P Chem Lab 5

  • November 2019
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V{Fe 3+} (ml) Sample # [Fe 3+] (M)

1/[Fe 3+] (L/N)

1

5 5 5

1 2 3

0 0 0 0

2

6 6 6

1 2 3

0 0 0

3

7 7 7

1 2 3

0 0 0

4

8 8 8

1 2 3

0 0 0

5

9 9 9

1 2 3

0 0 0

6

10 10 10

1 2 3

0 0 0

558.66

STDev= 465.55

STDev= 399.04

STDev= 349.16

STDev= 310.37

STDev= 279.33

STDev= 7

11 11 11

1 2 3

0 0 0

8

12 12 12

1 2 3

0 0 0

9

13 13 13

1 2 3

0 0 0

10

14 14 14

1 2 3

0.01 0.01 0.01

253.94

STDev= 232.77

STDev= 214.87

STDev= 199.52

STDev=

A400 0 0.19 0.19 0.19 3.06E-04 0.22 0.22 0.22 3.06E-04 0.24 0.24 0.24 1.20E-03 0.26 0.26 0.26 1.56E-03 0.28 0.28 0.29 1.04E-03 0.3 0.31 0.3 1.51E-03 0.32 0.32 0.32 9.87E-04 0.34 0.34 0.35 3.05E-03 0.36 0.36 0.36 5.29E-04 0.37 0.36 0.36 1.67E-03

A455 0 0.39 0.39 0.39 4.00E-04 0.45 0.45 0.45 1.53E-04 0.5 0.5 0.5 2.17E-03 0.54 0.54 0.54 2.14E-03 0.58 0.59 0.58 1.94E-03 0.63 0.63 0.62 2.48E-03 0.67 0.67 0.67 1.04E-03 0.7 0.71 0.71 3.93E-03 0.73 0.73 0.73 1.76E-03 0.75 0.75 0.75 2.06E-03

A500 0.29 0.29 0.29 2.65E-04 0.33 0.33 0.33 3.00E-04 0.37 0.37 0.37 1.88E-03 0.4 0.4 0.4 2.77E-03 0.43 0.43 0.43 7.57E-04 0.46 0.47 0.46 2.69E-03 0.49 0.5 0.49 2.01E-03 0.52 0.52 0.53 3.63E-03 0.54 0.54 0.54 1.00E-03 0.56 0.55 0.55 3.03E-03

[SCN-] / A400 [SCN-] / A455

[SCN-] / A500

0 0 0

0 0 0

0 0 0

0 0 0

0 0 0

0 0 0

0 0 0

0 0 0

0 0 0

0 0 0

0 0 0

0 0 0

0 0 0

0 0 0

0 0 0

0 0 0

0 0 0

0 0 0

0 0 0

0 0 0

0 0 0

0 0 0

0 0 0

0 0 0

0 0 0

0 0 0

0 0 0

0 0 0

0 0 0

0 0 0

[SCN-] stock (M) [Fe 3+] stock 0 0.0179 M

[SCN-]Total/Aλ vs. 1/[Fe 3+]total 0

0.8 0.7 [SCN-] / A400

0

[SCN-] / A455 [SCN-] / A500 Linear regression, [SCN-] / A400 Linear regression, [SCN-] / A455 Linear regression, [SCN-] / A500

0 0 0 0 0 0 0

100

200

300 1/[Fe 3+]total

400

500

600

0.6 Absorbance ()

[SCN-]Total/Aλ

0

0.5 0.4 0.3 0.2 0.1 0 0

[Fe 3+] vs Absorbance 0.8 0.7 Absorbance ()

0.6 0.5 A400 A455 A500

0.4 0.3 0.2 0.1 0 0

0

0

0

0

0

0

[Fe 3+] (M)

0

0

0

0.01

0.01

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