Pigment Dyeing - Exhausion

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TECHNICAL DEPARTMENT

Exhaustion

AVCO VIETNAM May 2006

Pigment Dyeing Overview

YOUR PARTNER IN TEXTILE CHEMISTRY…

TECHNICAL DEPARTMENT

PIGMENT DYEING

BACKGROUND V

Pigment dyeing is not really " dyeing" in it's truest form.

V

Pigments are insoluble in water. They are milled into a paste for garment dyeing purposes.

V

The process is complete when a binder is added to "lock" the pigment into place.

TECHNICAL DEPARTMENT

V

Pigments are generally used for light to medium dyeing for fully fashioned garments and for indoor cloth such as wall covering, furniture, table cloth and bed sheets…

V

Pigments are also used to achieve dark shades for outdoor fabrics like tents, stores, awnings…

V

The process is attractive when dyeing cotton/synthetics fabrics in a single phase. AVCO VIETNAM May 2006

Pigment Dyeing Overview

YOUR PARTNER IN TEXTILE CHEMISTRY…

TECHNICAL DEPARTMENT

PURPOSES

MARKET OVERVIEW V

GARMENT MANUFACTURERS MOVING AWAY FROM EUROPE

V

TECHNICAL AND SPECIALITY EFFECTS DEMANDED IN THE MARKET

V

HIGH QUALITY FASTNESS REQUIREMENTS

V

« DELAVE » LOOK GARMENTS WHERE FASTNESS REQUIREMENTS ARE LESS IMPORTANT

V

“RIGHT FIRST TIME” & DELIVERY DEADLINE PRESSURE FOR FASHIONABLE GARMENT

V

ENVIRONMENTAL RESTRICTION ESPACIALLY IN EU, US AVCO VIETNAM May 2006

Pigment Dyeing Overview

YOUR PARTNER IN TEXTILE CHEMISTRY…

TECHNICAL DEPARTMENT

TECHNICAL DEPARTMENT

MARKET DEMAND

PIGMENT DYEING BY EXHAUSTION Machinery: Rottery Washing Machine/ Winches/Jet

V

Effective method for garment dyeing using a combination of performing cationic mordant: AVCOFIX EP-25 and a specific binder AVCOBINDER D

V

After Bleaching, the dyeing method is carried out in two steps:

TECHNICAL DEPARTMENT

TECHNICAL DEPARTMENT

V

1. Cationisation & 2. AVCOLOR/DYEFIX Dyeing

AVCO VIETNAM May 2006

Pigment Dyeing Overview

YOUR PARTNER IN TEXTILE CHEMISTRY…

PIGMENT DYEING BY EXHAUSTION V

HALF-BLEACH

NaOH

98° C

30’

AVCOSAN LPD 15’ 80° C

H2O2

• Add chemicals.

TECHNICAL DEPARTMENT

• Heat to 98°C and treat at 98°C for 30 min. • Cool to 80°C, • add AVCOSAN LPD run for 15min. Drop. • Neutralize with Acetic acid at 70°C • Rinse cold 10 min.

AVCO VIETNAM May 2006

Pigment Dyeing Overview

YOUR PARTNER IN TEXTILE CHEMISTRY…

TECHNICAL DEPARTMENT

AVCO-ANTIFOAM 100 AVCO-SLIP LB AVCO-BIOLUZE DCB AVCO-STABIQUEST HS

PIGMENT DYEING BY EXHAUSTION V

TWO –STEP PROCESS

1. Cationisation 60°C

1°C/min

Adjust pH 4.5 – 5.5 with AVCOCID PHS AVCOFIX EP-25 dosing

TECHNICAL DEPARTMENT

• Add: AVCOSLIP RF & AVCOAVCO-ANTIFOAM 100 • Add: AVCOFIX EPEP-25 • Heat to 60° 60°C – 1°C/min. • Treat at 60° 60°C for 20min – drop. • Rinse cold 5 min. 2 times

AVCO VIETNAM May 2006

Pigment Dyeing Overview

YOUR PARTNER IN TEXTILE CHEMISTRY…

TECHNICAL DEPARTMENT

AVCO-SLIP RF AVCO-ANTIFOAM 100

20’

PIGMENT DYEING BY EXHAUSTION V

TWO –STEP PROCESS CONT. 2. AVCOLOR/ DYEFIX Dyeing 70°C

AVCO-SLIP RF ANTIFOAM 100 AVCO-LEVELER NI AVCO-BIOLUZE DCB

10’

20’

Check for full exhaustion Add 5g/l Na2SO4

X % DYEFIX PIGMENTS dosing 10’

• Add: AVCOSLIP RF, ANTIFOAM 100, LEVELER NI & BIOLUZE DCB

TECHNICAL DEPARTMENT

• Adjust pH 4.5 -5.5 with AVCOCID PHS • Add slowly AVCOLOR/ DYEFIX • Heat to 70° 70°C – 1°C/min. • Run at 70° 70°C for 20min – Check for full exhaustion. • Add Na2SO4 if needed – run 10min. • Add AVCO BINDER D – run 5min – Drop. • Rinse cold 5min. Note: pigments must be stirred well before use AVCO VIETNAM May 2006

Pigment Dyeing Overview

YOUR PARTNER IN TEXTILE CHEMISTRY…

5’

TECHNICAL DEPARTMENT

1°C/mi n

Adjust pH 4.5 – 5.5 with AVCOCID PHS

AVCO BINDER D

PIGMENT DYEING BY EXHAUSTION V

Bio-polishing

80 °C

AVCOSON BPE

30’ – 60’

55°C

• Adjust pH 4.5 -5.5 with AVCOCID PHS • Heat to 55° 55°C. • Add AVCOSON BPE

TECHNICAL DEPARTMENT

• Run at 550C for 3030-60min. • Heat to 800C and run for 10min. • Drop • Rinse cold 5min.

AVCO VIETNAM May 2006

Pigment Dyeing Overview

YOUR PARTNER IN TEXTILE CHEMISTRY…

TECHNICAL DEPARTMENT

Adjust pH 4.55.5 with AVCOCID PHS

10’

PIGMENT DYEING BY EXHAUSTION V

Softening 1 – 2% AVCO-ELASTOSIL WNE 1 - 2 % AVCOSOFT 2005

40°C

20’ – 30’

• Adjust pH 4.5 -5.5 with AVCOCID PHS

TECHNICAL DEPARTMENT

• Add: AVCOAVCO-ELASTOSIL WNE - Hydrophilic silicone softener AVCOSOFT 2005 • Run at 400C for 2020-30min. • Drop

AVCO VIETNAM May 2006

Pigment Dyeing Overview

YOUR PARTNER IN TEXTILE CHEMISTRY…

TECHNICAL DEPARTMENT

Adjust pH 4.5-5.5 with AVCOCID PHS

V

Compatibility of all chemical & pigment is important for the whole process to run correctly

V

AVCO pigment dyeing process is developed thanks to our experience from production for many decades

V

Drying at maximum temperatures 100°C to 150°C is VITAL to achieve curing and good rub fastness. NO moisture should be left in the fabric. This is called “BONE DRY”.

V

Similar shades should be dried in the same drums in order to avoid staining.

AVCO VIETNAM May 2006

Pigment Dyeing Overview

YOUR PARTNER IN TEXTILE CHEMISTRY…

TECHNICAL DEPARTMENT

TECHNICAL DEPARTMENT

HIGHLIGHTS & TIPS

V

GIVES A UNIQUE «WASHED DOWN» OR «WEATHERED» LOOK ON THE GARMENTS STRAIGHT AFTER DYEING AND DRYING

V

IMPARTS A SOFT HANDLE TO THE DYED GARMENT WITHOUT SOFTENER ADDITION

V

MORE ECOLOGICAL: ALMOST TOTALY EXHAUSTED BATH

V

BETTER PENETRATION AND LEVELLING

V

BETTER COLOUR YIELD AS WELL AS HIGHER BRILLANCY NOTE: STAINING OF THE DYEING EQUIPMENT: For cleaning the machines we recommend to use AVCOCLEAN OGM. The dosage is depending on how strong is the staining. AVCO VIETNAM May 2006

Pigment Dyeing Overview

YOUR PARTNER IN TEXTILE CHEMISTRY…

TECHNICAL DEPARTMENT

TECHNICAL DEPARTMENT

STRENGTHS

CONTACT AVCO VIETNAM CO., LTD Plant: Nhon Trach Industrial Zone 1, Dong Nai Province, Vietnam

TECHNICAL DEPARTMENT

AVCO VIETNAM May 2006

Pigment Dyeing Overview

YOUR PARTNER IN TEXTILE CHEMISTRY…

TECHNICAL DEPARTMENT

HCMC Office: 28 Phan Liem Street, District 1, Ho Chi Minh City, Vietnam Tel: (848) 8208 940 – 41 -42 Fax: (848) 8208 943 E-mail: [email protected]

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