Msds Colamine 1-76

Material Safety Data Sheet Cola®Mine 1-76 Page 1 of 3 Emergency Telephone # 423/837-8800 Chemtrec 800/424-9300

Colonial Chemical, Inc. 225 Colonial Drive S.Pittsburg, TN 37380 Product Name: C.A.S. No.: Product Class: Hazard Rating:

SECTION I – PRODUCT INFORMATION Cola®Mine 1-76 File: 1-76 Proprietary Blend Alkanolamide Health: 1 Flammability: 1 Reactivity: 0

Direct Phone:

423/837-8800

THE CHEMTREC NUMBER IS TO BE CALLED ONLY IN THE EVENT OF CHEMICAL EMERGENCIES INVOLVING A SPILL, LEAK, FIRE, EXPOSURE OR ACCIDENT INVOLVING CHEMICALS. Emergency Overview: May cause moderate eye and skin irritation. SECTION II – HAZARDOUS INGREDIENTS Ingredients CAS # Weight % PEL (ppm) DIETHANOLAMINE

111-42-2

TLV (ppm)

18

*** All ingredients in this product are listed in the TSCA Inventory. SECTION III – PHYSICAL DATA Appearance: Clear light amber liquid Boiling Point (°F): 150° F % Volatile: NIL Vapor Pressure: Not determined Vapor Density: Estimated heavier than air Evaporation Rate: Estimated slower than ethyl ether pH (10% AQ.): 9.0 Specific Gravity @25°C: 0.99 SECTION IV – FIRE AND EXPLOSION HAZARD DATA Flash Point: 201°F Extinguishing Media: CO2, foam, dry chemical, BC/ABC extinguishers Special Fire Fighting Procedures: Firefighters should wear full protective clothing including self-contained breathing apparatus Unusual Fire and Explosion Hazards: None SECTION V – REACTIVITY DATA Stability: Stable under normal conditions Hazardous Polymerization: Will not occur Incompatibility (Materials to avoid): Strong-oxidizing agents. Hazardous Decomposition Products: Oxides of carbon and nitrogen

Cola®Mine 1-76

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SECTION VI – HEALTH HAZARD DATA EMERGENCY OVERVIEW: May cause irritation to the eyes, skin, and respiratory system. HEALTH EFFECTS: Eyes – May cause irritation Skin – Prolonged and/or repeated skin contact with this product may cause irritation/dermatitis Inhalation – Vapors or mists may be irritating to respiratory system FIRST AID: Eye Contact -

Immediately flush with copious amounts of water for at least 15 minutes while holding eyelids open. Consult physician. Skin Contact- Immediately flush with copious amounts of soap and water for at least 5 minutes. Remove contaminated clothing. If irritation persists, contact physician. Launder contaminated clothing before reuse. IngestionIf patient is conscious and can swallow, give 2 glasses of water. Call a physician or Poison Control Center immediately. Induce vomiting as directed by medical personnel. InhalationRemove to fresh air – if necessary give oxygen, artificial respiration. Contact physician. Ingestion If material is swallowed, get medical attention immediately. SECTION VII – SPECIAL PROTECTION INFORMATION Occupational Exposure Limits ACGIH TLV ACGIH TLV-C ACGIH STEL OSHA STEL OSHA PEL DIETHANOLAMINE 0.46 PPM N/est N/est N/est 3.00 PPM Respiratory Protection:

If vapors are present, use a NIOSH approved respirator for ammoniacal vapors, air-line respirator, or a self-contained breathing apparatus. Ventilation: Provide adequate local exhaust ventilation to maintain worker exposure below exposure limits. Local exhaust is suggested for use, where possible, in enclosed or confined spaces. Eye Protection: Chemical goggles Protective Gloves: Impervious Other Protection: Wear protective clothing to prevent skin contact. Eye wash stations and safety showers are recommended. SECTION VIII – SPECIAL PRECAUTIONS HANDLING PROCEDURES: Wash thoroughly after handling. STORAGE PROCEDURES: Avoid freezing or excessive heat. OTHER PRECAUTIONS: Spilled material is quite slippery. SPILL OR LEAK PROCEDURES: Absorb spill with inert material. Shovel material into appropriate container for disposal. Flush area with water to remove trace residue. Do not allow the spilled product to enter public drainage system or open watercourses. Ventilate the contaminated area.

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SECTION IX – REGULATORY INFORMATION TSCA: Listed in TSCA inventory. SARA TITLE III – Section 313: Diethanolamine, See Section II SECTION X – WASTE DISPOSAL Waste Disposal Method: In accordance with local, state and federal regulations. SECTION XI – TOXICOLOGICAL INFORMATION CARCINOGENICITY: No carcinogenicity data available for this product. OTHER TOXICOLOGICAL INFORMATION: Do not use nitrosating agents with this product since nitrosamines may form. Some nitrosamines have been shown to be carcinogenic tests with laboratory animals. NIOSH – SELECTED LD50s AND LC50s: Diethanolamine CAS #: 111-42-2 Oral LD50 Rat: 620 uL/kg; Oral LD50 Mouse: 3300 mg/kg; Dermal LD50 Rabbit: 7640 uL/kg

SECTION XII – TRANSPORTATION INFORMATION Proper Shipping Name: Environmentally Hazardous Substance, liquid N.O.S. (contains Diethanolamine) DOT Hazard Class: 9 UN Number: UN3082 Packing Group: III ***This item contains Diethanolamine, which has an RQ amount of 100 pounds. Any container that holds an equal or greater amount is a DOT hazardous substance and is shipped as stated above. ***Any container containing a lesser amount is non-regulated.

HEALTH FLAMMABILITY REACTIVITY PERSONAL PROTECTION

1 1 0 B

The above data is for information purposes only and is accurate to the best of Colonial Chemical, Inc.’s knowledge. No guarantees or liabilities are expressed or implied.

REVISED: 06-16-2006

J.STAFFORD