour
Production/Process Equipment Reactors,
Exchangers, Boilers, Hot Oil systems, Chillers,Centrifuges, Dryers, Scrubbers, etc
Raw Material
Combustible Flammable Explosive Toxic Corrrosive Spontaneous igniting Reactive Incompatible etc
Reactions Hydroforming Catalytic
cracking Polymerisation High pressure Synthesis Hydrogenation Halogenation Grignard, Fridel Kraft, Amination etc
Process Parameters Pressure Temperature Flow Level Monitoring
& Measurement
Results Equipment
+ Materials+ Reactions+ Process parameters= Products/Bye products Material Balance Un-reacted wastes Recovery, Recycle, Reuse, Reduce Scrubbing, Treatment, Transfer, Emit
Deviations Leads to Risk. Design Changes without evaluation Operational Failure
of Utilities or Cooling system Scrubbing system failures, Malfunction /Failure of Process Controls Parameter deviations
Incident -Consequences Fire Explosion Toxic
release
Step-2 Consequences- Who might be harmed People Environment Equipment Materials
Incident--What it Means
Property Damage /Personnel harm Plant Start-up Delays Restricted Output Downtime Repairs Cost Insurance Costs Public Reaction Societal impact Economic Impact
Related Consequences Legal Statutory Insurance Public
Liability
Desirable Approach Avoid
Major Manage Medium Live with Low risk Treat, Tolerate, Transfer, Terminate ALARP ALASA Within Permissible Limits
Step-3 Basis—Risk Analysis Structured
& Relevant Qualitative & Quantitative Adopt applicable methodology CCPS AIChE publication, HSE- UK, US EPA, European Directives Risk Templates used by Accreditation agencies and such
Hazard Analysis Typical Applications Activity Technique Design PHA Detailed Engineering Fault Tree / Event Tree Analysis Construction / Startup Checklist/Safety Review Pilot Plant Operation / HAZOP Routine Operation
Hazard Analysis (Contd) Decommissioning
What–If, Checklist Analysis Expansion HAZOP/Relative Ranking R&D What – If Incident Investigation What– If / FMEA / HRA
Step-4 Considerations for Impact Derivations On
Site risk tabulation Hazmat Inventory volumes Hazard ratings-NFPA, Maximum Credible Scenarios shortlist Weather factors, Environmental risk Exposure factors--Acute/Chronic
Step 5 -Impact estimation/ Assessment Review F
& E and Mond Indexing TLV/PEL/TEEL/ERPG references BMPPD values estimation AMPPD values estimation Software derivations Recording Risk Impact Assessing Protection & Controls
Protection & Controls Design
/Layout integrated Management controls Process Safety Management Operational Controls Procedural Controls Administrative Controls Emergency combat protection
Design & Layout Codes
& Standards Regulatory specifications Demographical considerations Domino/Cascade effects Land use zoning aspects Later additions
Management Controls Setting
Objectives & Goals Legal Register compliance Audits—Internal, Multi-Disciplinary, External , Statutory Audit follow through Activity Planners Performance Review
Good Audits
Clarity in Scope definition Standards referenced Audit methodology—LPRM Specialist- Core competency,No rigid formats, No boundaries, Out of the Box approach, Bare all/ Tell all Partners/ Benchmark Facilitators-Reputation driven. Pre-audit survey/information input Physical visit—Opening meeting, Site co-ordinators, Physical tour, Interaction, Documents review, Audit notes, Draft sum-up, Closing meeting, Focus area identification, Action plan Roadmap, Final report
AUDIT CHECKLIST REFERENCES BIS
14489 5-STAR ISRS OHSAS DUPONT SYSTEMS DOW CHECKLIST PSM
Document Management Design,
Installation, Operation, Final Qualification acceptance criteria Maintenance and History cards Inspection and Condition monitoring trends
People Management Training NEST,STOP,
CARE Participative forums Self- Regulating mindset Beyond Compliance
Process Safety Management Process
Safety Information Process Hazard Analysis Standard Operating Procedures Training Contractor control Pre-start up safety review Mechanical Integrity
PSM Contd Non-routine
work authorisations Management of Change Investigation of incidents Emergency Preparedness Compliance audit Employee participation
Operational Controls
Built in Equipment Safeguards LOPA SIL Instrument Controls-Alarm/Trip/Interlock Remote ESD DCS PLC SCADA
Procedural Controls SOPs WI Checklists Permits
to Work
Change Management/Equipment Management
Featured in Link http://www.pdfcoke.com/doc/ 20319667/Safety-in-Chemical-andHydrocarbon-process-IndustryChange-Management
Change Management-Key aspects
Change involves thinking holistically Change may necessitate downtime Interruption due to incidents can affect safety of personnel and Business economics. Each change review should be situation specific. General references cannot displace internal Multi-disciplinary review and validation. Yet changes can become necessary to continually improve Safety, Health & Environment
Preparedness Despite
all this and the inescapable Human Error factor it is essential to be well prepared to handle Emergencies to Control, Contain incidents with Nil or Minimal consequential damage
Emergency handling Site
specific Emergency Preparedness Plan Drills—Site/Process Specific Evaluation template for Drills Inclusion of Natural perils scenarios—Storm, Building Collapse Security related –IED, Arson, Terrorism, Malicious damage, Riots
SHE Management
Technology selection, Design Safeguards, Layout form a key triangle in Facility Construction.
Process/Protection controls, Condition monitoring, Site Audits, form the triangle for smooth operations.
Management Controls, Standard Operating Procedures, Training, form the key 3 Administrative measures.
Regulations, Codes and Standards and Third party Audits complete the key elements for successful Management of SHE.
Systematic Analysis/Approach
Avoids GUESS “Going Unorganised Eliminating Systematic Study” Enables Focus on Realistic, Practical, Attainable solutions balancing EHS/Business activities Risk Management Plan can be tailored integrating Regulatory needs/EHS Plan/Business Economics. Lends greater credibility to justify implementation costs of Safeguards
Company Benefits Good
corporate citizen Reputation management Cost effectiveness Continual improvement Cause focused /Not consequence centric Proactive Vs Reactive Rework avoid
Abbreviations List -AL
AIChE ALARP ALASA AMC AMPPD BIS BMPPD CARE CCA CCPS DCS EHS ERPG ESD ETA
American Institute of Chemical Engineers As Low As Reasonably Practical As Low As Societal Acceptable Annual Maintenance Contract Actual Maximum Probable Property Damage Bureau of Indian Standards Base Maximum Probable Property Damage Constant Accident Reduction Efforts Cause Consequence Analysis Centre for Chemical Process Safety Distributed Control System Environment, Health & Safety Emergency Response Planning Guideline Emergency Safety Device Event Tree Analysis
AL
F&E FLP FMEA FRLS FTA HAZOP HR HRA HSE ID IDLH IED IP ISRS
Fire & Explosion Flameproof Failure Mode and Effects Analysis Fire Resistant Low Smoke Fault Tree Analysis Hazard Operability Heat Resistant Human Reliability Analysis Health & Safety Executive Identity Immediately Dangerous to Life & Health Improvised Explosive Devices Ingress Protection International Safety Rating System
AL
LOP LOPA LPRM MAHAC MOC MTBF MTO NDT NEST NFPA O&M OEM OHSAS OSEP
Loss of Profit Layer of Protection Analysis Loss Prevention Risk Management Major Accident Hazard Category Material of Construction Mean Time Between Failure Material Transfer Order Non Destructive Testing New Employee Safety Training National Fire Protection Agency Operation & Maintenance Original Equipment Manufacturer Occupational Health and Safety Assessment Series On Site Emergency Plan
AL
P & ID PDCA PEL PEME PHA PLC PM PSM R&D RCA SCADA SHE SIL SOP STOP
Piping & Instrumentation Diagram Plan, Develop, Check and Act Permissible Exposure Limit People, Environment, Materials, Equipment Process Hazard Analysis Programme Logic Control Preventive Maintenance Process Safety Management Research & Development Root Cause Analysis Supervisory Control and Data Acquisition Safety, Health & Environment Safety Integrity Level Standard Operating Procedure Safety Training Observation Program
AL TEEL TLV US EPA WI ZH Source credits:
Temporary Emergency Exposure Limit Threshold Limit Value United States Environment Protection Agency Work Instructions Zero Halogen CCPS, HSE -UK,US- EPA, SCAPA,CFR-1910 DuPont, Dow Publications,Dow F &EI Practical Experiences Professional contributions Interactions with Chemical Industry,OEMs.