Relevant Details Of Amines

Reagent

Relevant used in this MEA Details of amines AMP DIPAstudy

Formula Cas no. Mol weight (g/mol) Density (kg/L) Melting point (oC) Boiling point (oC) Flash point (cc test ) (oC) COD (exp) (g O2/g amine) COD -theoretical (g O2/ g amine) Viscosity (cp) pH (at 20 C) Water solubility (g/L) LD 50 (ratoral) (mg/Kg bw) Risk sentence(s)

synonyms

Piperazine

C2H7NO 141-43-5 61.1

C4H11NO 124-68-5 89.1

C6H15NO2 110-97-4 133.2

C5H13NO2 105-59-9 119.2

C4H10N2 110-85-0 86.1

1.013 (20oC) 1.0125 (25 Oc) 10-12

0.928 (40 oC)

1.03 (20 c)

1.1 (20 C)

30-31 oC

0.990 (20oC) 1.0 (40oC) 35-42

-21 oC

107-112

170

165

245-250

247

85-94.5

67-78

123 -135

127-138

65 / 82

1.37

1.91

1.75

1.46

1.62

1.31

1.97

1.92

1.74

1.86

24 (at 20 oC)

102 (at 30 oC)

198 (45 C)

101 (20 C)

12.1 at100 g/L

11.4 at 100 g/L

11.5 at 100 g/L

Fully Miscible at 20 oC

11.3 for 0.1M solution Fully miscible at 20 oC

Miscible 870 (at 20oC)

Fully miscible at 20 C

12 at 150 g/L 150 g/L (20 c)

>1515

2900

>2000

>1900

>1900

Harmful by inhalation, Irritating to eyes skin and respiratory system Monoethanolamin e, 2-aminoethanol, 2-ethanolamine, Ethanolamine

R36/38 : Irritating to eyes and skin. R52/53 (note 1)

R36 : Irritating to eyes.

R36 : Irritating to eyes.

R34, R42/43 R52/53 (See note 1)

2-amino-2methyl-1propanol, Aminomethylprop anol

Diisopropanolamine, 1,1’-Iminodi-2proponol,

Methyldiethanola mine, N-methyl2,2’-iminodiethan ol, 2,2’-methylimino diethanol

N,Ndiethylenedi amine

[CH3CH(OH)CH2]2NH

CH3N(CH2CH2OH)2

Secondary alkanolamine

Tertiary alkanolamine

Structure formula

H H H

NH2CH2CH2OH

H C C OH NH2 H

Category

MDEA

Primery alkanolamine

H

HCH

H

H C C C OH H NH2 H

Sterically hindered (primary) amine

http://ecb.jrc.it/I http://ecb.jrc.it/I http://ecb.jrc.it/IUC Link to UCLIDLIDIUCLID data UCLIDDataSheets/141 DataSheets/ 124 DataSheets/110974 sheet 435.pdf .pdf .pdf Relevant details of amines 685 to be tested 11-08.2008

Cyclic amine

http://ecb.jrc.it/ http://ecb.j IUCLIDrc.it/IUCLI DataSheets/105 DDataSheet 599.pdfDeshai Botheju s/110850.p df

Relevant Details of amines used in this study Risk sentences Note 1: R34 : Causes burns. R42/43 : May cause sensitization by inhalation and skin contact. R52/53 : Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Relevant details of amines to be tested

11-08.2008

Deshai Botheju