Methane 1
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tR (min) H2 O2 CO CH4 CO2 C2H2 C2H4 C2H6 C3H6 C3H8 C3H4 iC4H10 nC4H10
FID (area) 1.99 0 5.79 3.39 16.23 8.66 9 29.4 42.13 28.19 43.77 32.9 33.87
0 0 1684.13 1640.49 1732.13 3056.34 3253.34 3279.95 4454.86 4232.11 4433.96 5654.26 5165.35
calibration data (area method) H2 729.54 727.39 150.17 149.68 O2 843.81 86.76 101.73 CO CH4
tR (min)
tR (min)
TCD 4.4 2.5 5.72 3.36 16.15 8.63 8.97 29.36 42.08 28.17 43.72 32.87 33.84
1169.95 98.18 98.79 248.79 94.18 192.9 185.84 384.73 402.9 308.94 339.57 324.09 281.9
FID (height)
232.25 161.3 146.98 306.61 351.59 329.66 340.22 363.87
728.47 149.93 102.09
102.15
1639.77 248.53
1640.98 248.54
1640.69 249.26
1640.61 248.73
3006.26 192.71 3257.34 187.15
3075.96 193.81 3257.44 186.11
3086.79 192.17 3245.25 184.27
4193.32 316.98
4327.03 314.8
4327.72 299.64
5660.91 323.17 5486.82 296.72
5647.6 325.01 4843.88 267.08
98.18
1640.38 248.92
1640.49 248.79
CO2 C2H2 C2H4
3056.34 192.9 3253.34 185.84
C2H6 C3H6 C3H8
4080.38 304.34
4232.11 308.94
C3H4 iC4H10 nC4H10
calibration data (height method) CH4 232.28 232.21 C2H2 C2H4 146.88 146.94 C3H8 206.69 206.69 iC4H10 259.9 258.22 nC4H10 256.69 235.01
5654.26 324.09 5165.35 281.9
232.24 147.12 197.87
232.25
232.23
232.25 146.98 203.75 259.06 245.85
tR (min) H2 O2 CO CH4 CO2 C2H2 C2H4 C2H6 C3H6 C3H8 C3H4 iC4H10 nC4H10
FID (area) 0 0 64.09 3535.88 3400.25 6531.64 6490.51 6901.19 9706.08 9799.68
1.99 2.46 0 0 0 0 0 0 0 0
33.37 35.23
12117.36 12060.91
0 0
nC4H10
12070.94 339.5 12060.74 363.73
12163.77 340.93 12061.08 364.02
tR (min)
TCD
0 0 2.57 3.63 6.62 10.69 10.91 13.42 24.06 25.07
calibration data (area method) H2 729.54 727.39 150.17 149.68 O2 84.81 86.76 16.81 17.63 CO 63.99 64.19 12.75 12.84 CH4 3535.88 3535.88 467.46 467.46 CO2 3165.35 3635.15 212.53 239.31 C2H2 6520.06 6543.23 344.13 345.28 C2H4 6490.51 6490.51 258.45 258.45 C2H6 6865.79 6936.58 305.72 307.5 C3H6 9706.08 9706.08 351.59 351.59 C3H8 9731.27 9868.09 327.93 331.4 C3H4 iC4H10
tR (min)
728.47 85.78
FID (height) 1.99 2.46 2.57 3.63 6.62 10.69 10.91 13.42 24.06 25.07
149.93 17.22 12.8 467.46 225.92 344.71 258.45 306.61 351.59 329.66
33.37 35.23
340.22 363.87
728.47 149.93 85.78 17.22 64.09 12.8 3535.88 467.46 3400.25 225.92 6531.64 344.71 6490.51 258.45 6901.19 306.61 9706.08 351.59 9799.68 329.66
12117.36 340.22 12060.91 363.87
column Inject Detector 1 Detector 2 Aux 1 Aux 2
10ft Hayesep D + 10ft 10%Carbowax 180 oC 250 oC 250 oC 140 oC 350 oC
Temperature program 50oC 5 mins 5oC/min 220oC 3 mins Analysis conditions FID Threshold 0.01 Peak width 5 Peak area 0.75 Peak Height 0 Range Sense Attn
8 1 0
TCD 0.01 5 0.5 0 0 4 0
Experiment of Methane Kinetic Conversion power @ 60 and 80W and flowrate @ 30 mL/min frequency flow rate power
20 kHz 30 mL/min 60 W (Metex)
CH4
reactant FID (flow rate) 8.42 25.53 25.66 29.40 42.13 42.98 43.77 51.25 53.31 TCD 4.40 8.39 power V (kV) I (mA) total mol FID TCD calculation FID 8.42 25.53 25.66 29.40 42.13 42.98 43.77 51.25 53.31 TCD 4.40 power (Watt) RMS integration C total H total
sample volume mole sample
before 29.19 1744.71
500 uL 0 mol
Al2O3 after 29.88 1583.17 18.81
before
ZSM5 after
before
after
71.79 29.21
312.87
72.57 281.47 2.77 24.82
0 #DIV/0! 0 FID 7.12 16.79 0.00 60.65 0.00 26.07 #DIV/0! 0.00 0.00
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! #DIV/0! FID #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! #DIV/0! FID #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
145.20
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
50.00 68.85 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
0.00 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
0.00 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
2n reactant
CH4 before
FID 8.42 25.53
Al2O3
20 1767.31
after 19 1530.75 22.84
before 70.88 1566.43
ZSM5 after 70.18 1368.43 19.56
before 62.95 1583.33
after 62.63 1384.03 18.78
25.66 29.40 42.13 42.98 43.77 51.25 53.31
105.31 17.75 50.60
81.12
81.58
30.62
32.21
14.60 12.33
TCD 4.40 8.39 power (RMS) V (kV) I (mA) total mol FID TCD calculation FID 8.42
0 #DIV/0! 0 FID 17.72
0 #DIV/0! #DIV/0! TCD #DIV/0!
0 #DIV/0! 0 FID 13.51
0 #DIV/0! #DIV/0! TCD #DIV/0!
0 #DIV/0! 0 FID 13.03
0 #DIV/0! #DIV/0! TCD #DIV/0!
25.53 25.66 29.40 42.13 42.98 43.77 51.25 53.31
7.50 0.00 32.74 5.88 16.62 #DIV/0! 5.20 4.37
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
9.91 0.00 38.89 0.00 15.51 #DIV/0! 0.00 0.00
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
9.81 0.00 40.33 0.00 16.82 #DIV/0! 0.00 0.00
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
78.47
#DIV/0!
92.46
#DIV/0!
101.74
#DIV/0!
307.64
106.56 264.30
276.56
2.85 23.74
81.43 237.60
278.62
2.79 23.67
86.89 242.06 2.79 23.90
TCD 4.40 power RMS integration C total H total
48.00 67.56 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
49.00 66.06 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
50.00 66.59 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
3rd reactant FID 8.42 25.53 25.66 29.40 42.13 42.98 43.77 51.25 53.31
Al2O3
CH4 before 105.47 1362.24
after 106.11 1070.21 17.78
before 104.67 1329.94
ZSM5 after 105.16 1062.81 16.29
before 117.05 1358.6
after 120.52 1079.62 23.45
95.57
101.06
102.63
48.91
42.08
42.20
11.69
TCD 4.40
133.49
149.43
140.95
8.39 power (RMS) V (kV) I (mA) total mol FID TCD calculation FID 8.42 25.53 25.66 29.40 42.13 42.98 43.77 51.25 53.31 TCD 4.40 power RMS integration C total H total
report < 10%
246.40
192.88
240.66
2.60 21.50
190.17
243.69
2.86 15.18
191.94 2.62 23.93
0 #DIV/0! 0 FID 20.96 6.78 0.00 34.50 0.00 18.65 #DIV/0! 0.00 0.00
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! 0 FID 19.71 6.76 0.00 39.69 0.00 17.45 #DIV/0! 0.00 0.00
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! 0 FID 18.18 10.58 0.00 43.84 0.00 19.04 #DIV/0! 0.00 5.69
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
114.13
#DIV/0!
138.97
#DIV/0!
142.61
#DIV/0!
50.00 55.92 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
50.00 43.46 #DIV/0! #DIV/0!
Al2O3
#DIV/0! #DIV/0!
50.00 62.72 #DIV/0! #DIV/0!
CH4 conv.
empty #DIV/0!
#DIV/0!
ZSM5 #DIV/0!
H2
#DIV/0!
#DIV/0!
#DIV/0!
C2H2
#DIV/0!
#DIV/0!
#DIV/0!
C2H6
#DIV/0!
#DIV/0!
#DIV/0!
C3H8
#DIV/0!
#DIV/0!
#DIV/0!
C4
#DIV/0!
#DIV/0!
#DIV/0!
10-20% CH4 conv.
#DIV/0!
#DIV/0!
#DIV/0!
H2
#DIV/0!
#DIV/0!
#DIV/0!
C2H2
#DIV/0!
#DIV/0!
#DIV/0!
C2H6
#DIV/0!
#DIV/0!
#DIV/0!
C3H8
#DIV/0!
#DIV/0!
#DIV/0!
C4
#DIV/0!
#DIV/0!
#DIV/0!
> 20% CH4 conv.
#DIV/0!
#DIV/0!
#DIV/0!
H2
#DIV/0!
#DIV/0!
#DIV/0!
C2H2
#DIV/0!
#DIV/0!
#DIV/0!
C2H6
#DIV/0!
#DIV/0!
#DIV/0!
C3H8
#DIV/0!
#DIV/0!
#DIV/0!
0.4
#DIV/0!
0.33
#DIV/0! #DIV/0!
C4
#DIV/0!
#DIV/0!
#DIV/0!
e Kinetic Conversion
flowrate @ 30 mL/min
1st trial 3% Fe/Al2O3 before 59.94 1539.94
after 59.48 1462.41
3% Fe/ZSM5 before after
3% Cu/Al2O3 before
after
3% Cu/ZSM5 before 29.14 1654.38
51.25
30.82 265.69
280.81
314.29
2.61 24.02 0 #DIV/0! 0 FID 5.76 0.00 0.00 58.77 0.00 0.00 #DIV/0! 0.00 0.00
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! #DIV/0! FID #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! #DIV/0! FID #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! 0 FID 8.42 0.00 0.00 60.51 0.00 25.49 #DIV/0! 0.00 0.00
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
166.40
83.70
35.00 62.60 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
51.00 0.00
0.00 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
2nd trial 3% Fe/Al2O3 before 55.49 1525.45
after 55.79 1337.47 18.89
3% Fe/ZSM5 before 383.61 772.02
after 386.32 648.66 16.31
3% Cu/Al2O3 before 62.14 1596.97
after 58.16 1384.14 17.97
3% Cu/ZSM5 before
78.17
45.70 5.63 19.07
26.66
88.63 32.35
4.88 5.55 85.64 242.95
278.71
58.61 108.83
128.98
2.77 24.14
92.82 240.07
278.40
2.89 24.21
2.75 23.45
0 #DIV/0! 0 FID 11.85
0 #DIV/0! #DIV/0! TCD #DIV/0!
0 #DIV/0! 0 FID 15.39
0 #DIV/0! #DIV/0! TCD #DIV/0!
0 #DIV/0! 0 FID 18.89
0 #DIV/0! #DIV/0! TCD #DIV/0!
0 #DIV/0! #DIV/0! FID #DIV/0!
11.37 0.00 44.54 0.00 16.04 #DIV/0! 0.00 0.00
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
14.97 0.00 39.70 5.22 17.50 #DIV/0! 4.85 5.49
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
6.04 0.00 28.18 0.00 10.87 #DIV/0! 0.00 0.00
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
115.56
#DIV/0!
120.60
#DIV/0!
69.90
#DIV/0!
#DIV/0!
49.00 66.87 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
48.00 69.85 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
51.00 64.51 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
3rd trial 3% Fe/Al2O3 before 20.04 1714.32
3% Cu/Al2O3
3% Fe/ZSM5
after 20.1 1289.47 36.67
before 28.2 1683.23
after 24.61 1485.66
before 118.43 1390.88
3% Cu/ZSM5
after 115.26 1077.8 20.88
163.43
74.57
94.80
72.16
28.78
37.85
23.48 18.19 192.57
82.68
139.72
before
294.93
218.64
310.54
280.90
2.80 24.37 0 #DIV/0! 0 FID 24.56 9.46 0.00 39.90 0.00 18.61 #DIV/0! 6.56 5.06
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
111.34
#DIV/0!
3% Fe/Al2O3
#DIV/0! #DIV/0!
195.28
2.85 25.42 0 #DIV/0! 0 FID 22.97 0.00 0.00 17.25 0.00 7.03 #DIV/0! 0.00 0.00 45.29
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
50.00 68.33 #DIV/0! #DIV/0!
254.30
2.52 24.14 0 #DIV/0! 0 FID 24.58 6.43 0.00 27.65 0.00 11.66 #DIV/0! 0.00 0.00
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! #DIV/0! FID #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0!
#DIV/0!
96.52
50.00 72.50 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
49.00 60.88 #DIV/0! #DIV/0!
3% Cu/Al2O3
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0!
3% Fe/ZSM5 #DIV/0!
#DIV/0!
3% Cu/ZSM5 #DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
3% Cu/ZSM5 after 29.89 1477.27
1% Pt/Al2O3 before 60.65 1520.66
5% Mn/Al2O3
after 60.65 1368.15 20.17
before 29.55 1668.01
3% Ru/Al2O3
after 29.72 1491.99 19.45
before 65.02 1709.93
after 65.11 1545.33 21.46
80.16
68.45
65.21
91.60
31.96
26.93
27.49
39.66
93.07 277.73
73.14 250.81
278.04
2.77 24.88
70.44 276.97
311.80
2.38 24.64
96.01 271.58
300.80
2.77 24.27
2.79 23.38
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! 0 FID 10.03 14.32 0.00 45.99 0.00 19.11 #DIV/0! 0.00 0.00
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! 0 FID 10.04 12.64 0.00 40.11 0.00 17.86 #DIV/0! 0.00 0.00
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! 0 FID 9.49 14.33 0.00 57.91 0.00 26.49 #DIV/0! 0.00 0.00
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0!
116.40
#DIV/0!
102.62
#DIV/0!
143.77
#DIV/0!
50.00 68.79 #DIV/0! #DIV/0!
3% Cu/ZSM5 after
36.00 58.64 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
1% Pt/Al2O3 before 59.12 1506.64
after 61.34 1262.63 23.31
50.00 67.11 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
5% Mn/Al2O3 before
after
50.00 65.16 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
3% Ru/Al2O3 before
after
94.62 35.16
109.34 227.18
274.31
2.47 24.31 0 #DIV/0! #DIV/0! TCD #DIV/0!
0 #DIV/0! 0 FID 13.06
0 #DIV/0! #DIV/0! TCD #DIV/0!
0 #DIV/0! #DIV/0! FID #DIV/0!
0 #DIV/0! #DIV/0! TCD #DIV/0!
0 #DIV/0! #DIV/0! FID #DIV/0!
0 #DIV/0! #DIV/0! TCD #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
13.31 0.00 51.14 0.00 20.08 #DIV/0! 0.00 0.00
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0!
139.97
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
48.00 0.00 #DIV/0! #DIV/0!
3% Cu/ZSM5 after
52.00 60.12 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
1% Pt/Al2O3 before 67.1 1427.66
0.00 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
5% Mn/Al2O3
after 66.98 1125.36 13.01
before 118.56 1357.72
0.00 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
3% Ru/Al2O3
after 119.22 871.94 31.77
before 117.19 1357.71
after 118.21 843.19 28.02
118.99
146.47
152.37
44.78
57.06
63.38
11.09
19.09 16.03
19.61 15.91
152.81
253.82
282.6
245.04
194.45
245.09
156.39
2.72 21.88
246.22
148.79
2.29 23.59
2.38 24.50
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! 0 FID 21.32 4.62 0.00 39.99 0.00 15.90 #DIV/0! 0.00 4.25
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! 0 FID 35.42 7.19 0.00 31.38 0.00 12.91 #DIV/0! 4.68 3.91
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! 0 FID 37.36 6.03 0.00 31.05 0.00 13.64 #DIV/0! 4.57 3.69
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0!
121.63
#DIV/0!
128.80
#DIV/0!
136.39
#DIV/0!
50.00 59.51
0.00 #DIV/0! #DIV/0!
3% Cu/ZSM5
#DIV/0! #DIV/0!
1% Pt/Al2O3
#DIV/0! #DIV/0!
50.00 54.07 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
5% Mn/Al2O3
51.00 58.26 #DIV/0! #DIV/0!
3% Ru/Al2O3
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0! #DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
ZnCr2O4 before
after
0 #DIV/0! #DIV/0! FID #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0!
#DIV/0!
0.00 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
ZnCr2O4 before
after
0 #DIV/0! #DIV/0! FID #DIV/0!
0 #DIV/0! #DIV/0! TCD #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0!
#DIV/0!
0.00 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
ZnCr2O4 before 18.9 1645.59
after 18.03 1219.48 30.69 164.47 68.42 22.72 20.04 211.27
309.46
226.62 2.66 23.93
0 #DIV/0! 0 FID 29.29 6.58 0.00 33.37 0.00 14.66 #DIV/0! 5.27 4.63
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
101.51
#DIV/0! 50.00 63.65
#DIV/0! #DIV/0!
ZnCr2O4 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0!
Experiment of Meth
power @ 60 and 80W a frequency flow rate
20 kHz 30 mL/min
sample volume mole sample
500 uL 0 mol
6 CH4
reactan FID (flow rate) CH4 C2H2 C2H4 C2H6 C3H6 C3H8 iC4H10 nC4H10
before 27.61 232.25
C2H2 after
before
C2H4 after
before 27.83
28.3 195.31 0.58 0.37 4.00
6490.51
4.93 2.18 1.53
after 26.13 13.28 230 5828.42 50.18 39.66 69.69 86.85 236.21
TCD H2 conv. power V (kV) I (mA) total mol FID TCD calculation FID CH4 C2H2 C2H4 C2H6 C3H6 C3H8 iC4H10 nC4H10
98.08 13.80
15.70 2.83 40.23
0 0 FID 13.80 2.51 2.14 19.37 0.00 33.32 19.03 12.50
3.54 28.55
0
TCD
0 #DIV/0! FID #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0
0
0
0 TCD
FID
TCD
1.12 21.06 15.70 4.35 3.67 6.38 8.57 23.43
TCD 4.40 power (Watt) RMS integration C total H total
50.00
#DIV/0! 60.00 113.77
88.87 102.59
0.00 60.00 0.00
#DIV/0! #DIV/0!
60.00 100.95 68.58 39.96
8 CH4
reactan before
C2H2 after
before
C2H4 after
before
after
FID CH4 C2H2 C2H4 C2H6 C3H6 C3H8 iC4H10 nC4H10
27.61 232.25
28.4 178.6 0.63 0.71 5.10 0.45 3.76 1.41 1.28
30.54 6531.64
30.07 216.17 5834.66 3.80
23.49
146.98
13.48 61.68 95.58
21.36 5.21 20.75 90.34 3.09 3.25 5.50 3.39 12.65
TCD 4.40 conv. power (RMS) V (kV) I (mA) total mol FID TCD calculation FID 8.42 25.53 25.66 29.40 42.13 42.98 43.77 51.25
106.56 20.90
22.79 12.05
2.85 23.74 0
0
0 FID
TCD
2.09 1.80 2.70 16.38 1.89 16.86 8.16 6.92
86.89 44.11
3.74 35.40 0 0 FID 24.99 12.05 12.02 0.00 1.70 0.00 8.32 12.95
2.79 23.90
0
0
0
0 TCD
FID
0 TCD
2.02 21.82 44.11 3.65 5.03 9.08 7.22 25.21
TCD 4.40 power RMS integration C total H total
report 60 W Conversion H2
36.01
12.79 80.00 67.56
54.71 69.32
CH4 13.80
21.62 80.00 132.43
59.99 33.53
C2H2
80.00 66.59 74.03 78.60
C2H4 15.70
50.00
0.00
C2H2
2.51
21.06
C2H4
2.14
15.70
C2H6
19.37
4.35
C3H6 C3H8 iC4H10 nC4H10
0.00 33.32 19.03 12.50
3.67 6.38 8.57 23.43
80 W Conversion H2
20.90
12.05
44.11
36.01
12.79
21.62
C2H2
1.80
12.05
21.82
C2H4
2.70
12.02
44.11
C2H6
16.38
0.00
3.65
C3H6 C3H8 iC4H10 nC4H10
1.89 16.86 8.16 6.92
1.70 0.00 8.32 12.95
5.03 9.08 7.22 25.21
C2H6 C3H6 C3H8 i-C4H10 n-C4H10
13.85 14.72 16.38 3.60 16.86 16.48 19.87 87.91
2.70 3.38 1.89 1.86 4.16 3.92
12.02 19.76 1.70 18.72 20.64 15.95 88.80
50 40
Selectivity (%)
C2H4
30 20 10 0
H4 C2
H6 C2
H6 C3
H8 C3
Compounds
Experiment of Methane Kinetic Conversion power @ 60 and 80W and flowrate @ 30 mL/min
60 Watt C2H6 before 27.68
6901.19
C3H6 after 28.39 33.16 4.28 5.30 6094.11 15.46 84.93 6.25 99.47
before 29.49
9706.08
C3H8 after 29.29 24.89 5.56 6.46 32.30 8810.13 220.01 120.77 69.81
42.34 9.84 3.08 31.28 0
0
TCD
5.10 13.51 22.31 9.43 2.60 14.14 1.12 17.94
2.37 10.85 16.81 3.15 9.84 22.65 13.41 7.79
31.61
30.47 60.00 96.31
259.06
16.67 3.39 49.55
0 0 FID 10.04 4.11 17.70 8.30 33.19 11.73 1.52 0.00
0
60.00 111.03
0 0
TCD
FID 4.64 9.26 15.83 6.50 18.83 8.20 16.67 46.82
70.35
77.03 73.32
before 28.21
70
0
0 FID
76.71 75.53
32.5 9.62 1.45 4.69 2.61 7.97 169.36 0.26 0.00
11.73 3.28 33.84
0
FID
215.22
after
44
9.43
0
before 28.98
iC4H10
81.99 51.00 167.97
74.85 111.37
110.08 146.79
80 Watt C2H6 before
C3H6 after
before
C3H8 after
before
iC4 after
before
27.33
6901.19
28.58 112.22 5.81 9.76 5448.36 32.64 172.20 26.81 199.70
30.04
9706.08
29.46 52.38 9.73 11.12 56.52 8041.06 258.56 171.47 106.11
78.36 17.45
0
0
TCD
9.51 10.10 22.63 17.45 3.02 15.80 2.65 19.85
2.58 9.84 15.00 2.86 18.75 13.80 9.87 6.13
32.23
15.79 80.00 105.33
91.50 84.49
C2H6 9.43
0
0 FID
C3H6 9.84
29.68
259.06
92.82 15.23 2.75 23.45 0 0 FID 12.63 6.93 33.27 10.96 39.23 12.90 2.36 1.34
0
0 0
TCD
FID 4.77 2.36 4.67 4.04 18.42 7.00 15.23 34.47
85.81 80.00 124.84
76.25 53.59
34.68 13.15 2.66 9.58 3.74 10.24 165.22 0.45 0.27
12.90 3.61 34.60
0
FID
215.00
44 18.75
3.26 32.36 0
30.6
0.00 80.00 64.51
106.71 142.23
75.73 46.45
C3H8 11.73
iC4H10 16.67
31.61
30.47
70.35
81.99
13.51
10.85
4.11
9.26
22.31
16.81
17.70
15.83
9.43
3.15
8.30
6.50
2.60 14.14 1.12 17.94
9.84 22.65 13.41 7.79
33.19 11.73 1.52 0.00
18.83 8.20 16.67 46.82
17.45
18.75
12.90
15.23
32.23
15.79
85.81
0.00
10.10
9.84
6.93
2.36
22.63
15.00
33.27
4.67
17.45
2.86
10.96
4.04
3.02 15.80 2.65 19.85
18.75 13.80 9.87 6.13
39.23 12.90 2.36 1.34
18.42 7.00 15.23 34.47
Column B Column D
H6 C2
H6 C3
H8 C3
Compounds
10 4H i-C
10 4H n-C
iC4H10
nC4H10 after 37.48 8.3 6.10 7.82 3.81 8.44 3.45 162.49 16.28
before 27.35
245.85
114.15 190.58
after 29.17 5.56 3.50 5.56 3.67 4.48 4.50 7.42 211.26
8.37
2.77 24.88 0
0
0
0 TCD
FID
0 TCD
5.61 9.57 20.27 11.29 18.01 19.31 41.13 8.37
0.00 60.00 68.79
60.00 0.00 125.19 61.82
iC4H10
nC4H10 after
before
after
31.83 9.64 1.76 2.61 2.68 9.33 3.33 204.79 13.56
27.35
245.85
29.17 5.56 3.50 5.56 3.67 4.48 4.50 7.42 211.21
8.39 2.47 24.31 0
0
0
0 TCD
FID
TCD
5.59 9.55 20.22 11.26 17.96 19.26 41.01 8.39
0.00 80.00 0.00
80.00 60.12 124.84 61.67
iC4H10
nC4H10 8.37 0.00 9.57 20.27 11.29 18.01 19.31 41.13 8.37
8.39 0.00 9.55 20.22 11.26 17.96 19.26 41.01 8.39
Experiment of Meth
power @ 60 and 80W a frequency flow rate
20 kHz 30 mL/min
sample volume mole sample
500 uL 0 mol
6 CH4
reactan FID (flow rate) CH4 C2H2 C2H4 C2H6 C3H6 C3H8 iC4H10 nC4H10
before 27.61 232.25
C2H2 after
before
C2H4 after
before 27.83
28.3 195.31 0.58 0.37 4.00
after 26.13 13.28 230 5828.42 50.18 39.66 69.69 86.85 236.21
6490.51
4.93 2.18 1.53
TCD H2 conv. power V (kV) I (mA) total mol FID TCD calculation FID CH4 C2H2 C2H4 C2H6 C3H6 C3H8 iC4H10 nC4H10
98.08 13.80
15.70 2.83 40.23
0
3.54 28.55
0
0 FID concentration 13.80 86.20 2.51 0.17 2.14 0.15 19.37 1.34 0.00 0.00 33.32 1.53 19.03 0.66 12.50 0.43
0
0
#DIV/0! FID concentration #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0
0
0 FID 1.12 21.06 15.70 4.35 3.67 6.38 8.57 23.43
concentration 2.67 3.31 84.30 0.68 0.38 0.67 0.67 1.84
TCD 4.40 power (Watt) RMS integration C total H total
50.00
13.80
#DIV/0!
60.00 113.77 88.87 102.59
90.48 101.12
0.00 60.00 0.00
#DIV/0! #DIV/0!
0.00 0.00
0.00 60.00 100.95
68.58 39.96
94.52 97.84
8 CH4
reactan before
C2H2 after
before
C2H4 after
before
after
FID CH4 C2H2 C2H4 C2H6 C3H6 C3H8 iC4H10 nC4H10
27.61 232.25
28.4 178.6 0.63 0.71 5.10 0.45 3.76 1.41 1.28
30.54 6531.64
30.07 216.17 5834.66 3.80
23.49
24.36 5.21 20.75 90.34 3.09 3.25 5.50 3.39 12.65
146.98
13.48 61.68 95.58
TCD 4.40 conv. power (RMS) V (kV) I (mA) total mol FID TCD calculation FID 8.42 25.53 25.66 29.40 42.13 42.98 43.77 51.25
106.56 20.90
22.79 12.05
2.85 23.74 0
0
0 FID 2.09 1.80 2.70 16.38 1.89 16.86 8.16 6.92
concentration 79.10 0.19 0.28 1.71 0.13 1.17 0.43 0.36
86.89 36.26
3.74 35.40 0
2.79 23.90
0
0 FID concentration 24.99 6.02 12.05 87.95 12.02 1.45 0.00 0.00 1.70 0.14 0.00 0.00 8.32 0.50 12.95 0.78
0
0
0
0 concentration 1.16 6.24 63.74 1.05 0.96 1.73 1.03 3.61
FID 2.80 30.27 36.26 5.07 6.98 12.60 10.02 34.97
TCD 4.40 power RMS integration C total H total
report 60 W
36.01
15.05
12.79
80.00 67.56 54.71 69.32
83.38 94.09
3.08
29.99
80.00 132.43 59.99 33.53
96.84 112.79
80.00 66.59 102.71 96.58
86.20
0.00
50.00
13.80
0.00
0.00
0.00
2.51
0.17
0.00
21.06
3.31
C2H4
2.14
0.15
0.00
15.70
84.30
C2H6
19.37
1.34
0.00
4.35
0.68
C3H6 C3H8 iC4H10 nC4H10
0.00 33.32 19.03 12.50
0.00 1.53 0.66 0.43
0.00 0.00 0.00 0.00
3.67 6.38 8.57 23.43
0.38 0.67 0.67 1.84
C2H2
C2H4 15.70
79.51 92.27
CH4 13.80
Conversion H2
C2H2
12.37
2.67
80 W Conversion H2
20.90
79.10
12.05
6.02
36.26
1.16
36.01
15.05
12.79
3.08
29.99
12.37
C2H2
1.80
0.19
12.05
87.95
30.27
6.24
C2H4
2.70
0.28
12.02
1.45
36.26
63.74
C2H6
16.38
1.71
0.00
0.00
5.07
1.05
C3H6 C3H8 iC4H10 nC4H10
1.89 16.86 8.16 6.92
0.13 1.17 0.43 0.36
1.70 0.00 8.32 12.95
0.14 0.00 0.50 0.78
6.98 12.60 10.02 34.97
0.96 1.73 1.03 3.61
Reactan
Products concentration [%] C2H6 C3H6
CH4
C2H2
C2H4
C3H8
0.45
2.04
0.00
0.93
CH4
86.20
0.17
C2H2
3.03
81.95
1.45
0.00
0.14
0.00
C2H4
2.67
3.31
84.30
0.68
0.38
0.67
C2H6
0.96
1.27
2.10
90.57
0.16
0.89
C3H6
0.70
1.60
2.48
0.46
80.16
2.23
C3H8
2.31
0.47
2.03
0.95
2.54
88.27
iC4H10
2.36
2.35
4.02
1.65
3.19
1.39
nC4H10
1.27
1.08
2.29
1.28
1.36
1.46
4.0 61.9 26.1 15.3 7.7 27.5 11.3 11.5
32.4 20.2 17.7 5.6 11.2 9.8 0.35
3.03 2.67 0.96 0.70 2.31 2.36 1.27
6.61 2.55 3.2 0.94 4.7 2.17 3.2
40.6 11.2 6.6 3.1 13.4 4.2 4.5
27.7 17.6 14.1 5.5 8.4 7.6
10.5 29.6 33.4 27.5 24.2 19.2 20.7 0.9 2.9 4.21 4.97 4.07 8.04 4.59 8.3 38.8 29.1 21.8 23.6 14.4 16.2
47.6 0.0 6.7 5.1 11.4 7.9 11.5 4.08 0 1.37 0.93 1.91 3.3 2.55 37.5 0.0 5.7 4.1 11.1 5.9 9.0
0.0 2.8 3.8 2.6 30.3 15.3 12.3 0 0.41 1.15 0.49 7.63 9.56 4.07 0.0 5.5 4.8 3.4 44.3 17.1 14.4
21.7 0.0 6.5 14.1 24.7 6.6 13.2 2.79 0 2 2.67 6.69 4.17 4.37 25.6 0.0 8.4 18.4 29.4 7.5 15.4
Reactan
Conversion [%]
CH4
C2H2
C2H4
Products concentration [%] C2H6 C3H6
CH4
13.8
86.20
0.17
0.45
2.04
0.00
C2H2
12.0
3.03
81.95
1.45
0.00
0.14
C2H4
15.7
2.67
3.31
84.30
0.68
0.38
C2H6
9.4
0.96
1.27
2.10
90.57
0.16
C3H6
9.8
0.70
1.60
2.48
0.46
80.16
C3H8
11.7
2.31
0.47
2.03
0.95
2.54
iC4H10
16.7
2.36
2.35
4.02
1.65
3.19
nC4H10
8.4
1.27
1.08
2.29
1.28
1.36
Experiment of Methane Kinetic Conversion power @ 60 and 80W and flowrate @ 30 mL/min
60 Watt C2H6 before 27.68
C3H6 after 28.39 33.16 4.28 5.30 6094.11 15.46 84.93 6.25 99.47
6901.19
before 29.49
C3H8 after 29.29 24.89 5.56 6.46 32.30 8810.13 220.01 120.77 69.81
9706.08
42.34 9.84
0
0 5.10 13.51 22.31 9.43 2.60 14.14 1.12 17.94
31.61
5.96
2.37 10.85 16.81 3.15 9.84 22.65 13.41 7.79
concentration 0.70 1.60 2.48 0.46 90.16 2.23 0.99 0.57
30.47
60.00 96.31 76.71 75.53
96.86 97.87
6.00
99.20 100.86
16.67
0
0
0 FID concentration 10.04 2.31 4.11 0.47 17.70 2.03 8.30 0.95 33.19 2.54 11.73 88.27 1.52 0.09 0.00 0.00
70.35
60.00 111.03 77.03 73.32
259.06
3.39 49.55
0
0 FID
before 28.21
70
3.28 33.84
0
concentration 0.96 1.27 2.10 90.57 0.16 0.89 0.05 0.85
32.5 9.62 1.45 4.69 2.61 7.97 169.36 0.26 0.00
11.73
3.08 31.28
FID
215.22
after
44
9.43
0
before 28.98
iC4H10
10.78
0 0 FID 4.64 9.26 15.83 6.50 18.83 8.20 16.67 46.82
81.99
51.00 167.97 74.85 111.37
96.66 95.98
110.08 146.79
80 Watt C2H6 before
C3H6 after
before
C3H8 after
before
iC4 after
before
27.33
28.58 112.22 5.81 9.76 5448.36 32.64 172.20 26.81 199.70
6901.19
30.04
29.46 52.38 9.73 11.12 56.52 8041.06 258.56 171.47 106.11
9706.08
78.36 17.45
0
0 9.51 10.10 22.63 17.45 3.02 15.80 2.65 19.85
0
0 concentration 3.32 1.76 3.95 82.55 0.35 1.84 0.23 1.73
32.23
11.25
FID 2.58 9.84 15.00 2.86 18.75 13.80 9.87 6.13
concentration 1.45 2.77 4.22 0.80 81.25 2.59 1.39 0.86
15.79
80.00 105.33 91.50 84.49
C2H6 9.43
95.74 97.81
0.96
5.92
C3H6 9.84
95.33 95.93
259.06
15.23 2.75 23.45
0
0
0 FID concentration 12.63 3.19 6.93 0.87 33.27 4.20 10.96 1.38 39.23 3.30 12.90 87.10 2.36 0.15 1.34 0.08
85.81
80.00 124.84 76.25 53.59
29.68
92.82
3.61 34.60
0
34.68 13.15 2.66 9.58 3.74 10.24 165.22 0.45 0.27
12.90
3.26 32.36
FID
215.00
44 18.75
0
30.6
14.44
0 0 FID 4.77 2.36 4.67 4.04 18.42 7.00 15.23 34.47
0.00
80.00 64.51 106.71 142.23
0.70
C3H8 11.73
100.28 98.43
2.31
75.73 46.45
iC4H10 16.67
31.61
5.96
30.47
6.00
70.35
10.78
81.99
13.51
1.27
10.85
1.60
4.11
0.47
9.26
22.31
2.10
16.81
2.48
17.70
2.03
15.83
9.43
90.57
3.15
0.46
8.30
0.95
6.50
2.60 14.14 1.12 17.94
0.16 0.89 0.05 0.85
9.84 22.65 13.41 7.79
90.16 2.23 0.99 0.57
33.19 11.73 1.52 0.00
2.54 88.27 0.09 0.00
18.83 8.20 16.67 46.82
17.45
3.32
18.75
1.45
12.90
3.19
15.23
32.23
11.25
15.79
5.92
85.81
14.44
0.00
10.10
1.76
9.84
2.77
6.93
0.87
2.36
22.63
3.95
15.00
4.22
33.27
4.20
4.67
17.45
82.55
2.86
0.80
10.96
1.38
4.04
3.02 15.80 2.65 19.85
0.35 1.84 0.23 1.73
18.75 13.80 9.87 6.13
81.25 2.59 1.39 0.86
39.23 12.90 2.36 1.34
3.30 87.10 0.15 0.08
18.42 7.00 15.23 34.47
Atom balance Cout/Cin Hout/Hin
iC4H10
nC4H10
0.26
0.43
0.95
1.01
0.00
0.28
0.87
1.13
0.67
1.84
0.95
0.98
0.05
0.85
0.97
0.98
0.99
0.57
0.89
1.01
0.09
0.00
0.97
0.96
83.33
5.94
1.04
1.00
2.33
91.63
1.03
0.98
6.1 0.0 6.6 0.8 10.9 1.0
10.1 5.7 18.0 13.4 6.4 0.0 28.4
21.0 1.04 0 2.69 0.21 3.96 0.35 0 9.3 9.6 0.0 11.3 1.5 17.4 2.0 32.9
1.73 1.12 7.35 3.38 2.3 0 23.78 0 15.9 15.0 30.8 23.4 10.1 0.0 42.5
ntration [%] C3H8
iC4H10
nC4H10
Atom balance Cout/Cin Hout/Hin [1]
0.93
0.26
0.43
0.95
1.01
0.00
0.00
0.28
0.87
1.13
0.67
0.67
1.84
0.95
0.98
0.89
0.05
0.85
0.97
0.98
2.23
0.99
0.57
0.89
1.01
88.27
0.09
0.00
0.97
0.96
1.39
83.33
5.94
1.04
1.00
1.46
2.33
91.63
1.03
0.98
iC4H10
nC4H10 after 37.48 8.3 6.10 7.82 3.81 8.44 3.45 162.49 16.28
before 27.35
after 29.17 5.56 3.50 5.56 3.67 4.48 4.50 7.42 211.26
245.85
114.15 190.58
8.37
2.77 24.88 0
0
0
0 concentration 2.36 2.35 4.02 1.65 3.19 1.39 83.33 5.94
20.82
FID 5.61 9.57 20.27 11.29 18.01 19.31 41.13 8.37
concentration 1.27 1.08 2.29 1.28 1.36 1.46 2.33 91.63
0.00
60.00 68.79 104.23 100.47
0.00 60.00 0.00
125.19 61.82
iC4H10
102.69 98.34
nC4H10 after
before
after
31.83 9.64 1.76 2.61 2.68 9.33 3.33 204.79 13.56
27.35
29.17 5.56 3.50 5.56 3.67 4.48 4.50 7.42 211.21
245.85
8.39 2.47 24.31 0
0
0
0 concentration 2.21 0.55 1.08 0.94 2.85 1.08 84.77 4.00
0.00
FID 5.59 9.55 20.22 11.26 17.96 19.26 41.01 8.39
concentration 1.27 1.08 2.29 1.28 1.36 1.46 2.33 91.61
0.00
80.00 0.00 97.48 93.33
iC4H10
0.00 80.00 60.12
124.84 61.67
102.67 98.32
nC4H10 8.37
1.27
20.82
0.00
0.00
2.35
9.57
1.08
4.02
20.27
2.29
1.65
11.29
1.28
3.19 1.39 83.33 5.94
18.01 19.31 41.13 8.37
1.36 1.46 2.33 91.63
2.36
2.21
8.39
1.27
0.00
0.00
0.00
0.55
9.55
1.08
1.08
20.22
2.29
0.94
11.26
1.28
2.85 1.08 84.77 4.00
17.96 19.26 41.01 8.39
1.36 1.46 2.33 91.61
60W
0.74
0.06 0 1.79 0.3 0.23 0.97 0.67 1.07
0.18 0.17 0 1.03 0.33 0.16 1.28 2.27
0.5 0.18 0.01 0 0.14 0.49 0.89 0.39
0.02 0.31 0.22 0.07 0 0.48 1.28 1.05
0.3 0.06 0.02 0.67 0.53 0 1.45 0.33
0.13 0.14 0.25 0.15 0.54 0.7 0 1.38
0 0 0.03 4.33 5.24 0.04 1.44 0.63
0.11 0 0.49 0.04 0.39 0.37 0.95 6.79
0.01 4.29 0 0.13 0.12 0.41 1.71 0.6
0.17 3.86 0.05 0 0.16 0.14 5.28 0.73
0.05 2.39 0.01 2.96 0 1.04 0.04 0.14
0.22 0.82 0.09 0.43 1.85 0 0.88 2.25
0.03 5.84 0.02 0.05 0.84 0.42 0 0.79
0 0.42 0.07 2.87 0.79 1.96 0.68 0.19
0.08 0 0.24 0.35 1.31 2.02 1.93 0.24
0.42 2.57 0 0.61 0.83 1 2.82 2.9
0.2 0.43 0 0 1.1 0.68 1.21 0.93
0.01 0.97 0.14 1.72 0 0.97 0.89 2.02
0.55 3.03 0.03 4.21 0.76 0 1.01 0.01
0.13 0.77 0.26 0.25 0.49 1.65 0 1.09
0 1.82 0.08 0 0.15 1.06 0.79 0.61
0.1 0 0.12 0.16 2.01 1.3 2.11 0.24
0.57 2.54 0 0 0.6 0.89 2.47 1.78
0.2 0.54 0 0 2.53 0.12 2.55 0.47
0.01 1.82 0.21 0 0 1.2 0.48 1.52
0.92 0.59 0 0.01 0.08 0 3.34 0
0.34 0.59 0.6 0.21 0.99 1.06 0 0.14
0 0.32 0.1 0 0.02 0.03
0.03 0 0.29 0.18 0 3.02
0.4 0.61 0 0 0.17 0.2
0.17 1.03 0 0 0 0.19
0.01 0.6 0.15 0 0 0.02
0.6 0.4 0 0 0.13 0
0.33 1.09 5.29 0.17 0 1.21
0 1.31 0.08 0.11 0.09 0.06 0.06
CH4
C2H4
C2H6
C3H6
0.88 1.02
6.68 0.08
0.75 4
2.02 0.29
0.14 2.72
1.9 0
0 0.2
0 0.3 0.23 0 0.03 0.05 2.75 1.76
0.05 0 0.17 0.26 0 0.04 0.01 0.03
0.19 0.53 0 0 0.12 0.11 0.88 4.2
0.26 0.45 0 0 0 0 2.03 0.1
0.01 1.89 0.45 0 0 0.07 0.28 5.2
0.29 0.61 0 0 0.22 0 2.87 0.01
0.01 1.29 1.87 0.21 0 0.19 0 0.17
0 0.07 0.02
0.02 0 0.23
0.32 0.67 0
0.19 0.71 0
0.02 0.8 0.37
0.38 0.6 0
0.02 0.41 2.56
0 0.02 0.04 0.07 0.92
0.5 0 0.03 0.01 0.06
0 0.2 0.46 0.15 2.35
0 0 0 0.06 0.19
0 0 0.01 0.05 2.69
0 0.38 0 0.05 0.01
0.09 0 0.19 0 0.23
0 0.06 0.02 0 0.05 0.03 0.08 0.05
0.03 0 0.18 0.6 0 0.02 0 0.06
0.17 0.72 0 0 0.26 0.35 0.21 0.08
0.08 1.26 0 0 0 0 0.08 0.02
0.02 0.7 0.2 0 0 0.02 0.06 0.04
0.52 0.71 0 0 0.29 0 0.11 0.01
0.02 0.35 1.94 0.09 0 0.2 0 0.05
C3H8
iC4H10
n-C4H10
0.29 1.47 1.01 0.94 0.53 0.97 2.45 0
0 0.47 0.03 3.53 0.13 2.39 6.18 0
0.4 0.13 0.02 0.25 0.59 3.28 4.14 0
0.6 0.1 0.01 0 0.4 0.03 3.86 0
0.89 0.06 0.02 0 0.04 0.02
1 2 3 4 5 6 7 8
1 0.0 8.1 8.5 17.3 21.8 13.5 20.6 7.2
2 5.3 0.0 8.6 6.1 35.1 11.3 36.2 21.8
3 11.6 12.0 0.0 9.2 7.8 28.2 7.7 6.4
4 6.5 8.4 18.9 0.0 7.0 8.1 21.7 8.0
5 7.5 38.6 6.2 18.0 0.0 10.8 8.2 18.3
2.18 0
0.04 0.08 0.01 0 0.04 0.02 0.26 0
0.06 0.04 0 0 0.14 0.07 0.32 0
0.04 0.07 0 0 0.1 0.05 0.23 0
6 9.8 20.7 15.6 21.7 10.9 0.0 8.3 23.8
7 10.7 16.1 9.1 4.7 8.5 7.9 0.0 7.7
8 11.1 9.1 9.9 13.7 7.1 13.3 8.9 0.0
kij
i
(1) CH4
(2) C2H2
(1) CH4
0
( 0.0
)
0.06
( 5.3
)
(2) C2H2
1.31
( 8.1
)
0
( 0.0
)
(3) C2H4
0.08
( 8.5
)
1.79
( 8.6
)
(4) C2H6
0.11
( 17.3 )
0.3
( 6.1
)
(5) C3H6
0.09
( 21.8 )
0.23
( 35.1 )
(6) C3H8
0.06
( 13.5 )
0.97
( 11.3 )
(7) i-C4H10
0.06
( 20.6 )
0.67
( 36.2 )
(8) n-C4H10
0.74
( 7.2
1.07
( 21.8 )
)
j (3) C2H4
(4) C2H6
(5) C3H6
(6) C3H8
0.18
( 11.6 )
0.5
( 6.5
)
0.02
( 7.5
)
0.3
0.17
( 12.0 )
0.18
( 8.4
)
0.31
( 38.6 )
( 9.8
(7) i-C4H10
(8) n-C
)
0.13
( 10.7 )
0.29
0.06
( 20.7 )
0.14
( 16.1 )
1.47
0
( 0.0
)
0.01
( 18.9 )
0.22
( 6.2
)
0.02
( 15.6 )
0.25
( 9.1
)
1.01
1.03
( 9.2
)
0
( 0.0
)
0.07
( 18.0 )
0.67
( 21.7 )
0.15
( 4.7
)
0.94
0.33
( 7.8
)
0.14
( 7.0
)
0
( 0.0
)
0.53
( 10.9 )
0.54
( 8.5
)
0.53
0.16
( 28.2 )
0.49
( 8.1
)
0.48
( 10.8 )
0
( 0.0
)
0.7
( 7.9
)
0.97
1.28
( 7.7
)
0.89
( 21.7 )
1.28
( 8.2
)
1.45
( 8.3
)
0
( 0.0
)
2.45
2.27
( 6.4
)
0.39
( 8.0
1.05
( 18.3 )
0.33
( 23.8 )
1.38
( 7.7
)
0
)
(8) n-C4H10 ( 11.1 ) ( 9.1
)
( 9.9
)
( 13.7 ) ( 7.1
)
( 13.3 ) ( 8.9
)
( 0.0
)
FID (area) 1.99 0 5.79 3.39 16.23 8.66 9 29.4 42.13 28.19 43.77 32.9 33.87
0 0 1684.13 1640.49 1732.13 3056.34 3253.34 3279.95 4454.86 4232.11 4433.96 5654.26 5165.35
calibration data (area method) H2 729.54 727.39 150.17 149.68 O2 843.81 86.76 101.73 CO CH4
tR (min)
tR (min)
TCD 4.4 2.5 5.72 3.36 16.15 8.63 8.97 29.36 42.08 28.17 43.72 32.87 33.84
1169.95 98.18 98.79 248.79 94.18 192.9 185.84 384.73 402.9 308.94 339.57 324.09 281.9
FID (height)
232.25 161.3 146.98 306.61 351.59 329.66 340.22 363.87
728.47 149.93 102.09
102.15
1639.77 248.53
1640.98 248.54
1640.69 249.26
1640.61 248.73
3006.26 192.71 3257.34 187.15
3075.96 193.81 3257.44 186.11
3086.79 192.17 3245.25 184.27
4193.32 316.98
4327.03 314.8
4327.72 299.64
5660.91 323.17 5486.82 296.72
5647.6 325.01 4843.88 267.08
98.18
1640.38 248.92
1640.49 248.79
CO2 C2H2 C2H4
3056.34 192.9 3253.34 185.84
C2H6 C3H6 C3H8
4080.38 304.34
4232.11 308.94
C3H4 iC4H10 nC4H10
calibration data (height method) CH4 232.28 232.21 C2H2 C2H4 146.88 146.94 C3H8 206.69 206.69 iC4H10 259.9 258.22 nC4H10 256.69 235.01
5654.26 324.09 5165.35 281.9
232.24 147.12 197.87
232.25
232.23
232.25 146.98 203.75 259.06 245.85
tR (min) H2 O2 CO CH4 CO2 C2H2 C2H4 C2H6 C3H6 C3H8 C3H4 iC4H10 nC4H10
FID (area) 0 0 64.09 3535.88 3400.25 6531.64 6490.51 6901.19 9706.08 9799.68
1.99 2.46 0 0 0 0 0 0 0 0
33.37 35.23
12117.36 12060.91
0 0
nC4H10
12070.94 339.5 12060.74 363.73
12163.77 340.93 12061.08 364.02
tR (min)
TCD
0 0 2.57 3.63 6.62 10.69 10.91 13.42 24.06 25.07
calibration data (area method) H2 729.54 727.39 150.17 149.68 O2 84.81 86.76 16.81 17.63 CO 63.99 64.19 12.75 12.84 CH4 3535.88 3535.88 467.46 467.46 CO2 3165.35 3635.15 212.53 239.31 C2H2 6520.06 6543.23 344.13 345.28 C2H4 6490.51 6490.51 258.45 258.45 C2H6 6865.79 6936.58 305.72 307.5 C3H6 9706.08 9706.08 351.59 351.59 C3H8 9731.27 9868.09 327.93 331.4 C3H4 iC4H10
tR (min)
728.47 85.78
FID (height) 1.99 2.46 2.57 3.63 6.62 10.69 10.91 13.42 24.06 25.07
149.93 17.22 12.8 467.46 225.92 344.71 258.45 306.61 351.59 329.66
33.37 35.23
340.22 363.87
728.47 149.93 85.78 17.22 64.09 12.8 3535.88 467.46 3400.25 225.92 6531.64 344.71 6490.51 258.45 6901.19 306.61 9706.08 351.59 9799.68 329.66
12117.36 340.22 12060.91 363.87
column Inject Detector 1 Detector 2 Aux 1 Aux 2
10ft Hayesep D + 10ft 10%Carbowax 180 oC 250 oC 250 oC 140 oC 350 oC
Temperature program 50oC 5 mins 5oC/min 220oC 3 mins Analysis conditions FID Threshold 0.01 Peak width 5 Peak area 0.75 Peak Height 0 Range Sense Attn
8 1 0
TCD 0.01 5 0.5 0 0 4 0
Experiment of Methane Kinetic Conversion power @ 60 and 80W and flowrate @ 30 mL/min frequency flow rate power
20 kHz 30 mL/min 60 W (Metex)
CH4
reactant FID (flow rate) 8.42 25.53 25.66 29.40 42.13 42.98 43.77 51.25 53.31 TCD 4.40 8.39 power V (kV) I (mA) total mol FID TCD calculation FID 8.42 25.53 25.66 29.40 42.13 42.98 43.77 51.25 53.31 TCD 4.40 power (Watt) RMS integration C total H total
sample volume mole sample
before 29.19 1744.71
500 uL 0 mol
Al2O3 after 29.88 1583.17 18.81
before
ZSM5 after
before
after
71.79 29.21
312.87
72.57 281.47 2.77 24.82
0 #DIV/0! 0 FID 7.12 16.79 0.00 60.65 0.00 26.07 #DIV/0! 0.00 0.00
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! #DIV/0! FID #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! #DIV/0! FID #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
145.20
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
50.00 68.85 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
0.00 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
0.00 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
2n reactant
CH4 before
FID 8.42 25.53
Al2O3
20 1767.31
after 19 1530.75 22.84
before 70.88 1566.43
ZSM5 after 70.18 1368.43 19.56
before 62.95 1583.33
after 62.63 1384.03 18.78
25.66 29.40 42.13 42.98 43.77 51.25 53.31
105.31 17.75 50.60
81.12
81.58
30.62
32.21
14.60 12.33
TCD 4.40 8.39 power (RMS) V (kV) I (mA) total mol FID TCD calculation FID 8.42
0 #DIV/0! 0 FID 17.72
0 #DIV/0! #DIV/0! TCD #DIV/0!
0 #DIV/0! 0 FID 13.51
0 #DIV/0! #DIV/0! TCD #DIV/0!
0 #DIV/0! 0 FID 13.03
0 #DIV/0! #DIV/0! TCD #DIV/0!
25.53 25.66 29.40 42.13 42.98 43.77 51.25 53.31
7.50 0.00 32.74 5.88 16.62 #DIV/0! 5.20 4.37
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
9.91 0.00 38.89 0.00 15.51 #DIV/0! 0.00 0.00
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
9.81 0.00 40.33 0.00 16.82 #DIV/0! 0.00 0.00
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
78.47
#DIV/0!
92.46
#DIV/0!
101.74
#DIV/0!
307.64
106.56 264.30
276.56
2.85 23.74
81.43 237.60
278.62
2.79 23.67
86.89 242.06 2.79 23.90
TCD 4.40 power RMS integration C total H total
48.00 67.56 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
49.00 66.06 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
50.00 66.59 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
3rd reactant FID 8.42 25.53 25.66 29.40 42.13 42.98 43.77 51.25 53.31
Al2O3
CH4 before 105.47 1362.24
after 106.11 1070.21 17.78
before 104.67 1329.94
ZSM5 after 105.16 1062.81 16.29
before 117.05 1358.6
after 120.52 1079.62 23.45
95.57
101.06
102.63
48.91
42.08
42.20
11.69
TCD 4.40
133.49
149.43
140.95
8.39 power (RMS) V (kV) I (mA) total mol FID TCD calculation FID 8.42 25.53 25.66 29.40 42.13 42.98 43.77 51.25 53.31 TCD 4.40 power RMS integration C total H total
report < 10%
246.40
192.88
240.66
2.60 21.50
190.17
243.69
2.86 15.18
191.94 2.62 23.93
0 #DIV/0! 0 FID 20.96 6.78 0.00 34.50 0.00 18.65 #DIV/0! 0.00 0.00
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! 0 FID 19.71 6.76 0.00 39.69 0.00 17.45 #DIV/0! 0.00 0.00
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! 0 FID 18.18 10.58 0.00 43.84 0.00 19.04 #DIV/0! 0.00 5.69
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
114.13
#DIV/0!
138.97
#DIV/0!
142.61
#DIV/0!
50.00 55.92 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
50.00 43.46 #DIV/0! #DIV/0!
Al2O3
#DIV/0! #DIV/0!
50.00 62.72 #DIV/0! #DIV/0!
CH4 conv.
empty #DIV/0!
#DIV/0!
ZSM5 #DIV/0!
H2
#DIV/0!
#DIV/0!
#DIV/0!
C2H2
#DIV/0!
#DIV/0!
#DIV/0!
C2H6
#DIV/0!
#DIV/0!
#DIV/0!
C3H8
#DIV/0!
#DIV/0!
#DIV/0!
C4
#DIV/0!
#DIV/0!
#DIV/0!
10-20% CH4 conv.
#DIV/0!
#DIV/0!
#DIV/0!
H2
#DIV/0!
#DIV/0!
#DIV/0!
C2H2
#DIV/0!
#DIV/0!
#DIV/0!
C2H6
#DIV/0!
#DIV/0!
#DIV/0!
C3H8
#DIV/0!
#DIV/0!
#DIV/0!
C4
#DIV/0!
#DIV/0!
#DIV/0!
> 20% CH4 conv.
#DIV/0!
#DIV/0!
#DIV/0!
H2
#DIV/0!
#DIV/0!
#DIV/0!
C2H2
#DIV/0!
#DIV/0!
#DIV/0!
C2H6
#DIV/0!
#DIV/0!
#DIV/0!
C3H8
#DIV/0!
#DIV/0!
#DIV/0!
0.4
#DIV/0!
0.33
#DIV/0! #DIV/0!
C4
#DIV/0!
#DIV/0!
#DIV/0!
e Kinetic Conversion
flowrate @ 30 mL/min
1st trial 3% Fe/Al2O3 before 59.94 1539.94
after 59.48 1462.41
3% Fe/ZSM5 before after
3% Cu/Al2O3 before
after
3% Cu/ZSM5 before 29.14 1654.38
51.25
30.82 265.69
280.81
314.29
2.61 24.02 0 #DIV/0! 0 FID 5.76 0.00 0.00 58.77 0.00 0.00 #DIV/0! 0.00 0.00
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! #DIV/0! FID #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! #DIV/0! FID #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! 0 FID 8.42 0.00 0.00 60.51 0.00 25.49 #DIV/0! 0.00 0.00
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
166.40
83.70
35.00 62.60 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
51.00 0.00
0.00 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
2nd trial 3% Fe/Al2O3 before 55.49 1525.45
after 55.79 1337.47 18.89
3% Fe/ZSM5 before 383.61 772.02
after 386.32 648.66 16.31
3% Cu/Al2O3 before 62.14 1596.97
after 58.16 1384.14 17.97
3% Cu/ZSM5 before
78.17
45.70 5.63 19.07
26.66
88.63 32.35
4.88 5.55 85.64 242.95
278.71
58.61 108.83
128.98
2.77 24.14
92.82 240.07
278.40
2.89 24.21
2.75 23.45
0 #DIV/0! 0 FID 11.85
0 #DIV/0! #DIV/0! TCD #DIV/0!
0 #DIV/0! 0 FID 15.39
0 #DIV/0! #DIV/0! TCD #DIV/0!
0 #DIV/0! 0 FID 18.89
0 #DIV/0! #DIV/0! TCD #DIV/0!
0 #DIV/0! #DIV/0! FID #DIV/0!
11.37 0.00 44.54 0.00 16.04 #DIV/0! 0.00 0.00
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
14.97 0.00 39.70 5.22 17.50 #DIV/0! 4.85 5.49
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
6.04 0.00 28.18 0.00 10.87 #DIV/0! 0.00 0.00
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
115.56
#DIV/0!
120.60
#DIV/0!
69.90
#DIV/0!
#DIV/0!
49.00 66.87 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
48.00 69.85 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
51.00 64.51 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
3rd trial 3% Fe/Al2O3 before 20.04 1714.32
3% Cu/Al2O3
3% Fe/ZSM5
after 20.1 1289.47 36.67
before 28.2 1683.23
after 24.61 1485.66
before 118.43 1390.88
3% Cu/ZSM5
after 115.26 1077.8 20.88
163.43
74.57
94.80
72.16
28.78
37.85
23.48 18.19 192.57
82.68
139.72
before
294.93
218.64
310.54
280.90
2.80 24.37 0 #DIV/0! 0 FID 24.56 9.46 0.00 39.90 0.00 18.61 #DIV/0! 6.56 5.06
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
111.34
#DIV/0!
3% Fe/Al2O3
#DIV/0! #DIV/0!
195.28
2.85 25.42 0 #DIV/0! 0 FID 22.97 0.00 0.00 17.25 0.00 7.03 #DIV/0! 0.00 0.00 45.29
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
50.00 68.33 #DIV/0! #DIV/0!
254.30
2.52 24.14 0 #DIV/0! 0 FID 24.58 6.43 0.00 27.65 0.00 11.66 #DIV/0! 0.00 0.00
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! #DIV/0! FID #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0!
#DIV/0!
96.52
50.00 72.50 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
49.00 60.88 #DIV/0! #DIV/0!
3% Cu/Al2O3
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0!
3% Fe/ZSM5 #DIV/0!
#DIV/0!
3% Cu/ZSM5 #DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
3% Cu/ZSM5 after 29.89 1477.27
1% Pt/Al2O3 before 60.65 1520.66
5% Mn/Al2O3
after 60.65 1368.15 20.17
before 29.55 1668.01
3% Ru/Al2O3
after 29.72 1491.99 19.45
before 65.02 1709.93
after 65.11 1545.33 21.46
80.16
68.45
65.21
91.60
31.96
26.93
27.49
39.66
93.07 277.73
73.14 250.81
278.04
2.77 24.88
70.44 276.97
311.80
2.38 24.64
96.01 271.58
300.80
2.77 24.27
2.79 23.38
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! 0 FID 10.03 14.32 0.00 45.99 0.00 19.11 #DIV/0! 0.00 0.00
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! 0 FID 10.04 12.64 0.00 40.11 0.00 17.86 #DIV/0! 0.00 0.00
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! 0 FID 9.49 14.33 0.00 57.91 0.00 26.49 #DIV/0! 0.00 0.00
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0!
116.40
#DIV/0!
102.62
#DIV/0!
143.77
#DIV/0!
50.00 68.79 #DIV/0! #DIV/0!
3% Cu/ZSM5 after
36.00 58.64 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
1% Pt/Al2O3 before 59.12 1506.64
after 61.34 1262.63 23.31
50.00 67.11 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
5% Mn/Al2O3 before
after
50.00 65.16 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
3% Ru/Al2O3 before
after
94.62 35.16
109.34 227.18
274.31
2.47 24.31 0 #DIV/0! #DIV/0! TCD #DIV/0!
0 #DIV/0! 0 FID 13.06
0 #DIV/0! #DIV/0! TCD #DIV/0!
0 #DIV/0! #DIV/0! FID #DIV/0!
0 #DIV/0! #DIV/0! TCD #DIV/0!
0 #DIV/0! #DIV/0! FID #DIV/0!
0 #DIV/0! #DIV/0! TCD #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
13.31 0.00 51.14 0.00 20.08 #DIV/0! 0.00 0.00
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0!
139.97
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
48.00 0.00 #DIV/0! #DIV/0!
3% Cu/ZSM5 after
52.00 60.12 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
1% Pt/Al2O3 before 67.1 1427.66
0.00 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
5% Mn/Al2O3
after 66.98 1125.36 13.01
before 118.56 1357.72
0.00 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
3% Ru/Al2O3
after 119.22 871.94 31.77
before 117.19 1357.71
after 118.21 843.19 28.02
118.99
146.47
152.37
44.78
57.06
63.38
11.09
19.09 16.03
19.61 15.91
152.81
253.82
282.6
245.04
194.45
245.09
156.39
2.72 21.88
246.22
148.79
2.29 23.59
2.38 24.50
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! 0 FID 21.32 4.62 0.00 39.99 0.00 15.90 #DIV/0! 0.00 4.25
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! 0 FID 35.42 7.19 0.00 31.38 0.00 12.91 #DIV/0! 4.68 3.91
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! 0 FID 37.36 6.03 0.00 31.05 0.00 13.64 #DIV/0! 4.57 3.69
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0!
121.63
#DIV/0!
128.80
#DIV/0!
136.39
#DIV/0!
50.00 59.51
0.00 #DIV/0! #DIV/0!
3% Cu/ZSM5
#DIV/0! #DIV/0!
1% Pt/Al2O3
#DIV/0! #DIV/0!
50.00 54.07 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
5% Mn/Al2O3
51.00 58.26 #DIV/0! #DIV/0!
3% Ru/Al2O3
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0! #DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
ZnCr2O4 before
after
0 #DIV/0! #DIV/0! FID #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0!
#DIV/0!
0.00 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
ZnCr2O4 before
after
0 #DIV/0! #DIV/0! FID #DIV/0!
0 #DIV/0! #DIV/0! TCD #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0!
#DIV/0!
0.00 #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
ZnCr2O4 before 18.9 1645.59
after 18.03 1219.48 30.69 164.47 68.42 22.72 20.04 211.27
309.46
226.62 2.66 23.93
0 #DIV/0! 0 FID 29.29 6.58 0.00 33.37 0.00 14.66 #DIV/0! 5.27 4.63
0 #DIV/0! #DIV/0! TCD #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
101.51
#DIV/0! 50.00 63.65
#DIV/0! #DIV/0!
ZnCr2O4 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0!
Experiment of Meth
power @ 60 and 80W a frequency flow rate
20 kHz 30 mL/min
sample volume mole sample
500 uL 0 mol
6 CH4
reactan FID (flow rate) CH4 C2H2 C2H4 C2H6 C3H6 C3H8 iC4H10 nC4H10
before 27.61 232.25
C2H2 after
before
C2H4 after
before 27.83
28.3 195.31 0.58 0.37 4.00
6490.51
4.93 2.18 1.53
after 26.13 13.28 230 5828.42 50.18 39.66 69.69 86.85 236.21
TCD H2 conv. power V (kV) I (mA) total mol FID TCD calculation FID CH4 C2H2 C2H4 C2H6 C3H6 C3H8 iC4H10 nC4H10
98.08 13.80
15.70 2.83 40.23
0 0 FID 13.80 2.51 2.14 19.37 0.00 33.32 19.03 12.50
3.54 28.55
0
TCD
0 #DIV/0! FID #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0
0
0
0 TCD
FID
TCD
1.12 21.06 15.70 4.35 3.67 6.38 8.57 23.43
TCD 4.40 power (Watt) RMS integration C total H total
50.00
#DIV/0! 60.00 113.77
88.87 102.59
0.00 60.00 0.00
#DIV/0! #DIV/0!
60.00 100.95 68.58 39.96
8 CH4
reactan before
C2H2 after
before
C2H4 after
before
after
FID CH4 C2H2 C2H4 C2H6 C3H6 C3H8 iC4H10 nC4H10
27.61 232.25
28.4 178.6 0.63 0.71 5.10 0.45 3.76 1.41 1.28
30.54 6531.64
30.07 216.17 5834.66 3.80
23.49
146.98
13.48 61.68 95.58
21.36 5.21 20.75 90.34 3.09 3.25 5.50 3.39 12.65
TCD 4.40 conv. power (RMS) V (kV) I (mA) total mol FID TCD calculation FID 8.42 25.53 25.66 29.40 42.13 42.98 43.77 51.25
106.56 20.90
22.79 12.05
2.85 23.74 0
0
0 FID
TCD
2.09 1.80 2.70 16.38 1.89 16.86 8.16 6.92
86.89 44.11
3.74 35.40 0 0 FID 24.99 12.05 12.02 0.00 1.70 0.00 8.32 12.95
2.79 23.90
0
0
0
0 TCD
FID
0 TCD
2.02 21.82 44.11 3.65 5.03 9.08 7.22 25.21
TCD 4.40 power RMS integration C total H total
report 60 W Conversion H2
36.01
12.79 80.00 67.56
54.71 69.32
CH4 13.80
21.62 80.00 132.43
59.99 33.53
C2H2
80.00 66.59 74.03 78.60
C2H4 15.70
50.00
0.00
C2H2
2.51
21.06
C2H4
2.14
15.70
C2H6
19.37
4.35
C3H6 C3H8 iC4H10 nC4H10
0.00 33.32 19.03 12.50
3.67 6.38 8.57 23.43
80 W Conversion H2
20.90
12.05
44.11
36.01
12.79
21.62
C2H2
1.80
12.05
21.82
C2H4
2.70
12.02
44.11
C2H6
16.38
0.00
3.65
C3H6 C3H8 iC4H10 nC4H10
1.89 16.86 8.16 6.92
1.70 0.00 8.32 12.95
5.03 9.08 7.22 25.21
C2H6 C3H6 C3H8 i-C4H10 n-C4H10
13.85 14.72 16.38 3.60 16.86 16.48 19.87 87.91
2.70 3.38 1.89 1.86 4.16 3.92
12.02 19.76 1.70 18.72 20.64 15.95 88.80
50 40
Selectivity (%)
C2H4
30 20 10 0
H4 C2
H6 C2
H6 C3
H8 C3
Compounds
Experiment of Methane Kinetic Conversion power @ 60 and 80W and flowrate @ 30 mL/min
60 Watt C2H6 before 27.68
6901.19
C3H6 after 28.39 33.16 4.28 5.30 6094.11 15.46 84.93 6.25 99.47
before 29.49
9706.08
C3H8 after 29.29 24.89 5.56 6.46 32.30 8810.13 220.01 120.77 69.81
42.34 9.84 3.08 31.28 0
0
TCD
5.10 13.51 22.31 9.43 2.60 14.14 1.12 17.94
2.37 10.85 16.81 3.15 9.84 22.65 13.41 7.79
31.61
30.47 60.00 96.31
259.06
16.67 3.39 49.55
0 0 FID 10.04 4.11 17.70 8.30 33.19 11.73 1.52 0.00
0
60.00 111.03
0 0
TCD
FID 4.64 9.26 15.83 6.50 18.83 8.20 16.67 46.82
70.35
77.03 73.32
before 28.21
70
0
0 FID
76.71 75.53
32.5 9.62 1.45 4.69 2.61 7.97 169.36 0.26 0.00
11.73 3.28 33.84
0
FID
215.22
after
44
9.43
0
before 28.98
iC4H10
81.99 51.00 167.97
74.85 111.37
110.08 146.79
80 Watt C2H6 before
C3H6 after
before
C3H8 after
before
iC4 after
before
27.33
6901.19
28.58 112.22 5.81 9.76 5448.36 32.64 172.20 26.81 199.70
30.04
9706.08
29.46 52.38 9.73 11.12 56.52 8041.06 258.56 171.47 106.11
78.36 17.45
0
0
TCD
9.51 10.10 22.63 17.45 3.02 15.80 2.65 19.85
2.58 9.84 15.00 2.86 18.75 13.80 9.87 6.13
32.23
15.79 80.00 105.33
91.50 84.49
C2H6 9.43
0
0 FID
C3H6 9.84
29.68
259.06
92.82 15.23 2.75 23.45 0 0 FID 12.63 6.93 33.27 10.96 39.23 12.90 2.36 1.34
0
0 0
TCD
FID 4.77 2.36 4.67 4.04 18.42 7.00 15.23 34.47
85.81 80.00 124.84
76.25 53.59
34.68 13.15 2.66 9.58 3.74 10.24 165.22 0.45 0.27
12.90 3.61 34.60
0
FID
215.00
44 18.75
3.26 32.36 0
30.6
0.00 80.00 64.51
106.71 142.23
75.73 46.45
C3H8 11.73
iC4H10 16.67
31.61
30.47
70.35
81.99
13.51
10.85
4.11
9.26
22.31
16.81
17.70
15.83
9.43
3.15
8.30
6.50
2.60 14.14 1.12 17.94
9.84 22.65 13.41 7.79
33.19 11.73 1.52 0.00
18.83 8.20 16.67 46.82
17.45
18.75
12.90
15.23
32.23
15.79
85.81
0.00
10.10
9.84
6.93
2.36
22.63
15.00
33.27
4.67
17.45
2.86
10.96
4.04
3.02 15.80 2.65 19.85
18.75 13.80 9.87 6.13
39.23 12.90 2.36 1.34
18.42 7.00 15.23 34.47
Column B Column D
H6 C2
H6 C3
H8 C3
Compounds
10 4H i-C
10 4H n-C
iC4H10
nC4H10 after 37.48 8.3 6.10 7.82 3.81 8.44 3.45 162.49 16.28
before 27.35
245.85
114.15 190.58
after 29.17 5.56 3.50 5.56 3.67 4.48 4.50 7.42 211.26
8.37
2.77 24.88 0
0
0
0 TCD
FID
0 TCD
5.61 9.57 20.27 11.29 18.01 19.31 41.13 8.37
0.00 60.00 68.79
60.00 0.00 125.19 61.82
iC4H10
nC4H10 after
before
after
31.83 9.64 1.76 2.61 2.68 9.33 3.33 204.79 13.56
27.35
245.85
29.17 5.56 3.50 5.56 3.67 4.48 4.50 7.42 211.21
8.39 2.47 24.31 0
0
0
0 TCD
FID
TCD
5.59 9.55 20.22 11.26 17.96 19.26 41.01 8.39
0.00 80.00 0.00
80.00 60.12 124.84 61.67
iC4H10
nC4H10 8.37 0.00 9.57 20.27 11.29 18.01 19.31 41.13 8.37
8.39 0.00 9.55 20.22 11.26 17.96 19.26 41.01 8.39
Experiment of Meth
power @ 60 and 80W a frequency flow rate
20 kHz 30 mL/min
sample volume mole sample
500 uL 0 mol
6 CH4
reactan FID (flow rate) CH4 C2H2 C2H4 C2H6 C3H6 C3H8 iC4H10 nC4H10
before 27.61 232.25
C2H2 after
before
C2H4 after
before 27.83
28.3 195.31 0.58 0.37 4.00
after 26.13 13.28 230 5828.42 50.18 39.66 69.69 86.85 236.21
6490.51
4.93 2.18 1.53
TCD H2 conv. power V (kV) I (mA) total mol FID TCD calculation FID CH4 C2H2 C2H4 C2H6 C3H6 C3H8 iC4H10 nC4H10
98.08 13.80
15.70 2.83 40.23
0
3.54 28.55
0
0 FID concentration 13.80 86.20 2.51 0.17 2.14 0.15 19.37 1.34 0.00 0.00 33.32 1.53 19.03 0.66 12.50 0.43
0
0
#DIV/0! FID concentration #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0
0
0 FID 1.12 21.06 15.70 4.35 3.67 6.38 8.57 23.43
concentration 2.67 3.31 84.30 0.68 0.38 0.67 0.67 1.84
TCD 4.40 power (Watt) RMS integration C total H total
50.00
13.80
#DIV/0!
60.00 113.77 88.87 102.59
90.48 101.12
0.00 60.00 0.00
#DIV/0! #DIV/0!
0.00 0.00
0.00 60.00 100.95
68.58 39.96
94.52 97.84
8 CH4
reactan before
C2H2 after
before
C2H4 after
before
after
FID CH4 C2H2 C2H4 C2H6 C3H6 C3H8 iC4H10 nC4H10
27.61 232.25
28.4 178.6 0.63 0.71 5.10 0.45 3.76 1.41 1.28
30.54 6531.64
30.07 216.17 5834.66 3.80
23.49
24.36 5.21 20.75 90.34 3.09 3.25 5.50 3.39 12.65
146.98
13.48 61.68 95.58
TCD 4.40 conv. power (RMS) V (kV) I (mA) total mol FID TCD calculation FID 8.42 25.53 25.66 29.40 42.13 42.98 43.77 51.25
106.56 20.90
22.79 12.05
2.85 23.74 0
0
0 FID 2.09 1.80 2.70 16.38 1.89 16.86 8.16 6.92
concentration 79.10 0.19 0.28 1.71 0.13 1.17 0.43 0.36
86.89 36.26
3.74 35.40 0
2.79 23.90
0
0 FID concentration 24.99 6.02 12.05 87.95 12.02 1.45 0.00 0.00 1.70 0.14 0.00 0.00 8.32 0.50 12.95 0.78
0
0
0
0 concentration 1.16 6.24 63.74 1.05 0.96 1.73 1.03 3.61
FID 2.80 30.27 36.26 5.07 6.98 12.60 10.02 34.97
TCD 4.40 power RMS integration C total H total
report 60 W
36.01
15.05
12.79
80.00 67.56 54.71 69.32
83.38 94.09
3.08
29.99
80.00 132.43 59.99 33.53
96.84 112.79
80.00 66.59 102.71 96.58
86.20
0.00
50.00
13.80
0.00
0.00
0.00
2.51
0.17
0.00
21.06
3.31
C2H4
2.14
0.15
0.00
15.70
84.30
C2H6
19.37
1.34
0.00
4.35
0.68
C3H6 C3H8 iC4H10 nC4H10
0.00 33.32 19.03 12.50
0.00 1.53 0.66 0.43
0.00 0.00 0.00 0.00
3.67 6.38 8.57 23.43
0.38 0.67 0.67 1.84
C2H2
C2H4 15.70
79.51 92.27
CH4 13.80
Conversion H2
C2H2
12.37
2.67
80 W Conversion H2
20.90
79.10
12.05
6.02
36.26
1.16
36.01
15.05
12.79
3.08
29.99
12.37
C2H2
1.80
0.19
12.05
87.95
30.27
6.24
C2H4
2.70
0.28
12.02
1.45
36.26
63.74
C2H6
16.38
1.71
0.00
0.00
5.07
1.05
C3H6 C3H8 iC4H10 nC4H10
1.89 16.86 8.16 6.92
0.13 1.17 0.43 0.36
1.70 0.00 8.32 12.95
0.14 0.00 0.50 0.78
6.98 12.60 10.02 34.97
0.96 1.73 1.03 3.61
Reactan
Products concentration [%] C2H6 C3H6
CH4
C2H2
C2H4
C3H8
0.45
2.04
0.00
0.93
CH4
86.20
0.17
C2H2
3.03
81.95
1.45
0.00
0.14
0.00
C2H4
2.67
3.31
84.30
0.68
0.38
0.67
C2H6
0.96
1.27
2.10
90.57
0.16
0.89
C3H6
0.70
1.60
2.48
0.46
80.16
2.23
C3H8
2.31
0.47
2.03
0.95
2.54
88.27
iC4H10
2.36
2.35
4.02
1.65
3.19
1.39
nC4H10
1.27
1.08
2.29
1.28
1.36
1.46
4.0 61.9 26.1 15.3 7.7 27.5 11.3 11.5
32.4 20.2 17.7 5.6 11.2 9.8 0.35
3.03 2.67 0.96 0.70 2.31 2.36 1.27
6.61 2.55 3.2 0.94 4.7 2.17 3.2
40.6 11.2 6.6 3.1 13.4 4.2 4.5
27.7 17.6 14.1 5.5 8.4 7.6
10.5 29.6 33.4 27.5 24.2 19.2 20.7 0.9 2.9 4.21 4.97 4.07 8.04 4.59 8.3 38.8 29.1 21.8 23.6 14.4 16.2
47.6 0.0 6.7 5.1 11.4 7.9 11.5 4.08 0 1.37 0.93 1.91 3.3 2.55 37.5 0.0 5.7 4.1 11.1 5.9 9.0
0.0 2.8 3.8 2.6 30.3 15.3 12.3 0 0.41 1.15 0.49 7.63 9.56 4.07 0.0 5.5 4.8 3.4 44.3 17.1 14.4
21.7 0.0 6.5 14.1 24.7 6.6 13.2 2.79 0 2 2.67 6.69 4.17 4.37 25.6 0.0 8.4 18.4 29.4 7.5 15.4
Reactan
Conversion [%]
CH4
C2H2
C2H4
Products concentration [%] C2H6 C3H6
CH4
13.8
86.20
0.17
0.45
2.04
0.00
C2H2
12.0
3.03
81.95
1.45
0.00
0.14
C2H4
15.7
2.67
3.31
84.30
0.68
0.38
C2H6
9.4
0.96
1.27
2.10
90.57
0.16
C3H6
9.8
0.70
1.60
2.48
0.46
80.16
C3H8
11.7
2.31
0.47
2.03
0.95
2.54
iC4H10
16.7
2.36
2.35
4.02
1.65
3.19
nC4H10
8.4
1.27
1.08
2.29
1.28
1.36
Experiment of Methane Kinetic Conversion power @ 60 and 80W and flowrate @ 30 mL/min
60 Watt C2H6 before 27.68
C3H6 after 28.39 33.16 4.28 5.30 6094.11 15.46 84.93 6.25 99.47
6901.19
before 29.49
C3H8 after 29.29 24.89 5.56 6.46 32.30 8810.13 220.01 120.77 69.81
9706.08
42.34 9.84
0
0 5.10 13.51 22.31 9.43 2.60 14.14 1.12 17.94
31.61
5.96
2.37 10.85 16.81 3.15 9.84 22.65 13.41 7.79
concentration 0.70 1.60 2.48 0.46 90.16 2.23 0.99 0.57
30.47
60.00 96.31 76.71 75.53
96.86 97.87
6.00
99.20 100.86
16.67
0
0
0 FID concentration 10.04 2.31 4.11 0.47 17.70 2.03 8.30 0.95 33.19 2.54 11.73 88.27 1.52 0.09 0.00 0.00
70.35
60.00 111.03 77.03 73.32
259.06
3.39 49.55
0
0 FID
before 28.21
70
3.28 33.84
0
concentration 0.96 1.27 2.10 90.57 0.16 0.89 0.05 0.85
32.5 9.62 1.45 4.69 2.61 7.97 169.36 0.26 0.00
11.73
3.08 31.28
FID
215.22
after
44
9.43
0
before 28.98
iC4H10
10.78
0 0 FID 4.64 9.26 15.83 6.50 18.83 8.20 16.67 46.82
81.99
51.00 167.97 74.85 111.37
96.66 95.98
110.08 146.79
80 Watt C2H6 before
C3H6 after
before
C3H8 after
before
iC4 after
before
27.33
28.58 112.22 5.81 9.76 5448.36 32.64 172.20 26.81 199.70
6901.19
30.04
29.46 52.38 9.73 11.12 56.52 8041.06 258.56 171.47 106.11
9706.08
78.36 17.45
0
0 9.51 10.10 22.63 17.45 3.02 15.80 2.65 19.85
0
0 concentration 3.32 1.76 3.95 82.55 0.35 1.84 0.23 1.73
32.23
11.25
FID 2.58 9.84 15.00 2.86 18.75 13.80 9.87 6.13
concentration 1.45 2.77 4.22 0.80 81.25 2.59 1.39 0.86
15.79
80.00 105.33 91.50 84.49
C2H6 9.43
95.74 97.81
0.96
5.92
C3H6 9.84
95.33 95.93
259.06
15.23 2.75 23.45
0
0
0 FID concentration 12.63 3.19 6.93 0.87 33.27 4.20 10.96 1.38 39.23 3.30 12.90 87.10 2.36 0.15 1.34 0.08
85.81
80.00 124.84 76.25 53.59
29.68
92.82
3.61 34.60
0
34.68 13.15 2.66 9.58 3.74 10.24 165.22 0.45 0.27
12.90
3.26 32.36
FID
215.00
44 18.75
0
30.6
14.44
0 0 FID 4.77 2.36 4.67 4.04 18.42 7.00 15.23 34.47
0.00
80.00 64.51 106.71 142.23
0.70
C3H8 11.73
100.28 98.43
2.31
75.73 46.45
iC4H10 16.67
31.61
5.96
30.47
6.00
70.35
10.78
81.99
13.51
1.27
10.85
1.60
4.11
0.47
9.26
22.31
2.10
16.81
2.48
17.70
2.03
15.83
9.43
90.57
3.15
0.46
8.30
0.95
6.50
2.60 14.14 1.12 17.94
0.16 0.89 0.05 0.85
9.84 22.65 13.41 7.79
90.16 2.23 0.99 0.57
33.19 11.73 1.52 0.00
2.54 88.27 0.09 0.00
18.83 8.20 16.67 46.82
17.45
3.32
18.75
1.45
12.90
3.19
15.23
32.23
11.25
15.79
5.92
85.81
14.44
0.00
10.10
1.76
9.84
2.77
6.93
0.87
2.36
22.63
3.95
15.00
4.22
33.27
4.20
4.67
17.45
82.55
2.86
0.80
10.96
1.38
4.04
3.02 15.80 2.65 19.85
0.35 1.84 0.23 1.73
18.75 13.80 9.87 6.13
81.25 2.59 1.39 0.86
39.23 12.90 2.36 1.34
3.30 87.10 0.15 0.08
18.42 7.00 15.23 34.47
Atom balance Cout/Cin Hout/Hin
iC4H10
nC4H10
0.26
0.43
0.95
1.01
0.00
0.28
0.87
1.13
0.67
1.84
0.95
0.98
0.05
0.85
0.97
0.98
0.99
0.57
0.89
1.01
0.09
0.00
0.97
0.96
83.33
5.94
1.04
1.00
2.33
91.63
1.03
0.98
6.1 0.0 6.6 0.8 10.9 1.0
10.1 5.7 18.0 13.4 6.4 0.0 28.4
21.0 1.04 0 2.69 0.21 3.96 0.35 0 9.3 9.6 0.0 11.3 1.5 17.4 2.0 32.9
1.73 1.12 7.35 3.38 2.3 0 23.78 0 15.9 15.0 30.8 23.4 10.1 0.0 42.5
ntration [%] C3H8
iC4H10
nC4H10
Atom balance Cout/Cin Hout/Hin [1]
0.93
0.26
0.43
0.95
1.01
0.00
0.00
0.28
0.87
1.13
0.67
0.67
1.84
0.95
0.98
0.89
0.05
0.85
0.97
0.98
2.23
0.99
0.57
0.89
1.01
88.27
0.09
0.00
0.97
0.96
1.39
83.33
5.94
1.04
1.00
1.46
2.33
91.63
1.03
0.98
iC4H10
nC4H10 after 37.48 8.3 6.10 7.82 3.81 8.44 3.45 162.49 16.28
before 27.35
after 29.17 5.56 3.50 5.56 3.67 4.48 4.50 7.42 211.26
245.85
114.15 190.58
8.37
2.77 24.88 0
0
0
0 concentration 2.36 2.35 4.02 1.65 3.19 1.39 83.33 5.94
20.82
FID 5.61 9.57 20.27 11.29 18.01 19.31 41.13 8.37
concentration 1.27 1.08 2.29 1.28 1.36 1.46 2.33 91.63
0.00
60.00 68.79 104.23 100.47
0.00 60.00 0.00
125.19 61.82
iC4H10
102.69 98.34
nC4H10 after
before
after
31.83 9.64 1.76 2.61 2.68 9.33 3.33 204.79 13.56
27.35
29.17 5.56 3.50 5.56 3.67 4.48 4.50 7.42 211.21
245.85
8.39 2.47 24.31 0
0
0
0 concentration 2.21 0.55 1.08 0.94 2.85 1.08 84.77 4.00
0.00
FID 5.59 9.55 20.22 11.26 17.96 19.26 41.01 8.39
concentration 1.27 1.08 2.29 1.28 1.36 1.46 2.33 91.61
0.00
80.00 0.00 97.48 93.33
iC4H10
0.00 80.00 60.12
124.84 61.67
102.67 98.32
nC4H10 8.37
1.27
20.82
0.00
0.00
2.35
9.57
1.08
4.02
20.27
2.29
1.65
11.29
1.28
3.19 1.39 83.33 5.94
18.01 19.31 41.13 8.37
1.36 1.46 2.33 91.63
2.36
2.21
8.39
1.27
0.00
0.00
0.00
0.55
9.55
1.08
1.08
20.22
2.29
0.94
11.26
1.28
2.85 1.08 84.77 4.00
17.96 19.26 41.01 8.39
1.36 1.46 2.33 91.61
60W
0.74
0.06 0 1.79 0.3 0.23 0.97 0.67 1.07
0.18 0.17 0 1.03 0.33 0.16 1.28 2.27
0.5 0.18 0.01 0 0.14 0.49 0.89 0.39
0.02 0.31 0.22 0.07 0 0.48 1.28 1.05
0.3 0.06 0.02 0.67 0.53 0 1.45 0.33
0.13 0.14 0.25 0.15 0.54 0.7 0 1.38
0 0 0.03 4.33 5.24 0.04 1.44 0.63
0.11 0 0.49 0.04 0.39 0.37 0.95 6.79
0.01 4.29 0 0.13 0.12 0.41 1.71 0.6
0.17 3.86 0.05 0 0.16 0.14 5.28 0.73
0.05 2.39 0.01 2.96 0 1.04 0.04 0.14
0.22 0.82 0.09 0.43 1.85 0 0.88 2.25
0.03 5.84 0.02 0.05 0.84 0.42 0 0.79
0 0.42 0.07 2.87 0.79 1.96 0.68 0.19
0.08 0 0.24 0.35 1.31 2.02 1.93 0.24
0.42 2.57 0 0.61 0.83 1 2.82 2.9
0.2 0.43 0 0 1.1 0.68 1.21 0.93
0.01 0.97 0.14 1.72 0 0.97 0.89 2.02
0.55 3.03 0.03 4.21 0.76 0 1.01 0.01
0.13 0.77 0.26 0.25 0.49 1.65 0 1.09
0 1.82 0.08 0 0.15 1.06 0.79 0.61
0.1 0 0.12 0.16 2.01 1.3 2.11 0.24
0.57 2.54 0 0 0.6 0.89 2.47 1.78
0.2 0.54 0 0 2.53 0.12 2.55 0.47
0.01 1.82 0.21 0 0 1.2 0.48 1.52
0.92 0.59 0 0.01 0.08 0 3.34 0
0.34 0.59 0.6 0.21 0.99 1.06 0 0.14
0 0.32 0.1 0 0.02 0.03
0.03 0 0.29 0.18 0 3.02
0.4 0.61 0 0 0.17 0.2
0.17 1.03 0 0 0 0.19
0.01 0.6 0.15 0 0 0.02
0.6 0.4 0 0 0.13 0
0.33 1.09 5.29 0.17 0 1.21
0 1.31 0.08 0.11 0.09 0.06 0.06
CH4
C2H4
C2H6
C3H6
0.88 1.02
6.68 0.08
0.75 4
2.02 0.29
0.14 2.72
1.9 0
0 0.2
0 0.3 0.23 0 0.03 0.05 2.75 1.76
0.05 0 0.17 0.26 0 0.04 0.01 0.03
0.19 0.53 0 0 0.12 0.11 0.88 4.2
0.26 0.45 0 0 0 0 2.03 0.1
0.01 1.89 0.45 0 0 0.07 0.28 5.2
0.29 0.61 0 0 0.22 0 2.87 0.01
0.01 1.29 1.87 0.21 0 0.19 0 0.17
0 0.07 0.02
0.02 0 0.23
0.32 0.67 0
0.19 0.71 0
0.02 0.8 0.37
0.38 0.6 0
0.02 0.41 2.56
0 0.02 0.04 0.07 0.92
0.5 0 0.03 0.01 0.06
0 0.2 0.46 0.15 2.35
0 0 0 0.06 0.19
0 0 0.01 0.05 2.69
0 0.38 0 0.05 0.01
0.09 0 0.19 0 0.23
0 0.06 0.02 0 0.05 0.03 0.08 0.05
0.03 0 0.18 0.6 0 0.02 0 0.06
0.17 0.72 0 0 0.26 0.35 0.21 0.08
0.08 1.26 0 0 0 0 0.08 0.02
0.02 0.7 0.2 0 0 0.02 0.06 0.04
0.52 0.71 0 0 0.29 0 0.11 0.01
0.02 0.35 1.94 0.09 0 0.2 0 0.05
C3H8
iC4H10
n-C4H10
0.29 1.47 1.01 0.94 0.53 0.97 2.45 0
0 0.47 0.03 3.53 0.13 2.39 6.18 0
0.4 0.13 0.02 0.25 0.59 3.28 4.14 0
0.6 0.1 0.01 0 0.4 0.03 3.86 0
0.89 0.06 0.02 0 0.04 0.02
1 2 3 4 5 6 7 8
1 0.0 8.1 8.5 17.3 21.8 13.5 20.6 7.2
2 5.3 0.0 8.6 6.1 35.1 11.3 36.2 21.8
3 11.6 12.0 0.0 9.2 7.8 28.2 7.7 6.4
4 6.5 8.4 18.9 0.0 7.0 8.1 21.7 8.0
5 7.5 38.6 6.2 18.0 0.0 10.8 8.2 18.3
2.18 0
0.04 0.08 0.01 0 0.04 0.02 0.26 0
0.06 0.04 0 0 0.14 0.07 0.32 0
0.04 0.07 0 0 0.1 0.05 0.23 0
6 9.8 20.7 15.6 21.7 10.9 0.0 8.3 23.8
7 10.7 16.1 9.1 4.7 8.5 7.9 0.0 7.7
8 11.1 9.1 9.9 13.7 7.1 13.3 8.9 0.0
kij
i
(1) CH4
(2) C2H2
(1) CH4
0
( 0.0
)
0.06
( 5.3
)
(2) C2H2
1.31
( 8.1
)
0
( 0.0
)
(3) C2H4
0.08
( 8.5
)
1.79
( 8.6
)
(4) C2H6
0.11
( 17.3 )
0.3
( 6.1
)
(5) C3H6
0.09
( 21.8 )
0.23
( 35.1 )
(6) C3H8
0.06
( 13.5 )
0.97
( 11.3 )
(7) i-C4H10
0.06
( 20.6 )
0.67
( 36.2 )
(8) n-C4H10
0.74
( 7.2
1.07
( 21.8 )
)
j (3) C2H4
(4) C2H6
(5) C3H6
(6) C3H8
0.18
( 11.6 )
0.5
( 6.5
)
0.02
( 7.5
)
0.3
0.17
( 12.0 )
0.18
( 8.4
)
0.31
( 38.6 )
( 9.8
(7) i-C4H10
(8) n-C
)
0.13
( 10.7 )
0.29
0.06
( 20.7 )
0.14
( 16.1 )
1.47
0
( 0.0
)
0.01
( 18.9 )
0.22
( 6.2
)
0.02
( 15.6 )
0.25
( 9.1
)
1.01
1.03
( 9.2
)
0
( 0.0
)
0.07
( 18.0 )
0.67
( 21.7 )
0.15
( 4.7
)
0.94
0.33
( 7.8
)
0.14
( 7.0
)
0
( 0.0
)
0.53
( 10.9 )
0.54
( 8.5
)
0.53
0.16
( 28.2 )
0.49
( 8.1
)
0.48
( 10.8 )
0
( 0.0
)
0.7
( 7.9
)
0.97
1.28
( 7.7
)
0.89
( 21.7 )
1.28
( 8.2
)
1.45
( 8.3
)
0
( 0.0
)
2.45
2.27
( 6.4
)
0.39
( 8.0
1.05
( 18.3 )
0.33
( 23.8 )
1.38
( 7.7
)
0
)
(8) n-C4H10 ( 11.1 ) ( 9.1
)
( 9.9
)
( 13.7 ) ( 7.1
)
( 13.3 ) ( 8.9
)
( 0.0
)
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