Plastomers Gradeslate Productguide
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Melt Index (dg/min)
FDA Note
3024
0.905
4.5
1a
3035
0.900
3.5
1a
3128
0.900
1.2
1a
4006
0.880
10
4
4053
0.888
2.2
3
4049
0.873
4.5
4
3040
0.900
16.5
2
3131
0.900
3.5
1b
3132
0.900
1.2
1b
3139
0.900
7.5
1b
4056
0.883
2.2
4
4150
0.895
3.5
2
4151
0.895
2.2
1b
0201
0.902
1.1
5
0201FX
0.902
1.1
1b
0203
0.902
3.0
5
0210
0.902
10
6
0230
0.902
30
6
5061
0.868
0.5
6
5062
0.860
0.5
6
5101
0.902
1.1
5
5171
0.870
1.0
6
5181
0.882
1.1
6
5361
0.860
3.0
6
5371
0.870
5.0
6
8201
0.882
1.1
6
8203
0.882
3.0
6
8210
0.882
10
6
8230
0.882
30
6
(CAS# 25213-02-9) (CAS# 25087-34-7)
Density (g/cc)
BUTENE
©2006 Exxon Mobil Corporation. The user may forward, distribute, and/or photocopy this copyrighted document only if unaltered and complete, including all of its headers, footers, disclaimers, and other information. ExxonMobil does not guarantee the typical (or other) values. Typical values only represent the values one would expect if the property were tested in our laboratories with our test methods on the specified date. Some product properties are not frequently measured, and accordingly typical values are not based upon a statistically relevant number of tests. The information in this document relates only to the named product or materials when not in combination with any other product or materials. We based the information on data believed to be reliable on the date compiled, but we do not represent, warrant, or otherwise guarantee, expressly or impliedly, the merchantability, fitness for a particular purpose, suitability, accuracy, reliability, or completeness of this information or the products, materials, or processes described. The user is solely responsible for all determinations regarding any use and any process. We expressly disclaim liability for any loss, damage, or injury directly or indirectly suffered or incurred as a result of or related to anyone using or relying on any of the information in this document. There is no warranty against patent infringement, nor any endorsement of any product or process, and we expressly disclaim any contrary implication. The terms, “we,” “our,” “ExxonMobil Chemical,” or “ExxonMobil” are used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates they directly or indirectly steward. ExxonMobil, the “Interlocking X” Device, Exact, and Exxpol are trademarks of Exxon Mobil Corporation.
Worldwide Sales Offices
EXACT Plastomers Grade
(CAS# 26221-73-8)
Type of Ethylene Copolymer
FDA Status
Americas ExxonMobil Chemical 13501 Katy Frwy. Houston, Texas 77079 Tel. 281.584.7614 Fax 281.588.2577
EXACT™ Plastomers Grade Slate And Product Guide
Europe ExxonMobil Chemical Hermeslaan, 2 B-1831 Machelen, Belgium Tel. 32.02.722.4363 Fax 32.02.722.4369 Asia Pacific ExxonMobil Chemical 1 HarbourFront Place #06-00 HarbourFront Tower One Singapore 098633 Tel. 65.6885.8473 Fax 65.6885.8488
Products with densities ≥0.880 g/cc may not be available in all regions.
HEXENE OCTENE
1a
1b
2
3 4
5
6
Complies with FDA regulation 21 CFR 177.1520 “Olefin polymers” paragraph (c)3.2a, and may be used as articles or components of articles intended for use in contact with food, including use in articles used for packing or holding food during cooking. Complies with FDA regulation 21 CFR 177.1520 “Olefin polymers” paragraph (c)3.2a, and may be used as articles or components of articles intended for use in contact with food, including use in articles used for packing or holding food during cooking. Finished articles may contact all food types identified in Table 1 of CFR 176.170(c) only under Conditions of Use B through H described in Table 2 of 21 CFR 176.170(c), at temperatures not in excess of 212°F. Complies with FDA regulation 21 CFR 177.1520 “Olefin polymers” paragraph (c)3.1a, and may be used as articles or components of articles intended for use in contact with food, except for articles used for packing or holding food during cooking. Complies with FDA regulation 21 CFR 177.1520 “Olefin polymers” paragraph (c)3.6, provided that it is used only as a blend component with specific regulated FDA materials to make films no thicker than 4 mils. Complies with FDA Regulation 21 CFR 175.105 “Adhesives” and may be used to prepare adhesives that are used as components of articles intended for use in packaging, transporting or holding food, subject to the restrictions provided in 21 CFR 175.105 (a) (2). Complies with FDA regulation 21 CFR 177.1520 “Olefin polymers” paragraph (c)3.2a, and may be used as articles or components of articles intended for use in contact with food, including use in articles used for packing or holding food during cooking. Complies with FDA regulation 21 CFR 177.1520 “Olefin polymers” paragraph (c)3.2c, and may be used in materials or articles that contact food. Finished articles may contact all food types identified in Table 1 of CFR 176.170(c) only under Conditions of Use C through H described in Table 2 of 21 CFR 176.170(c), at temperatures up to hot-filled or pasteurized above 150°F (less than 212°F).
A Well-Balanced Portfolio For Your Precise Needs.
exactplastomers.com exxonmobilchemical.com
Printed in U.S.A. • August 2006 • 119-0806-100 • 2,000
FDA Note FDA Statement
Typical Applications and Properties of EXACT™ Plastomers Grades
EXACT™ Plastomers Grade Slate 100
Polymer Modification Ethylene Butene
EXACT Plastomers Grade
0230
8230
10
4006 8210
0210 3139
5371
4049
4150 4056
1 5062
0 0.86
0203 4151
4053
3128 3132
5181 8201
5171
3024
3035 3131
8203
5361
5101 0201 0201FX
3024 3035
•
4006 4053
•
0201 0203 0210 0230 5061 5062 5101 5171
• • •
5181 5361 5371 8201
5061
8203 8210 8230
0.87
0.88
0.89
Extrusion
BlowMolded Packaging
Injection Molding
TPOs
Foams
Rotomolding
0.90
• • • • • • • • • •
• • • •
•
• •
• • •
•
• •
• •
• • • • • •
• • • • •
EXACTTM Plastomers are a family of ethylene alpha olefin copolymers produced using ExxonMobil Chemical’s ExxpolTM metallocene catalyst technology. They offer a unique set of properties in which rubber-like properties and plastic processbring value to your products. They enhance the toughness, clarity and sealing performance of flexible packaging materials. In molded and extruded products, they improve impact strength and flexibility. The combination of comonomer type and process technology offered by ExxonMobil results in a wide range of products designed to serve customers’ unique needs:
Hexene Outstanding toughness and puncture resistance for film applications Excellent hot-tack strength and seal-through contamination in film heat-seal applications
Octene Excellent toughness and heat-seal properties for film applications Easy processing for all applications due to shear thinning characteristics Low density grades for outstanding low temperature impact resistance in PP-based TPOs
Flexural Modulus 1% Sec (MPa)
Ultimate Tensile Strength (MPa)
Hardness
(g/cc)
Melt Index 190°C, 2.16 kg (dg/min)
(Shore A)
DSC Melting Peak, 10°C/min (°C)
ExxonMobil
ASTM D-1238
ASTM D-790
ASTM D-638
ASTM D-2240
ExxonMobil
3024 3035 4006 4053 0201 0203 0210 0230 5061 5062 5101
0.905 0.900 0.880 0.888 0.902 0.902 0.902 0.902 0.868 0.860 0.902
4.5 3.5 10 2.2 1.1 3.0 10 30 0.5 0.5 1.1
100 70 17 27 68 76 76 80 12 6 88
16 16 6 22 >21 >21 14.8 11 >7 >4 >21
90 94 79 84 90 87 85 88 65 57 90
97 88 60 70 97 94 96 95 53 43 98
5171 5181 5361 5371 8201 8203 8210 8230
0.870 0.882 0.860 0.870 0.882 0.882 0.882 0.882
1.0 1.1 3.0 5.0 1.1 3.0 10 30
13 26 4 13 26 28 26 26
>8 >14 1.4 >5 >14 >10 >8 6
70 84 52 70 78 80 79 75
55 73 36 64 67 73 74 77
Film/Flexible Packaging EXACT Plastomers Grade
Heat Seal Layer
Fresh Produce Packaging
Cling Layer in Stretch Film
Extrusion Coating
Batch Inclusion Bag Film
Toughness Layer
ability are realized in one material. Used neat or as polymer modifiers, EXACT Plastomers offer endless possibilities to
Good property balance in PP-based TPOs
Density
0.91
Density (g/cc)
Butene Good film properties, including high oxygen transmission rates for fresh produce packaging
EXACT Plastomers Grade Test Method Based on:
3040
Melt Index (dg/min)
EXACT™ PLASTOMERS – FOR YOUR PRECISE NEEDS
Ethylene Hexene Ethylene Octene
BLOWN FILM 3128 4053 3132 4056 4151 0201/0201FX1 5101 5181 8201 CAST FILM 3024 4053 4049 3040 3131 3139 4150 4151 0203 0210 0230 8203 8210 8230
BUTENE
• • •
• • •
• • • • •
• • • • •
• •
•
• • • • •
• • • •
•
•
HEXENE OCTENE
• •
•
•
• • • •
• •
• • • • •
• • • •
EXACT Plastomers Grade
Density (g/cc)
Melt Index 1% Secant Modulus 190°C, 2.16 kg MD/TD (dg/min) (MPa)
Test Method Based on:
ExxonMobil
ASTM D-1238
ASTM D-882
BLOWN FILM 3128 4053 3132 4056 4151 0201 5101 5181 8201
0.900 0.888 0.900 0.883 0.895 0.902 0.902 0.882 0.882
1.3 2.2 1.2 2.2 2.2 1.1 1.1 1.1 1.1
73/77 34/38 73/78 30/34 56/61 68/75 73/83 29/35 28/33
CAST FILM 3024 4053 4049 3040 3131 3139 4150 4151 0203 0210 0230 8203 8210 8230
0.905 0.888 0.873 0.900 0.900 0.900 0.895 0.895 0.902 0.902 0.902 0.882 0.882 0.882
4.5 2.2 4.5 16.5 3.5 7.5 3.5 2.2 3.0 10 30 3.0 10 30
1. EXACT 0201FX is EXACT 0201 with slip and anti-block
Tensile Strength MD/TD (MPa) ASTM D-882
Dart Drop DSC Melting Impact, Peak, 10°C/min F50 (g) (°C) ASTM D-1709(A)
ExxonMobil
60/52 57/50 74/74 78/72 78/72 56/61 66/63 56/54 66/52
670 140 1330 1030 1215 610 600 225 270
92 69 96 72 88 96 99 71 71
85/97 37/36
48/32 65/46
140 120
70/76 67/75 68/76 56/59 56/64 73/84 70/77 69/74 33/38 30/32
55/47 74/61 66/56 78/70 85/69 66/51 44/35 32/25 55/45 35/29
100 1050 240 540 940 230 90 70 170 70
97 69 53 95 94 95 89 88 95 95 95 72 73
FDA Note
3024
0.905
4.5
1a
3035
0.900
3.5
1a
3128
0.900
1.2
1a
4006
0.880
10
4
4053
0.888
2.2
3
4049
0.873
4.5
4
3040
0.900
16.5
2
3131
0.900
3.5
1b
3132
0.900
1.2
1b
3139
0.900
7.5
1b
4056
0.883
2.2
4
4150
0.895
3.5
2
4151
0.895
2.2
1b
0201
0.902
1.1
5
0201FX
0.902
1.1
1b
0203
0.902
3.0
5
0210
0.902
10
6
0230
0.902
30
6
5061
0.868
0.5
6
5062
0.860
0.5
6
5101
0.902
1.1
5
5171
0.870
1.0
6
5181
0.882
1.1
6
5361
0.860
3.0
6
5371
0.870
5.0
6
8201
0.882
1.1
6
8203
0.882
3.0
6
8210
0.882
10
6
8230
0.882
30
6
(CAS# 25213-02-9) (CAS# 25087-34-7)
Density (g/cc)
BUTENE
©2006 Exxon Mobil Corporation. The user may forward, distribute, and/or photocopy this copyrighted document only if unaltered and complete, including all of its headers, footers, disclaimers, and other information. ExxonMobil does not guarantee the typical (or other) values. Typical values only represent the values one would expect if the property were tested in our laboratories with our test methods on the specified date. Some product properties are not frequently measured, and accordingly typical values are not based upon a statistically relevant number of tests. The information in this document relates only to the named product or materials when not in combination with any other product or materials. We based the information on data believed to be reliable on the date compiled, but we do not represent, warrant, or otherwise guarantee, expressly or impliedly, the merchantability, fitness for a particular purpose, suitability, accuracy, reliability, or completeness of this information or the products, materials, or processes described. The user is solely responsible for all determinations regarding any use and any process. We expressly disclaim liability for any loss, damage, or injury directly or indirectly suffered or incurred as a result of or related to anyone using or relying on any of the information in this document. There is no warranty against patent infringement, nor any endorsement of any product or process, and we expressly disclaim any contrary implication. The terms, “we,” “our,” “ExxonMobil Chemical,” or “ExxonMobil” are used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates they directly or indirectly steward. ExxonMobil, the “Interlocking X” Device, Exact, and Exxpol are trademarks of Exxon Mobil Corporation.
Worldwide Sales Offices
EXACT Plastomers Grade
(CAS# 26221-73-8)
Type of Ethylene Copolymer
FDA Status
Americas ExxonMobil Chemical 13501 Katy Frwy. Houston, Texas 77079 Tel. 281.584.7614 Fax 281.588.2577
EXACT™ Plastomers Grade Slate And Product Guide
Europe ExxonMobil Chemical Hermeslaan, 2 B-1831 Machelen, Belgium Tel. 32.02.722.4363 Fax 32.02.722.4369 Asia Pacific ExxonMobil Chemical 1 HarbourFront Place #06-00 HarbourFront Tower One Singapore 098633 Tel. 65.6885.8473 Fax 65.6885.8488
Products with densities ≥0.880 g/cc may not be available in all regions.
HEXENE OCTENE
1a
1b
2
3 4
5
6
Complies with FDA regulation 21 CFR 177.1520 “Olefin polymers” paragraph (c)3.2a, and may be used as articles or components of articles intended for use in contact with food, including use in articles used for packing or holding food during cooking. Complies with FDA regulation 21 CFR 177.1520 “Olefin polymers” paragraph (c)3.2a, and may be used as articles or components of articles intended for use in contact with food, including use in articles used for packing or holding food during cooking. Finished articles may contact all food types identified in Table 1 of CFR 176.170(c) only under Conditions of Use B through H described in Table 2 of 21 CFR 176.170(c), at temperatures not in excess of 212°F. Complies with FDA regulation 21 CFR 177.1520 “Olefin polymers” paragraph (c)3.1a, and may be used as articles or components of articles intended for use in contact with food, except for articles used for packing or holding food during cooking. Complies with FDA regulation 21 CFR 177.1520 “Olefin polymers” paragraph (c)3.6, provided that it is used only as a blend component with specific regulated FDA materials to make films no thicker than 4 mils. Complies with FDA Regulation 21 CFR 175.105 “Adhesives” and may be used to prepare adhesives that are used as components of articles intended for use in packaging, transporting or holding food, subject to the restrictions provided in 21 CFR 175.105 (a) (2). Complies with FDA regulation 21 CFR 177.1520 “Olefin polymers” paragraph (c)3.2a, and may be used as articles or components of articles intended for use in contact with food, including use in articles used for packing or holding food during cooking. Complies with FDA regulation 21 CFR 177.1520 “Olefin polymers” paragraph (c)3.2c, and may be used in materials or articles that contact food. Finished articles may contact all food types identified in Table 1 of CFR 176.170(c) only under Conditions of Use C through H described in Table 2 of 21 CFR 176.170(c), at temperatures up to hot-filled or pasteurized above 150°F (less than 212°F).
A Well-Balanced Portfolio For Your Precise Needs.
exactplastomers.com exxonmobilchemical.com
Printed in U.S.A. • August 2006 • 119-0806-100 • 2,000
FDA Note FDA Statement
Typical Applications and Properties of EXACT™ Plastomers Grades
EXACT™ Plastomers Grade Slate 100
Polymer Modification Ethylene Butene
EXACT Plastomers Grade
0230
8230
10
4006 8210
0210 3139
5371
4049
4150 4056
1 5062
0 0.86
0203 4151
4053
3128 3132
5181 8201
5171
3024
3035 3131
8203
5361
5101 0201 0201FX
3024 3035
•
4006 4053
•
0201 0203 0210 0230 5061 5062 5101 5171
• • •
5181 5361 5371 8201
5061
8203 8210 8230
0.87
0.88
0.89
Extrusion
BlowMolded Packaging
Injection Molding
TPOs
Foams
Rotomolding
0.90
• • • • • • • • • •
• • • •
•
• •
• • •
•
• •
• •
• • • • • •
• • • • •
EXACTTM Plastomers are a family of ethylene alpha olefin copolymers produced using ExxonMobil Chemical’s ExxpolTM metallocene catalyst technology. They offer a unique set of properties in which rubber-like properties and plastic processbring value to your products. They enhance the toughness, clarity and sealing performance of flexible packaging materials. In molded and extruded products, they improve impact strength and flexibility. The combination of comonomer type and process technology offered by ExxonMobil results in a wide range of products designed to serve customers’ unique needs:
Hexene Outstanding toughness and puncture resistance for film applications Excellent hot-tack strength and seal-through contamination in film heat-seal applications
Octene Excellent toughness and heat-seal properties for film applications Easy processing for all applications due to shear thinning characteristics Low density grades for outstanding low temperature impact resistance in PP-based TPOs
Flexural Modulus 1% Sec (MPa)
Ultimate Tensile Strength (MPa)
Hardness
(g/cc)
Melt Index 190°C, 2.16 kg (dg/min)
(Shore A)
DSC Melting Peak, 10°C/min (°C)
ExxonMobil
ASTM D-1238
ASTM D-790
ASTM D-638
ASTM D-2240
ExxonMobil
3024 3035 4006 4053 0201 0203 0210 0230 5061 5062 5101
0.905 0.900 0.880 0.888 0.902 0.902 0.902 0.902 0.868 0.860 0.902
4.5 3.5 10 2.2 1.1 3.0 10 30 0.5 0.5 1.1
100 70 17 27 68 76 76 80 12 6 88
16 16 6 22 >21 >21 14.8 11 >7 >4 >21
90 94 79 84 90 87 85 88 65 57 90
97 88 60 70 97 94 96 95 53 43 98
5171 5181 5361 5371 8201 8203 8210 8230
0.870 0.882 0.860 0.870 0.882 0.882 0.882 0.882
1.0 1.1 3.0 5.0 1.1 3.0 10 30
13 26 4 13 26 28 26 26
>8 >14 1.4 >5 >14 >10 >8 6
70 84 52 70 78 80 79 75
55 73 36 64 67 73 74 77
Film/Flexible Packaging EXACT Plastomers Grade
Heat Seal Layer
Fresh Produce Packaging
Cling Layer in Stretch Film
Extrusion Coating
Batch Inclusion Bag Film
Toughness Layer
ability are realized in one material. Used neat or as polymer modifiers, EXACT Plastomers offer endless possibilities to
Good property balance in PP-based TPOs
Density
0.91
Density (g/cc)
Butene Good film properties, including high oxygen transmission rates for fresh produce packaging
EXACT Plastomers Grade Test Method Based on:
3040
Melt Index (dg/min)
EXACT™ PLASTOMERS – FOR YOUR PRECISE NEEDS
Ethylene Hexene Ethylene Octene
BLOWN FILM 3128 4053 3132 4056 4151 0201/0201FX1 5101 5181 8201 CAST FILM 3024 4053 4049 3040 3131 3139 4150 4151 0203 0210 0230 8203 8210 8230
BUTENE
• • •
• • •
• • • • •
• • • • •
• •
•
• • • • •
• • • •
•
•
HEXENE OCTENE
• •
•
•
• • • •
• •
• • • • •
• • • •
EXACT Plastomers Grade
Density (g/cc)
Melt Index 1% Secant Modulus 190°C, 2.16 kg MD/TD (dg/min) (MPa)
Test Method Based on:
ExxonMobil
ASTM D-1238
ASTM D-882
BLOWN FILM 3128 4053 3132 4056 4151 0201 5101 5181 8201
0.900 0.888 0.900 0.883 0.895 0.902 0.902 0.882 0.882
1.3 2.2 1.2 2.2 2.2 1.1 1.1 1.1 1.1
73/77 34/38 73/78 30/34 56/61 68/75 73/83 29/35 28/33
CAST FILM 3024 4053 4049 3040 3131 3139 4150 4151 0203 0210 0230 8203 8210 8230
0.905 0.888 0.873 0.900 0.900 0.900 0.895 0.895 0.902 0.902 0.902 0.882 0.882 0.882
4.5 2.2 4.5 16.5 3.5 7.5 3.5 2.2 3.0 10 30 3.0 10 30
1. EXACT 0201FX is EXACT 0201 with slip and anti-block
Tensile Strength MD/TD (MPa) ASTM D-882
Dart Drop DSC Melting Impact, Peak, 10°C/min F50 (g) (°C) ASTM D-1709(A)
ExxonMobil
60/52 57/50 74/74 78/72 78/72 56/61 66/63 56/54 66/52
670 140 1330 1030 1215 610 600 225 270
92 69 96 72 88 96 99 71 71
85/97 37/36
48/32 65/46
140 120
70/76 67/75 68/76 56/59 56/64 73/84 70/77 69/74 33/38 30/32
55/47 74/61 66/56 78/70 85/69 66/51 44/35 32/25 55/45 35/29
100 1050 240 540 940 230 90 70 170 70
97 69 53 95 94 95 89 88 95 95 95 72 73
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Plastomers Gradeslate Productguide
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