Foam Data Sheet

  • December 2019
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TECHNICAL DATA & APPLICATION DATA SHEET What is Jack Frost Foam™? Jack Frost Foam™ is a protective barrier against cold temperatures that can harm a plant. Jack Frost Foam™ is made up of three products that when combined in a mix tank will produce a long lasting, superior insulating, plant friendly, and economical insulating foam blanket.

Jack Frost Foam™ Products & tank applications: Jack Frost Foam™ consists of three formulas: 1) A foam stabilizer called Formula A used at a rate of 5.5% of tank volume (Read label for directions of use). 2) A plant safe foaming base called Formula B used at a rate of 1.2% of tank volume (Read label for directions of use). 3) An activator called Ph Activator used at a rate of approximate 2.8% +/- of tank volume (Read label for directions of use).

Important: NOTE the correct volume of ph Activator must be used to raise entire tank mix ph to between 7.4-7.8. Absolutely no other ph adjusting material, is to be used with any or all Jack Frost Foam’s™ products. Plant kill or damage can result.

Jack Frost Foam™ Product placement Procedure in mix tank must be in the following order (steps). Calculate mix tank volume using tank mix calculator 1) Water is added 1st to tank. 2) Formula A (application rate is 5.5% of tank volume) is added 2nd to tank and allowed to mix thoroughly with water. 3) Formula B (application rate is 1.2% of tank volume) is added 3rd to tank and allowed to mix thoroughly with water and Formula A. 4) When, steps 1 to 3 have thoroughly mixed in the tank, check ph of tank contents. 5) Directions for adding Ph Activator to mix tank, A.) Ph Activator (application rate is approximately 2.8% of tank volume) is added 4th to tank and allowed to mix thoroughly. A final ph of 7.4-7.8 is recommended and needed for entire Jack Frost Foam tank mix. Procedure: to add Ph Activator to mix tank. Add Ph Activator into the mix tank in intervals of 1% (example add 1 gallon ph activator to 100 gallon mix tank) of tank volume. It is recommended to slowly increase the tank mix ph until a final tank mix ph of 7.4-7.8 is achieved. After each ph adjustment is made, a ph check of the tank mix is recommended (before checking ph of mix, allow contents of tank mix to thoroughly mix and ph to stabilize before an accurate ph check can be made).

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Note: When ph is approximately 7.2 it is recommended to use a rate of 0.25% (use rate of 0.25% as described in step 5-Procedure) of tank volume when adding Ph Activator into mix tank, so not to exceed recommended final ph range 7.4-7.8.

Important Note: Do not exceed over or under the recommended ph of tank mix 7.4-7.8 or Jack Frost Foam™ will not have the ability to: A.) Last for any specific duration of time. B.) Stay stable in the mix tank and perform (in a foam state) as it was designed. C.) Will not have insulating properties against cold weather or frost. D.) Protect plants and can result in plant death.

Important: Note: Changing the order/procedure as listed (above) for placing Jack Frost Foam™ products in the mix tank can cause reactions to occur in the mix tank and cause the entire mix tank to become defective and unstable. NOTE: User and or applicator/operator(s) accepts total liability for all damages or all loss for altering the procedure of adding Jack Frost foam™ products into the mix tank as listed above.

Substituting or adding other Products into mix tank: Adding another product or substituting another product and combining these products with any Jack Frost Foam™ product, can and will result in the following: A.) Total crop kill can result, entire crop will suffer a burn effect with total plant kill to follow. B.) The insulating foam will not last very long (foam will breakdown in 1-25 minutes) also resulting in a total plant kill. C) Plants will freeze due to an altered product is produced that is not designed to insulate a plant against a killer freeze. NOTE: User and or applicator/operator(s) accept total liability for all damages and all loss associated with substituting or adding other materials in the mix tank with Jack Frost Foam™.

Crops Jack Frost Foam can be used on: What crops can be covered with Jack Frost Foam™? The crops that Jack Frost foam™ has been tested on can be found on the bottom of our web site in the “view our power point presentation on the efficacy of Cryo-Protectant Material for Frost Protection”. A crop compatibility test is always recommended and required on any plant or crop not listed, before actual plant coverage use of Jack Frost Foam™ begins. NOTE: User and or applicator/operator(s) accepts total liability for all damages and all loss associated with not testing plant and or crop compatibility with Jack Frost Foam™ products. Crops previously tested are peppers, tomatoes, strawberries, squash, and watermelon. Jack Frost Foam™ can be applied several times on freeze events on the same crop. www.jackfrostfoam.com . American Ag. Foam recommends too spray down the foam with water the next morning (after the freeze event has passed) when the temperature is at 40º F and climbing. Washing down the surface of the foam will weaken the foam’s 2

surface membrane, allowing the foam to break down quicker. This is recommended in southern states, where temperatures will increase the next day of a freeze event. A wash down is also recommended for the following reasons: 1) Prevents overheating (overheating can damage plants resulting in plant kill) within the foam due to the insulating abilities that the foam blanket exhibits. 2) Washing will help to reduce or eliminate foam residue on the plant surface that is a natural occurrence of foam breakdown. Washing will also clean surface areas where possible injury to individuals can occur due to the Jack Frost Foam having a soapy slippery residual effect, which can cause injury to individuals that may fall due to slick surface conditions. Wind Conditions and Jack Frost Foam™. Jack Frost Foam™ can stand wind speeds of up to 9 MPH with little surface sheering occurring, when used on bare ground areas. In tested areas Jack Frost Foam™ holds better, on bare ground compared to a smooth surface such as row plastic. On ground plastic wind speed of 6 mph or lower is recommended before applying Jack Frost Foam™ to your crop. Future Jack Frost products will be available that will allow Jack Frost Foam to be applied in winds of 10-20 mph. Check at www.jackfrostfoam.com for future product updates.

Disclaimer: Jack Frost Foam™ will create a-long lasting insulating foam when label directions and all technical information on mixing instructions are followed. American Ag. Foam LLC warrants Jack Frost Foam™ against defects in foaming ability and insulating ability (Jack Frost Foam’s™ ability to insulate is determined by the temperature reached and duration of the cold event compared to the thickness of the foam blanket applied. Note: The thicker the foam blanket applied the better the insulating abilities provided). Read all information before using Jack Frost Foam™ on any crop. Check physical compatibility first on any and all crops before beginning use of Jack Frost Foam™. Compatibility Recommendation: using a 1 quart jar add the proportionate amounts of Jack Frost Foam™ products (follow label directions of each product) for a 1 (one) quart mix. After thoroughly mixing, let mixture stand for a minimum of 30 minutes. Growers/user must apply liquid mix to a sampling of plants (wet entire exposed surface of plant and leafs and leave on plant for a period of 10 hours. Lightly rinse off Jack Frost Foam from plant surface and monitor tested plants for several days to determine plants sensitivity to Jack Frost Foam. Do not use on plants if a burn or damage of tested plants is found) It is recommended to test Jack Frost foam’s™ mix for phytotoxicity, leaf burn, or plant kill prior to large scale foam use is started. If for any reason user/applicator does not understand any or all of the directions and information contained in Jack Frost Foams™ labels, MSDS, Technical Data & Application sheet or provided verbally. American Ag. Foam LLC and its distributors recommends for the user/applicator to ask someone with a technical background and ability to explain any and/or all the information in a form more understandable to the user/applicator. If an individual, is not available to explain the information to the user/applicator, American Ag. LLC Foam

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recommends that the applicator/user not apply Jack Frost Foam on any plants until all directions and information is fully understood. Due to the wide variation in climatic conditions, cultural practices and other factors, the User assumes full responsibility for any and all crop damage or other liability resulting from the incorrect use or misunderstanding of directions of Jack Frost Foam™ on a crop or plant. WARRANTY: American Ag. Foam L.L.C. warrants that the material contained herein conforms to the description on the label and is reasonably fit for the purposes referred to in the direction for use. Timing and method of application, weather, watering practices, nature of soil, conditions of the crop, improper application, incompatibility with other chemicals not specifically recommended, and other influencing factors in the use of this product are beyond the control of the seller. Buyer/User assumes all risks of use, storage, or handling of this material not in strict accordance with directions given herein. NO OTHER EXPRESS OR IMPLIED WARRANTY OF THE FITNESS OR MECHANTABILITY IS MADE.

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MATERIAL SAFETY DATA SHEET American Ag Foam LLC, 534 CR 529A Lake Panasoffkee, Florida 33538 EMERGENCY INFORMATION (352) 793-1682 SECTION I - PRODUCT IDENTIFICATION DATE PREPARED: March 01, 2005 PRODUCT NAME: Jack Frost pH Activator GENERAL/GENERIC ID: Foaming ph Buffer DOT SHIPPING CLASS: 50 HAZARD CLASSIFICATION: Health-1, Fire-1, Reactivity-0 HAZARD CLASSIFICATION KEY: 0-least, 1-slight, 2-moderate, 3-high, 4-extreme SECTION II -HAZARDOUS INGREDIENTS COMPONENT

CAS NUMBER

PERCENT

Water

7732-18-5

70-85%

Sodium Carbonate

497-19-8

3%

Residual Monomers

Not Required

27-12%

ACGIH TLV

EXPOSURE OSHA - PEL

SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS BOILING POINT (F): 212º F SPECIFIC GRAVITY: 1.00 +0.005 VAPOR PRESSURE (mm Hg): 17.0 mmHg @ 25º C (77º C)H2O VAPOR DENSITY (air=<1.0water) SOLUBILITY (in water): 100% EVAPORATION RATE: <1.00 water pH OF CONCENTRATE: 10.2 FREEZE POINT: 37º F APPEARANCE AND ODOR: amber liquid SECTION IV - FIRE & EXPLOSION HAZARD DATA FLASH POINT (F): Non-Combustible FLAMMABLE LIMITS: Not Determined LEL: NOT DETERMINED VEL: NOT DETERMINED EXTINGUISHING MEDIA: DRY CHEMICAL, Water Spray (FOG), CO2; Foam; Sand/Earth SPECIAL FIRE FIGHTING PROCEDURES: SELF CONTAINED POSITIVE PRESSURE BREATHING APPARATUS and Protective Fire Fighting Clothing UNUSUAL FIRE & EXPLOSION HAZARDS; Apply cooling water to sides of containers that are exposed to flames. SECTION V - REACTIVITY DATA STABILITY: Product is stable. CONDITIONS TO AVOID: Do not keep container with lid open for long periods of time. MATERIALS TO AVOID: Aluminum powder, acids, fluorine, molten lithium. HAZARDOUS DECOMPOSITION OR BY PRODUCTS: Burning may produce sodium oxide . HAZARDOUS POLYMERIZATION: Product will not undergo polymerization. CONDITIONS TO AVOID: Heating of product. Burn may result. Store in temperatures ranges between 50º - 80 º degree F. Fallout will occur and product will become defective.

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SECTION VI - HEALTH HAZARD DATA ROUTE(S) OF ENTRY: INHILATION: no SKIN: yes INGESTION: UNLIKELY HEALTH HAZARDS (ACUTE & CHRONIC): ACUTE: Vapors and mist irritate nose and throat. Inhalation of high concentrations may cause headaches, vomiting and coma. Prolonged exposure may cause unconsciousness or death. Prolonged or repeated skin contact may cause irritation and dermatitis. Swallowing large quantities can cause headaches, nausea, vomiting, stomach cramps and diarrhea, and can cause unconsciousness. CHRONIC: Prolong or repeated exposure to high concentrations can produce severe or fatal central nervous system depression. CARCINOGENICITY: IARC MONOGRAPHS: NO OSHA REGULATED: NO NTP: NO SIGNS AND SYMPTOMS OF EXPOSURE: Eye and skin irritation, headache, nausea, and vomiting. Prolonged or repeated exposure may cause unconsciousness. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Persons with pre-existing skin disorders, eye problems, or impaired respiratory function may be more susceptible to the effects of this substance. ***EMERGENCY AND FIRST AID PROCEDURES*** INGESTION: Do not induce vomiting contact a physician or poison control center immediately. Offer small amounts of water or milk. Never give anything by mouth to an unconscious person. EYE CONTACT: Flush with water for 15 minutes. Get medical attention if irritation persists. SKIN CONTACT: Flush with water for 15 minutes. Get medical attention if irritation persists. INHALATION: Remove victim to fresh air. Administer oxygen if breathing is difficult. Apply artificial respiration if victim is not breathing. Get immediate medical attention. SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE SPILL STEPS: Contain spill by containment wall with absorbent material. Recover for reuse or absorb small spills on absorbent material and dispose of in approved waste disposal containers. Prevent large quantities of this product to contact vegetation or waterways; large spills could kill vegetation and fish. WASTE DISPOSAL METHOD: Dispose of in accordance with local, state and federal regulations. When a decision is made to discard this material as supplied, it does not meet RCRA’s Characteristic definition of ignitability, corrosivity, or reactivity, and is not listed in 40 CFR 261. STORAGE & HANDLING: Store in a cool, dry, fire-resistant area between 50-85ºF, product will freeze below 41º F. Fallout will occur and product will become defective.

Keep out of reach of children and animals. SECTION VIII - CONTROL MEASURES CONDITIONS TO AVOID: Contact with strong acids except under controlled conditions. Reacts with acids with release of large volumes of carbon dioxide gas and heat. RESPIRATORY PROTECTION: If mist or dust conditions should be present use respirator approved by NIOSH. VENTILATION: Adequate ventilation is required to maintain a fresh airflow. LOCAL EXHAUST: Adequate EYES AND FACE: Goggles or face shield HANDS, ARMS AND BODY: Adequate clothing should be worn to prevent skin contact. Rubber/Plastic Gloves. WORK/HYGIENIC PRACTICES: Wash all clothing before wearing. Wash all exposed skin surfaces with soap and water after using this product. SPECIAL CLOTHING AND EQUIPMENT: Eye bath, safety shower and oxygen mask.

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Section IX TRANSPORTATION INFORMATION D.O.T Not regulated for transport. IMO/IMDG Not regulated (Not dangerous for Transport) Transportation classifications may vary by container volume and may be influenced by regional or country variation in regulations.

Section X REGULATORY INFORMATION Workplace Classification: This product is considered non-listed under the OSHA Hazard Communication Standard (29CFR1910.1200) This product is not a ‘controlled product’ under the Canadian Workplace Hazardous Materials Information System (WHMIS). SARA TITLE III: Section 302 Categorizations (40CFR370): This product is not a hazardous chemical under 40CFR 355, Appendix A and therefore is not covered by Title III of SARA. SARA TITLE III: Section 313 Information (40 CFR372) This product is not listed in Section 313 reportable ingredients . CERCLA Information (40CFR302.4) DESIGNATION & REPORTABLE QUANTITIES (RQ); is not listed. US. Toxic Substances Control Act (TSCA): All components of this product are in compliance with the inventory listing requirements of the U.S. Toxic Substance Control Act (TSCA) Chemical Substance Inventory. Not listed. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information, and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal, and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Unless specified in the text. .WARRANTY Neither this data sheet nor any statement contained herein grants or extends any license, expressed or implied, in connection with patents issued or pending which may be the property of the manufacturer or others. The information in this data sheet has been assembled by the manufacturer based on its own studies and on the work of others. The manufacturer makes no warranties, expressed or implied, as to the accuracy, completeness, or adequacy of the information contained herein. The manufacturer shall not be liable (regardless of fault) to the Vendee, the Vendee's employees, or anyone for any direct, special or consequential damages arising out of or in connection with the accuracy, completeness, adequacy, or furnishing of such information. Disclaimer: Jack Frost Foam will create a-long lasting insulating foam when label directions and all technical information on mixing instructions are followed. American Ag. Foam LLC warrants Jack Frost Foam against defects in foaming ability and insulating ability (Jack Frost Foam’s ability to insulate is determined by the temperature reached and duration of the cold event compared to the thickness of the foam blanket applied. Note: The thicker the foam blanket applied the better the insulating abilities provided). Read all information before using Jack Frost Foam on any crop. Check physical compatibility first on any and all crops before beginning use of Jack Frost Foam. Recommendation: using a 1 quart jar add the proportionate amounts of Jack Frost Foam products (follow label directions of each product) to 1 (one) quart of water. After thoroughly mixing, let mixture stand for at least 30 minutes. Growers/user must apply liquid mix to a sampling of plants (wet entire exposed surface of plants) to test Jack Frost foam’s mix for phytotoxicity, leaf burn, or plant kill prior to large scale foam use. If for any reason user/applicator does not understand any or all of the directions and information contained in Jack Frost Foams labels, MSDS, Technical Data & Application sheet or provided verbally. American Ag. Foam LLC and its distributors recommends for the user/applicator to ask someone with a technical background and ability to explain any and/or all the information in a form more understandable. If an individual is not available to explain the information to the user/applicator, American Ag Foam LLC and its distributors recommend that the user/applicator return any unopened Jack Frost Foam products for a full refund (a restocking fee may apply). Due to the wide variation in climatic conditions, cultural practices and other factors, the User assumes full responsibility for any and all crop damage or other liability resulting from the incorrect use or misunderstanding of directions of Jack Frost Foam on a crop or plant. WARRANTY: American Ag. Foam L.L.C. warrants that the material contained herein conforms to the description on the label and is reasonably fit for the purposes referred to in the direction for use. Timing and method of application, weather, watering practices, nature of soil, conditions of the crop, improper application, incompatibility with other chemicals not specifically recommended, and other influencing factors in the use of this product are beyond the control of the seller. Buyer/User assumes all risks of use, storage, or handling of this material not in strict accordance with directions given herein. NO OTHER EXPRESS OR IMPLIED WARRANTY OF THE FITNESS OR MECHANTABILITY IS MADE.

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MATERIAL SAFETY DATA SHEET MANUFACTURER American Ag Foam LLC, 534 CR 529A Lake Panasoffkee, Florida 33538 EMERGENCY INFORMATION (352)793-1682 SECTION I - PRODUCT IDENTIFICATION DATE PREPARED: March 01, 2005 PRODUCT NAME: Jack Frost Formula B GENERAL/GENERIC ID: Alpha Olefin Sulfonate DOT SHIPPING CLASS: 50 HAZARD CLASSIFICATION: Health-1, Fire-1, Reactivity-0 HAZARD CLASSIFICATION KEY: 0-least, 1-slight, 2-moderate, 3-high, 4-extreme SECTION II -HAZARDOUS INGREDIENTS COMPONENT

CAS NUMBER

PERCENT

ACGIH TLV

ETHYLENE GLYCOL BUTYL ETHER (SARA SECTION 313)

111-76-2

<5

25 ppm(skin)

ISOPROPYL ALCOHOL

67-63-0

<8

400ppm(PEL/TWA) 500(STEL)

EXPOSURE OSHA - PEL

SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS BOILING POINT (F): 148.1(IBP SPECIFIC GRAVITY: 1.04 +0.005 VAPOR PRESSURE (mm Hg): 92(20º C) VAPOR DENSITY (air=1): N/E SOLUBILITY (in water): 100% EVAPORATION RATE: N/E pH OF CONCENTRATE: 10.2 (1% SOL) FREEZE POINT: 35º F APPEARANCE AND ODOR: PALE AMBER LIQUID, ALCOHOL ODOR SECTION IV - FIRE & EXPLOSION HAZARD DATA FLASH POINT (F): 102º F FLAMMABLE LIMITS: Not Determined LEL: NOT DETERMINED VEL: NOT DETERMINED EXTINGUISHING MEDIA: DRY CHEMICAL, Water Spray (FOG), CO2; Foam; Sand/Earth SPECIAL FIRE FIGHTING PROCEDURES: SELF CONTAINED POSITIVE PRESSURE BREATHING APPARATUS and Protective Fire Fighting Clothing UNUSUAL FIRE & EXPLOSION HAZARDS: Apply cooling water to sides of containers that are exposed to flames.

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SECTION V - REACTIVITY DATA STABILITY: Product is stable. CONDITIONS TO AVOID: Heat, sparks, open flame MATERIALS TO AVOID: Strong Oxidizers such as Hydrogen Peroxide, Bromine and Chromic HAZARDOUS DECOMPOSITION OR BYPRODUCTS: Burning may produce carbon monoxide and/or carbon dioxide HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID: None SECTION VI - HEALTH HAZARD DATA ROUTE(S) OF ENTRY: INHILATION: yes SKIN: yes INGESTION: UNLIKELY HEALTH HAZARDS (ACUTE & CHRONIC): ACUTE: Vapors and mist irritate nose and throat. Inhalation of high concentrations may cause headaches, vomiting and coma. Prolonged exposure may cause unconsciousness or death. Liquid and mists can severely irritate or damage eyes and cause corneal burns. Prolonged or repeated skin contact may cause irritation and dermatitis. Swallowing large quantities may cause headaches, nausea, vomiting, stomach cramps and diarrhea, and can cause unconsciousness. CHRONIC: Prolonged or repeated exposure to high concentrations can produce severe or fatal central nervous system depression. CARCINOGENICITY: IARC MONOGRAPHS: NO OSHA REGULATED: NO NTP: NO SIGNS AND SYMPTOMS OF EXPOSURE: Eye and skin irritation, headache, nausea, and vomiting. Prolonged or repeated exposure may cause unconsciousness. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Persons with pre-existing skin disorders, eye problems, or impaired respiratory function may be more susceptible to the effects of this substance. ***EMERGENCY AND FIRST AID PROCEDURES*** INGESTION:DO NOT INDUCE VOMITING, CONTACT A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. OFFER SMALL AMOUNTS OF WATER OR MILK. EYE CONTACT:FLUSH WITH WATER FOR 15 MINUTES. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. SKIN CONTACT:FLUSH WITH WATER FOR 15 MINUTES. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. INHALATION: REMOVE VICTIM TO FRESH AIR, ADMINISTER OXYGEN IF BREATHING IS DIFFICULT. APPLY ARTIFICIAL RESPIRATION IF VICTIM IS NOT BREATHING. GET IMMEDIATE MEDICAL ATTENTION. SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE SPILL STEPS: Remove all sources of ignition. Contain spill by containment wall with absorbent material. Recover for reuse or absorb small spills on absorbent material and dispose of in approved waste disposal containers. WASTE DISPOSAL METHOD: Dispose of in accordance with local, state and federal regulations. STORAGE & HANDLING: Store in a cool, dry, fire-resistant area between 50-85ºF, product will freeze below 41º F. Fallout will occur and product will become defective. Ground all Equipment and provide adequate Ventilation when opening container caps. Handle all containers carefully. Keep away from heat and all ignition sources

Keep out of reach of children and animals.

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SECTION VIII - CONTROL MEASURES RESPIRATORY PROTECTION: If mist or dust conditions should be present use respirator approved by NIOSH. VENTILATION: Adequate ventilation is required to maintain a fresh air-flow. LOCAL EXHAUST: Adequate EYES AND FACE: Goggles or face shield HANDS, ARMS AND BODY: Adequate clothing should be worn to prevent skin contact. Rubber/Plastic Gloves. WORK/HYGIENIC PRACTICES: Wash all clothing before wearing. Wash all exposed skin surfaces with soap and water after using this product. SPECIAL CLOTHING AND EQUIPMENT: Eye bath, safety shower and oxygen mask.

Section IX REGULATORY INFORMATION SARA HAZARD: Title III, Section 313: Contains the Glycol Ether listed above at 2-4% by weight. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information, and belief at the date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal, and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Unless specified in the text. .WARRANTY Neither this data sheet nor any statement contained herein grants or extends any license, expressed or implied, in connection with patents issued or pending which may be the property of the manufacturer or others. The information in this data sheet has been assembled by the manufacturer based on its own studies and on the work of others. The manufacturer makes no warranties, expressed or implied, as to the accuracy, completeness, or adequacy of the information contained herein. The manufacturer shall not be liable (regardless of fault) to the Vendee, the Vendee's employees, or anyone for any direct, special or consequential damages arising out of or in connection with the accuracy, completeness, adequacy, or furnishing of such information. Disclaimer: Jack Frost Foam will create a-long lasting insulating foam when label directions and all technical information on mixing instructions are followed. American Ag. Foam LLC warrants Jack Frost Foam against defects in foaming ability and insulating ability (Jack Frost Foam’s ability to insulate is determined by the temperature reached and duration of the cold event compared to the thickness of the foam blanket applied. Note: The thicker the foam blanket applied the better the insulating abilities provided). Read all information before using Jack Frost Foam on any crop. Check physical compatibility first on any and all crops before beginning use of Jack Frost Foam. Recommendation: using a 1 quart jar add the proportionate amounts of Jack Frost Foam products (follow label directions of each product) to 1 (one) quart of water. After thoroughly mixing, let mixture stand for at least 30 minutes. Growers/user must apply liquid mix to a sampling of plants (wet entire exposed surface of plants) to test Jack Frost foam’s mix for phytotoxicity, leaf burn, or plant kill prior to large scale foam use. If for any reason user/applicator does not understand any or all of the directions and information contained in Jack Frost Foams labels, MSDS, Technical Data & Application sheet or provided verbally. American Ag. Foam LLC and its distributors recommends for the user/applicator to ask someone with a technical background and ability to explain any and/or all the information in a form more understandable. If an individual is not available to explain the information to the user/applicator, American Ag Foam LLC and its distributors recommend that the user/applicator return any unopened Jack Frost Foam products for a full refund (a restocking fee may apply). Due to the wide variation in climatic conditions, cultural practices and other factors, the User assumes full responsibility for any and all crop damage or other liability resulting from the incorrect use or misunderstanding of directions of Jack Frost Foam on a crop or plant. WARRANTY: American Ag. Foam L.L.C. warrants that the material contained herein conforms to the description on the label and is reasonably fit for the purposes referred to in the direction for use. Timing and method of application, weather, watering practices, nature of soil, conditions of the crop, improper application, incompatibility with other chemicals not specifically recommended, and other influencing factors in the use of this product are beyond the control of the seller. Buyer/User assumes all risks of use, storage, or handling of this material not in strict accordance with directions given herein. NO OTHER EXPRESS OR IMPLIED WARRANTY OF THE FITNESS OR MECHANTABILITY IS MADE.

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MATERIAL SAFETY DATA SHEET Manufacturer American Ag Foam LLC, 534 CR529A Lake Panasoffkee, Florida 33538 EMERGENCY INFORMATION (352) 793-1682 SECTION I - PRODUCT IDENTIFICATION DATE PREPARED: March 01, 2005 PRODUCT NAME: Jack Frost Formula A GENERAL/GENERIC ID: Foaming Anti-Desiccate Stabilizer DOT SHIPPING CLASS: 60 HAZARD CLASSIFICATION: Health-1, Fire-1, Reactivity-0 HAZARD CLASSIFICATION KEY: 0-least, 1-slight, 2-moderate, 3-high, 4-extreme SECTION II -HAZARDOUS INGREDIENTS COMPONENT Water ISOPROPYL ALCOHOL Residual Monomers

CAS NUMBER

PERCENT

7732-18-5

70-85%

67-63-0

3%

Not Required

27-12%

ACGIH TLV

EXPOSURE OSHA - PEL

300 ppm 250(STEL)

SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS BOILING POINT (F): 150 º F SPECIFIC GRAVITY: 1.04 +0.005 VAPOR PRESSURE (mm Hg): 17.0 mmHg @ 25º C (77º C)H2O VAPOR DENSITY (air=<1.0water) SOLUBILITY (in water): 100% EVAPORATION RATE: <1.00 water pH OF CONCENTRATE: 5.6-5.9 FREEZE POINT: 36º F APPEARANCE AND ODOR: Milky white liquid, slight alcohol odor. SECTION IV - FIRE & EXPLOSION HAZARD DATA FLASH POINT (F): Non Combustible FLAMMABLE LIMITS: Not Determined LEL: NOT DETERMINED VEL: NOT DETERMINED EXTINGUISHING MEDIA: DRY CHEMICAL, Water Spray (FOG), CO2; Foam; Sand/Earth SPECIAL FIRE FIGHTING PROCEDURES: SELF CONTAINED POSITIVE PRESSURE BREATHING APPARATUS and Protective Fire Fighting Clothing UNUSUAL FIRE & EXPLOSION HAZARDS: Apply cooling water to sides of containers that are exposed to flames.

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SECTION V - REACTIVITY DATA STABILITY: Product is stable. CONDITIONS TO AVOID: Do not keep container with lid open for long periods of time. MATERIALS TO AVOID: There are no known materials, which are incompatible with this product HAZARDOUS DECOMPOSITION OR BYPRODUCTS: Burning may produce carbon monoxide and/or carbon dioxide HAZARDOUS POLYMERIZATION: Product will not undergo polymerization. CONDITIONS TO AVOID: Heating of product. Burn may result. SECTION VI - HEALTH HAZARD DATA ROUTE(S) OF ENTRY: INHILATION: yes SKIN: yes INGESTION: UNLIKELY HEALTH HAZARDS (ACUTE & CHRONIC): ACUTE: Vapors and mist irritate nose and throat. Inhalation of high concentrations may cause headaches, vomiting and coma. Prolonged exposure may cause unconsciousness or death. Prolonged or repeated skin contact may cause irritation and dermatitis. Swallowing large quantities can cause headaches, nausea, vomiting, stomach cramps and diarrhea, and can cause unconsciousness. CHRONIC: Prolong or repeated exposure to high concentrations can produce severe or fatal central nervous system depression. CARCINOGENICITY: IARC MONOGRAPHS: NO OSHA REGULATED: NO NTP: NO SIGNS AND SYMPTOMS OF EXPOSURE: Eye and skin irritation, headache, nausea, and vomiting. Prolonged or repeated exposure may cause unconsciousness. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Persons with pre-existing skin disorders, eye problems, or impaired respiratory function may be more susceptible to the effects of this substance. ***EMERGENCY AND FIRST AID PROCEDURES*** INGESTION: Do not induce vomiting contact a physician or poison control center immediately. Offer small amounts of water or milk. Never give anything by mouth to an unconscious person. EYE CONTACT: Flush with water for 15 minutes. Get medical attention if irritation persists. SKIN CONTACT: Flush with water for 15 minutes. Get medical attention if irritation persists. INHALATION: Remove victim to fresh air. Administer oxygen if breathing is difficult. Apply artificial respiration if victim is not breathing. Get immediate medical attention. SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE SPILL STEPS: Contain spill by containment wall with absorbent material. Recover for reuse or absorb small spills on absorbent material and dispose of in approved waste disposal containers. WASTE DISPOSAL METHOD: Dispose of in accordance with local, state and federal regulations. When a decision is made to discard this material as supplied, it does not meet RCRA’s Characteristic definition of ignitability, corrosivity, or reactivity, and is not listed in 40 CFR 261.33 The Toxicity characteristic (TC), however, has not been evaluated by the Toxicity Characteristic Leaching procedure (TCLP). Coagulate the emulsion by the stepwise addition of ferric chloride and lime. Remove the clear supernatant and flush to a chemical sewer. For disposal, incinerate this material at a facility that complies with local, state, and federal regulations. STORAGE & HANDLING: Store in a cool, dry, fire-resistant area between 50-85ºF, product will freeze below 41º F. If product freezes, fallout will occur and product will become defective. Buyer assumes risk. Keep out of reach of children and animals. SECTION VIII - CONTROL MEASURES RESPIRATORY PROTECTION: If mist or dust conditions should be present use respirator approved by NIOSH. VENTILATION: Adequate ventilation is required to maintain a fresh airflow.

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LOCAL EXHAUST: Adequate EYES AND FACE: Goggles or face shield HANDS, ARMS AND BODY: Adequate clothing should be worn to prevent skin contact. Rubber/Plastic Gloves. WORK/HYGIENIC PRACTICES: Wash all clothing before wearing. Wash all exposed skin surfaces with soap and water after using this product. SPECIAL CLOTHING AND EQUIPMENT: Eye bath, safety shower and oxygen mask.

Section IX TRANSPORTATION INFORMATION D.O.T Not regulated for transport. Transportation Classification 60 IMO/IMDG Not regulated (Not dangerous for Transport) Transportation classifications may vary by container volume and may be influenced by regional or country variation in regulations.

Section X REGULATORY INFORMATION Workplace Classification: This product is considered non-hazardous under the OSHA Hazard Communication Standard (29CFR1910.1200) This product is not a ‘controlled product’ under the Canadian Workplace Hazardous Materials Information System (WHMIS). SARA TITLE III: Section 311/312 Categorizations (40CFR370): This product is not a hazardous chemical under 29 CFR 1910.1200, and therefore is not covered by Title III of SARA. SARA TITLE III: Section 313 Information (40 CFR372) This product does not contain a chemical, which is listed in Section 313 at or above de minimis concentrations. CERCLA Information (40CFR302.4) Releases of this material to air, land, or water are not reportable to the Nationals Response Center under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) or to state and local emergency planning committees under the Superfund Amendments and Reauthorization Act (SARA) Title III Sections 304. US. Toxic Substances Control Act (TSCA): All components of this product are in compliance with the inventory listing requirements of the U.S. Toxic Substance Control Act (TSCA) Chemical Substance Inventory. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information, and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal, and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Unless specified in the text. WARRANTY Neither this data sheet nor any statement contained herein grants or extends any license, expressed or implied, in connection with patents issued or pending which may be the property of the manufacturer or others. The information in this data sheet has been assembled by the manufacturer based on its own studies and on the work of others. The manufacturer makes no warranties, expressed or implied, as to the accuracy, completeness, or adequacy of the information contained herein. The manufacturer shall not be liable (regardless of fault) to the Vendee, the Vendee's employees, or anyone for any direct, special or consequential damages arising out of or in connection with the accuracy, completeness, adequacy, or furnishing of such information. Disclaimer: Jack Frost Foam will create a-long lasting insulating foam when label directions and all technical information on mixing instructions are followed. American Ag. Foam LLC warrants Jack Frost Foam against defects in foaming ability and insulating ability (Jack Frost Foam’s ability to insulate is determined by the temperature reached and duration of the cold event compared to the thickness of the foam blanket applied. Note: The thicker the foam blanket applied the better the insulating abilities provided). Read all information before using Jack Frost Foam on any crop. Check physical compatibility first on any and all crops before beginning use of Jack Frost Foam. Recommendation: using a 1 quart jar add the proportionate amounts of Jack Frost Foam products (follow label directions of each product) to 1 (one) quart of water. After thoroughly mixing, let mixture stand for at least 30 minutes. Growers/user must apply liquid mix to a sampling of plants (wet entire exposed surface of plants) to test Jack Frost foam’s mix for phytotoxicity, leaf burn, or plant kill prior to large scale foam use. If for any reason user/applicator does not understand any or all of the directions and information contained in Jack Frost Foams labels, MSDS, Technical Data & Application sheet or provided verbally. American Ag. Foam LLC and its distributors recommends for the user/applicator to ask someone with a technical background and ability to explain any and/or all the information in a form more understandable. If an individual is not available to explain the information to the user/applicator, American Ag Foam

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LLC and its distributors recommend that the user/applicator return any unopened Jack Frost Foam products for a full refund (a restocking fee may apply). Due to the wide variation in climatic conditions, cultural practices and other factors, the User assumes full responsibility for any and all crop damage or other liability resulting from the incorrect use or misunderstanding of directions of Jack Frost Foam on a crop or plant. WARRANTY: American Ag. Foam L.L.C. warrants that the material contained herein conforms to the description on the label and is reasonably fit for the purposes referred to in the direction for use. Timing and method of application, weather, watering practices, nature of soil, conditions of the crop, improper application, incompatibility with other chemicals not specifically recommended, and other influencing factors in the use of this product are beyond the control of the seller. Buyer/User assumes all risks of use, storage, or handling of this material not in strict accordance with directions given herein. NO OTHER EXPRESS OR IMPLIED WARRANTY OF THE FITNESS OR MECHANTABILITY IS MADE.

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