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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006
Revision Date 13.03.2018
Version 18.3
SECTION 1. Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
REACH Registration Number This product is a mixture. REACH Registration Number see section 3.
1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses
Reagent for analysis, Chemical production In compliance with the conditions described in the annex to this safety data sheet.
1.3 Details of the supplier of the safety data sheet Company
Merck KGaA * 64271 Darmstadt * Germany * Phone:+49 6151 72-0
Responsible Department
LS-QHC * e-mail: [email protected]
1.4 Emergency telephone
Please contact the regional company representation in your country.
number
SECTION 2. Hazards identification 2.1 Classification of the substance or mixture Classification (REGULATION (EC) No 1272/2008)
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 1 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Corrosive to metals, Category 1, H290 Skin corrosion, Category 1B, H314 Specific target organ toxicity - single exposure, Category 3, Respiratory system, H335 Acute aquatic toxicity, Category 1, H400 For the full text of the H-Statements mentioned in this Section, see Section 16. 2.2 Label elements Labelling (REGULATION (EC) No 1272/2008)
Hazard pictograms
Signal word Danger
Hazard statements H290 May be corrosive to metals. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. H400 Very toxic to aquatic life.
Precautionary statements Prevention P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. Response P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P310 IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 2 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Reduced labelling (≤125 ml)
Hazard pictograms
Signal word Danger
Hazard statements H314 Causes severe skin burns and eye damage.
Precautionary statements P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P310 IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
2.3 Other hazards None known.
SECTION 3. Composition/information on ingredients Chemical nature
Aqueous ammoniacal solution.
3.1 Substance Not applicable 3.2 Mixture
Hazardous components (REGULATION (EC) No 1272/2008)
Chemical name (Concentration) CAS-No.
Registration number
Classification
ammonia solution (>= 25 % - < 50 % ) Substance does not meet the criteria for PBT or vPvB according to Regulation (EC) No 1907/2006, Annex XIII.
1336-21-6
01-2119488876-14xxxx
Corrosive to metals, Category 1, H290
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 3 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Skin corrosion, Category 1B, H314 Specific target organ toxicity - single exposure, Category 3, H335 Acute aquatic toxicity, Category 1, H400 For the full text of the H-Statements mentioned in this Section, see Section 16.
SECTION 4. First aid measures 4.1 Description of first aid measures
General advice First aider needs to protect himself. After inhalation: fresh air. Call in physician. In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately. After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses. After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise. 4.2 Most important symptoms and effects, both acute and delayed Irritation and corrosion, bronchitis, Cough, Shortness of breath, gastric pain, Unconsciousness, Bloody vomiting, Nausea, collapse, shock, Convulsions, Lung oedema, death Risk of blindness! 4.3 Indication of any immediate medical attention and special treatment needed No information available.
SECTION 5. Firefighting measures 5.1 Extinguishing media
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 4 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Unsuitable extinguishing media For this substance/mixture no limitations of extinguishing agents are given. 5.2 Special hazards arising from the substance or mixture Not combustible. Ammonia solution itself is not flammable, but can form an ignitable ammonia/air-mixture by outgassing. Ambient fire may liberate hazardous vapours. Fire may cause evolution of: nitrogen oxides 5.3 Advice for firefighters
Special protective equipment for firefighters Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
Further information Cool closed containers exposed to fire with water spray. Suppress (knock down) gases/vapours/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.
SECTION 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Advice for non-emergency personnel: Do not breathe vapours, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: Protective equipment see section 8. 6.2 Environmental precautions Do not empty into drains. 6.3 Methods and materials for containment and cleaning up The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 5 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up with liquid-absorbent and neutralising material (e.g. Chemizorb® OH⁻, Merck Art. No. 101596). Dispose of properly. Clean up affected area. 6.4 Reference to other sections Indications about waste treatment see section 13.
SECTION 7. Handling and storage 7.1 Precautions for safe handling
Advice on safe handling Observe label precautions.
Hygiene measures Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. 7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers No metal or light-weight-metal containers.
Storage conditions Tightly closed. Recommended storage temperature see product label. 7.3 Specific end use(s) See exposure scenario in the Annex to this MSDS.
SECTION 8. Exposure controls/personal protection 8.1 Control parameters
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 6 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Derived No Effect Level (DNEL)
ammonia solution (1336-21-6) Worker DNEL, acute
Systemic effects
dermal
6,8 mg/kg Body weight
Worker DNEL,
Systemic effects
dermal
6,8 mg/kg Body weight
Worker DNEL, acute
Systemic effects
inhalation
47,6 mg/m³
Worker DNEL, acute
Local effects
inhalation
36 mg/m³
Worker DNEL,
Systemic effects
inhalation
47,6 mg/m³
Local effects
inhalation
14 mg/m³
Systemic effects
dermal
68 mg/kg Body weight
Systemic effects
dermal
68 mg/kg Body weight
Systemic effects
inhalation
23,8 mg/m³
Local effects
inhalation
7,2 mg/m³
Systemic effects
inhalation
23,8 mg/m³
Local effects
inhalation
2,8 mg/m³
Systemic effects
oral
6,8 mg/kg Body weight
Systemic effects
oral
6,8 mg/kg Body weight
longterm
longterm Worker DNEL, longterm Consumer DNEL, acute Consumer DNEL, longterm Consumer DNEL, acute Consumer DNEL, acute Consumer DNEL, longterm Consumer DNEL, longterm Consumer DNEL, acute Consumer DNEL, longterm
Predicted No Effect Concentration (PNEC)
ammonia solution (1336-21-6) PNEC Fresh water
0,0011 mg/l
PNEC Aquatic intermittent release
0,0068 mg/l
PNEC Marine water
0,00011 mg/l
8.2 Exposure controls The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 7 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Engineering measures Technical measures and appropriate working operations should be given priority over the use of personal protective equipment. See section 7.1. Individual protection measures Protective clothing needs to be selected specifically for the workplace, depending on concentrations and quantities of the hazardous substances handled. The chemical resistance of the protective equipment should be enquired at the respective supplier.
Eye/face protection Tightly fitting safety goggles
Hand protection full contact: Glove material:
butyl-rubber
Glove thickness:
0,7 mm
Break through time:
> 480 min
Glove material:
Nitrile rubber
Glove thickness:
0,40 mm
Break through time:
> 240 min
splash contact:
The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the related standard EN374, for example KCL 898 Butoject® (full contact), KCL 730 Camatril® -Velours (splash contact). The breakthrough times stated above were determined by KCL in laboratory tests acc. to EN374 with samples of the recommended glove types. This recommendation applies only to the product stated in the safety data sheet<(>,<)> supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 8 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Other protective equipment protective clothing
Respiratory protection required when vapours/aerosols are generated. Recommended Filter type: Filter K (acc. to DIN 3181) for NH₃ The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
Environmental exposure controls Do not empty into drains.
SECTION 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Form
liquid
Colour
colourless
Odour
stinging
Odour Threshold
0,02 - 70,7 ppm Ammonia
pH
at 20 °C strongly alkaline
Melting point
-57,5 °C
Boiling point/boiling range
37,7 °C at 1.013 hPa
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 9 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Flash point
No information available.
Evaporation rate
No information available.
Flammability (solid, gas)
No information available.
Lower explosion limit
15,4 %(V)
Upper explosion limit
33,6 %(V)
Vapour pressure
483 hPa at 20 °C
Relative vapour density
No information available.
Density
0,903 g/cm3 at 20 °C
Relative density
No information available.
Water solubility
at 20 °C soluble
Partition coefficient: n-
log Pow: -1,38
octanol/water
(experimental) (anhydrous substance) (Lit.) Bioaccumulation is not expected.
Auto-ignition temperature
No information available.
Decomposition temperature
No information available.
Viscosity, dynamic
No information available.
Explosive properties
Not classified as explosive.
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 10 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Oxidizing properties
none
9.2 Other data Minimum ignition energy
380 - 680 mJ
Corrosion
May be corrosive to metals.
SECTION 10. Stability and reactivity 10.1 Reactivity See section 10.3 10.2 Chemical stability Ammonia solution itself is not flammable, but can form an ignitable ammonia/air-mixture by outgassing. 10.3 Possibility of hazardous reactions A risk of explosion and/or of toxic gas formation exists with the following substances: Oxidizing agents, Mercury, Oxygen, silver compounds, nitrogen trichloride, hydrogen peroxide, silver, antimony hydride, halogens, Acids, Calcium, Chlorine, Chlorites, auric salts, perchlorates, sodium hypochlorite, mercury compounds, halogen oxides Heavy metals, Heavy metal salts, Acid chlorides, Acid anhydrides Risk of ignition or formation of inflammable gases or vapours with: Boranes, Boron, Oxides of phosphorus, Nitric acid, silicon compounds, chromium(VI) oxide, chromyl chloride Exothermic reaction with: Acetaldehyde, Acrolein, Barium, boron compounds, Bromine, halogen-halogen compounds, hydrogen bromide, silane, Hydrogen chloride gas, halogen compounds, dimethylsulfate, nitrogen oxides, Fluorine, Hydrogen fluoride, chlorates, carbon dioxide Ethylene oxide, polymerisable 10.4 Conditions to avoid The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 11 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Heating. 10.5 Incompatible materials Aluminium, Lead, Nickel, silver, Zinc, Copper, metal alloys, various metals 10.6 Hazardous decomposition products in the event of fire: See section 5.
SECTION 11. Toxicological information 11.1 Information on toxicological effects Mixture
Acute oral toxicity LDLO human: 43 mg/kg (29% solution) (RTECS) Symptoms: gastric pain, Bloody vomiting, If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the oesophagus and the stomach.
Acute inhalation toxicity Symptoms: mucosal irritations, Cough, Shortness of breath, bronchitis, Possible damages:, damage of respiratory tract
Acute dermal toxicity This information is not available.
Skin irritation Rabbit Result: Severe irritations (29% solution) (RTECS) Dermatitis Necrosis Mixture causes burns.
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 12 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Eye irritation Rabbit Result: Severe irritations (29% solution) (RTECS) Mixture causes serious eye damage. Risk of blindness!
Sensitisation This information is not available.
Germ cell mutagenicity This information is not available.
Carcinogenicity This information is not available.
Reproductive toxicity This information is not available.
Teratogenicity This information is not available.
Specific target organ toxicity - single exposure Mixture may cause respiratory irritation. Target Organs: Respiratory system
Specific target organ toxicity - repeated exposure This information is not available.
Aspiration hazard This information is not available. 11.2 Further information Systemic effects: Nausea, collapse, shock, Unconsciousness, Convulsions Lung oedema, Possible effects: death Other dangerous properties can not be excluded. The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 13 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Handle in accordance with good industrial hygiene and safety practice. Components
ammonia solution No information available.
SECTION 12. Ecological information Mixture 12.1 Toxicity No information available. 12.2 Persistence and degradability
Biodegradability Not readily biodegradable. 12.3 Bioaccumulative potential
Partition coefficient: n-octanol/water log Pow: -1,38 (experimental) (anhydrous substance) (Lit.) Bioaccumulation is not expected. 12.4 Mobility in soil No information available. 12.5 Results of PBT and vPvB assessment Substance(s) in the mixture do(es) not meet the criteria for PBT or vPvB according to Regulation (EC) No 1907/2006, Annex XIII, or a PBT/vPvB assessment was not conducted. 12.6 Other adverse effects
Additional ecological information Biological effects: Harmful effect due to pH shift. Forms toxic and corrosive mixtures with water even if diluted. Discharge into the environment must be avoided.
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 14 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Components
ammonia solution
Substance does not meet the criteria for PBT or vPvB according to Regulation (EC) No 1907/2006, Annex XIII.
SECTION 13. Disposal considerations
Waste treatment methods See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.
SECTION 14. Transport information Land transport (ADR/RID) 14.1 UN number
UN 2672
14.2 Proper shipping name
AMMONIA SOLUTION
14.3 Class
8
14.4 Packing group
III
14.5 Environmentally hazardous
yes
14.6 Special precautions for
yes
user Tunnel restriction code
E
Inland waterway transport (ADN) Not relevant Air transport (IATA) 14.1 UN number
UN 2672
14.2 Proper shipping name
AMMONIA SOLUTION
14.3 Class
8
14.4 Packing group
III
14.5 Environmentally hazardous
yes
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 15 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
14.6 Special precautions for
no
user Sea transport (IMDG) 14.1 UN number
UN 2672
14.2 Proper shipping name
AMMONIA SOLUTION
14.3 Class
8
14.4 Packing group
III
14.5 Environmentally hazardous
yes
14.6 Special precautions for
yes
user EmS
F-A S-B
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not relevant
SECTION 15. Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations Major Accident Hazard
SEVESO III
Legislation
ENVIRONMENTAL HAZARDS E1 Quantity 1: 100 t Quantity 2: 200 t
Occupational restrictions
Take note of Dir 94/33/EC on the protection of young people at work.
Regulation (EC) No 1005/2009 on substances that
not regulated
deplete the ozone layer
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 16 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Regulation (EC) No 850/2004 of the European
not regulated
Parliament and of the Council of 29 April 2004 on persistent organic pollutants and amending Directive 79/117/EEC Substances of very high concern (SVHC)
This product does not contain substances of very high concern according to Regulation (EC) No 1907/2006 (REACH), Article 57 above the respective regulatory concentration limit of ≥ 0.1 % (w/w).
National legislation Storage class
8B
15.2 Chemical safety assessment For this product a chemical safety assessment was not carried out.
SECTION 16. Other information
Full text of H-Statements referred to under sections 2 and 3. H290
May be corrosive to metals.
H314
Causes severe skin burns and eye damage.
H335
May cause respiratory irritation.
H400
Very toxic to aquatic life.
Training advice Provide adequate information, instruction and training for operators. Labelling
Hazard pictograms
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 17 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Signal word Danger
Hazard statements H290 May be corrosive to metals. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. H400 Very toxic to aquatic life.
Precautionary statements Prevention P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. Response P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P310 IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
Key or legend to abbreviations and acronyms used in the safety data sheet Used abbreviations and acronyms can be looked up at www.wikipedia.org. Regional representation This information is given on the authorised Safety Data Sheet for your country.
The information contained herein is based on the present state of our knowledge. It characterises the product with regard to the appropriate safety precautions. It does not represent a guarantee of any properties of the product.
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 18 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
EXPOSURE SCENARIO 1 (Industrial use)
1. Industrial use Reagent for analysis, Chemical production)
Sectors of end-use
SU 3
Industrial uses: Uses of substances as such or in preparations at industrial sites
SU9
Manufacture of fine chemicals
SU 10
Formulation [mixing] of preparations and/ or re-packaging (excluding alloys)
Chemical product category
PC19
Intermediate
PC21
Laboratory chemicals
Process categories
PROC1
Use in closed process, no likelihood of exposure
PROC2
Use in closed, continuous process with occasional controlled exposure
PROC3
Use in closed batch process (synthesis or formulation)
PROC4
Use in batch and other process (synthesis) where opportunity for exposure arises
PROC5
Mixing or blending in batch processes for formulation of preparations and articles (multistage and/ or significant contact)
PROC8a
Transfer of substance or preparation (charging/ discharging) from/ to vessels/ large containers at non-dedicated facilities
PROC8b
Transfer of substance or preparation (charging/ discharging) from/ to vessels/ large containers at dedicated facilities
PROC9
Transfer of substance or preparation into small containers (dedicated filling line, including weighing)
PROC10
Roller application or brushing
PROC15
Use as laboratory reagent
Environmental Release Categories
ERC2
Formulation of preparations
ERC4
Industrial use of processing aids in processes and products, not becoming part of articles
ERC6a
Industrial use resulting in manufacture of another substance (use of intermediates)
ERC6b
Industrial use of reactive processing aids
ERC7
Industrial use of substances in closed systems
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 19 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
2. Contributing scenarios: Operational conditions and risk management measures 2.1 Contributing scenario controlling environmental exposure for: ERC2 Amount used Daily amount per site (Msafe)
3.030 t
Environment factors not influenced by risk management Dilution Factor (River)
10
Dilution Factor (Coastal Areas)
10
Other given operational conditions affecting environmental exposure Number of emission days per year
330
Emission or Release Factor: Water
0%
Conditions and measures related to municipal sewage treatment plant Type of Sewage Treatment Plant
Municipal sewage treatment plant
Flow rate of sewage treatment
2.000 m3/d
plant effluent Sludge Treatment
Can be landfilled or incinerated, when in compliance with local regulations.
Conditions and measures related to external treatment of waste for disposal Waste treatment
All contaminated waste water must be processed in an industrial or municipal wastewater treatment plant that incorporates both primary and secondary treatments.
Disposal methods
Effectiveness (of a measure): 100 %
2.2 Contributing scenario controlling environmental exposure for: ERC4 Amount used Daily amount per site (Msafe)
757.575,7 kg
Environment factors not influenced by risk management Dilution Factor (River)
10
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 20 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Other given operational conditions affecting environmental exposure Number of emission days per year
330
Emission or Release Factor: Water
0%
Conditions and measures related to municipal sewage treatment plant Type of Sewage Treatment Plant
Municipal sewage treatment plant
Flow rate of sewage treatment
2.000 m3/d
plant effluent Sludge Treatment
Can be landfilled or incinerated, when in compliance with local regulations.
Conditions and measures related to external treatment of waste for disposal Waste treatment
All contaminated waste water must be processed in an industrial or municipal wastewater treatment plant that incorporates both primary and secondary treatments.
Disposal methods
Effectiveness (of a measure): 100 %
2.3 Contributing scenario controlling environmental exposure for: ERC6a Amount used Daily amount per site (Msafe)
2.424.242 kg
Environment factors not influenced by risk management Dilution Factor (River)
10
Dilution Factor (Coastal Areas)
10
Other given operational conditions affecting environmental exposure Number of emission days per year
330
Emission or Release Factor: Water
0%
Conditions and measures related to municipal sewage treatment plant Type of Sewage Treatment Plant
Municipal sewage treatment plant
Flow rate of sewage treatment
2.000 m3/d
plant effluent Sludge Treatment
Can be landfilled or incinerated, when in compliance with local
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 21 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur® regulations.
Conditions and measures related to external treatment of waste for disposal Waste treatment
All contaminated waste water must be processed in an industrial or municipal wastewater treatment plant that incorporates both primary and secondary treatments.
Disposal methods
Effectiveness (of a measure): 100 %
2.4 Contributing scenario controlling environmental exposure for: ERC6b Amount used Daily amount per site (Msafe)
75.757 kg
Environment factors not influenced by risk management Dilution Factor (River)
10
Other given operational conditions affecting environmental exposure Number of emission days per year
330
Emission or Release Factor: Water
0%
Conditions and measures related to municipal sewage treatment plant Type of Sewage Treatment Plant
Municipal sewage treatment plant
Flow rate of sewage treatment
2.000 m3/d
plant effluent Sludge Treatment
Can be landfilled or incinerated, when in compliance with local regulations.
Conditions and measures related to external treatment of waste for disposal Waste treatment
All contaminated waste water must be processed in an industrial or municipal wastewater treatment plant that incorporates both primary and secondary treatments.
Disposal methods
Effectiveness (of a measure): 100 %
2.5 Contributing scenario controlling environmental exposure for: ERC7
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 22 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Amount used Daily amount per site (Msafe)
75.757,5 kg
Environment factors not influenced by risk management Dilution Factor (River)
10
Other given operational conditions affecting environmental exposure Number of emission days per year
330
Emission or Release Factor: Water
0%
Conditions and measures related to municipal sewage treatment plant Type of Sewage Treatment Plant
Municipal sewage treatment plant
Flow rate of sewage treatment
2.000 m3/d
plant effluent Sludge Treatment
Can be landfilled or incinerated, when in compliance with local regulations.
Conditions and measures related to external treatment of waste for disposal Waste treatment
All contaminated waste water must be processed in an industrial or municipal wastewater treatment plant that incorporates both primary and secondary treatments.
Disposal methods
Effectiveness (of a measure): 100 %
2.6 Contributing scenario controlling worker exposure for: PROC1, PROC2 Product characteristics Concentration of the Substance in
Covers the percentage of the substance in the product up to
Mixture/Article
40 %.
Physical Form (at time of use)
High volatile liquid
Frequency and duration of use Frequency of use
8 hours/day
Frequency of use
5 days/week
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 23 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Other operational conditions affecting workers exposure Outdoor / Indoor
Indoor without local exhaust ventilation (LEV)
Conditions and measures related to personal protection, hygiene and health evaluation Wear chemically resistant gloves (tested to EN374) in combination with specific activity training. Tightly fitting safety goggles
2.7 Contributing scenario controlling worker exposure for: PROC3, PROC4, PROC5, PROC8a, PROC8b, PROC9, PROC10, PROC15 Product characteristics Concentration of the Substance in
Covers the percentage of the substance in the product up to
Mixture/Article
40 %.
Physical Form (at time of use)
High volatile liquid
Frequency and duration of use Frequency of use
8 hours/day
Frequency of use
5 days/week
Other operational conditions affecting workers exposure Outdoor / Indoor
Indoor with local exhaust ventilation (LEV)
Conditions and measures related to personal protection, hygiene and health evaluation Wear chemically resistant gloves (tested to EN374) in combination with specific activity training. Tightly fitting safety goggles
3. Exposure estimation and reference to its source
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 24 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Environment CS
Use descriptor
Msafe
Compartment
RCR
Exposure Assessment Method
2.1
ERC2
3030 t/day
Fresh water
1
EUSES
2.2
ERC4
757 t/day
Fresh water
1
EUSES
2.3
ERC6a
2424 t/day
Fresh water
1
EUSES
2.4
ERC6b
75 t/day
Marine water
1
EUSES
2.5
ERC7
75,75 t/day
Fresh water
1
EUSES
Use descriptor
Exposure duration, route, effect
RCR
Exposure Assessment Method
PROC1
longterm, inhalative, systemic
< 0,01
ECETOC TRA 3
longterm, dermal, systemic
< 0,01
ECETOC TRA 3
longterm, combined, systemic
< 0,01
longterm, inhalative, local
< 0,01
ECETOC TRA 3
longterm, inhalative, systemic
0,15
ECETOC TRA 3
longterm, dermal, systemic
< 0,01
ECETOC TRA 3
longterm, combined, systemic
0,16
Workers CS 2.6
2.6
PROC2
longterm, inhalative, local
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
0,5
ECETOC TRA 3
Page 25 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
2.7
PROC3
longterm, inhalative, systemic
0,03
ECETOC TRA 3
longterm, dermal, systemic
< 0,01
ECETOC TRA 3
longterm, combined, systemic
0,03
longterm, inhalative, local 2.7
2.7
2.7
2.7
2.7
PROC4
PROC5
PROC8a
PROC8b
PROC9
0,1
ECETOC TRA 3
longterm, inhalative, systemic
0,06
ECETOC TRA 3
longterm, dermal, systemic
0,04
ECETOC TRA 3
longterm, combined, systemic
0,1
longterm, inhalative, local
0,2
ECETOC TRA 3
longterm, inhalative, systemic
0,15
ECETOC TRA 3
longterm, dermal, systemic
0,08
ECETOC TRA 3
longterm, combined, systemic
0,23
longterm, inhalative, local
0,51
ECETOC TRA 3
longterm, inhalative, systemic
0,15
ECETOC TRA 3
longterm, dermal, systemic
0,08
ECETOC TRA 3
longterm, combined, systemic
0,23
longterm, inhalative, local
0,51
ECETOC TRA 3
longterm, inhalative, systemic
0,04
ECETOC TRA 3
longterm, dermal, systemic
0,08
ECETOC TRA 3
longterm, combined, systemic
0,13
longterm, inhalative, local
0,15
ECETOC TRA 3
longterm, inhalative, systemic
0,12
ECETOC TRA 3
longterm, dermal, systemic
0,04
ECETOC TRA 3
longterm, combined, systemic
0,16
longterm, inhalative, local 2.7
2.7
PROC10
PROC15
0,4
ECETOC TRA 3
longterm, inhalative, systemic
0,15
ECETOC TRA 3
longterm, dermal, systemic
0,16
ECETOC TRA 3
longterm, combined, systemic
0,31
longterm, inhalative, local
0,51
ECETOC TRA 3
longterm, inhalative, systemic
0,03
ECETOC TRA 3
longterm, dermal, systemic
< 0,01
ECETOC TRA 3
longterm, combined, systemic
0,03
longterm, inhalative, local
0,1
ECETOC TRA 3
The default parameters and -efficiencies of the applied exposure assessment model were used for the calculation (unless stated differently).
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 26 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 27 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
4. Guidance to Downstream User to evaluate whether he works inside the boundaries set by the Exposure Scenario
Please refer to the following documents: ECHA Guidance on information requirements and chemical safety assessment Chapter R.12: Use descriptor system; ECHA Guidance for downstream users; ECHA Guidance on information requirements and chemical safety assessment Part D: Exposure Scenario Building, Part E: Risk Characterisation and Part G: Extending the SDS; VCI/Cefic REACH Practical Guides on Exposure Assessment and Communications in the Supply Chain; CEFIC Guidance Specific Environmental Release Categories (SPERCs). For scaling of worker exposure assessments performed with ECETOC TRA, please consult the Merck tool ScIDeEx® at www.merckmillipore.com/scideex.
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 28 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
EXPOSURE SCENARIO 2 (Professional use)
1. Professional use Reagent for analysis, Chemical production)
Sectors of end-use
SU 22
Professional uses: Public domain (administration, education, entertainment, services, craftsmen)
Chemical product category
PC21
Laboratory chemicals
Process categories
PROC15
Use as laboratory reagent
Environmental Release Categories
ERC2
Formulation of preparations
ERC6a
Industrial use resulting in manufacture of another substance (use of intermediates)
ERC6b
Industrial use of reactive processing aids
2. Contributing scenarios: Operational conditions and risk management measures 2.1 Contributing scenario controlling environmental exposure for: ERC2 Amount used Daily amount per site (Msafe)
3.030 t
Environment factors not influenced by risk management Dilution Factor (River)
10
Dilution Factor (Coastal Areas)
10
Other given operational conditions affecting environmental exposure Number of emission days per year
330
Emission or Release Factor: Water
0%
Conditions and measures related to municipal sewage treatment plant Type of Sewage Treatment Plant
Municipal sewage treatment plant
Flow rate of sewage treatment
2.000 m3/d
plant effluent The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 29 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Sludge Treatment
Can be landfilled or incinerated, when in compliance with local regulations.
Conditions and measures related to external treatment of waste for disposal Waste treatment
All contaminated waste water must be processed in an industrial or municipal wastewater treatment plant that incorporates both primary and secondary treatments.
Disposal methods
Effectiveness (of a measure): 100 %
2.2 Contributing scenario controlling environmental exposure for: ERC6a Amount used Daily amount per site (Msafe)
2.424.242 kg
Environment factors not influenced by risk management Dilution Factor (River)
10
Dilution Factor (Coastal Areas)
10
Other given operational conditions affecting environmental exposure Number of emission days per year
330
Emission or Release Factor: Water
0%
Conditions and measures related to municipal sewage treatment plant Type of Sewage Treatment Plant
Municipal sewage treatment plant
Flow rate of sewage treatment
2.000 m3/d
plant effluent Sludge Treatment
Can be landfilled or incinerated, when in compliance with local regulations.
Conditions and measures related to external treatment of waste for disposal Waste treatment
All contaminated waste water must be processed in an industrial or municipal wastewater treatment plant that incorporates both primary and secondary treatments.
Disposal methods
Effectiveness (of a measure): 100 %
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 30 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
2.3 Contributing scenario controlling environmental exposure for: ERC6b Amount used Daily amount per site (Msafe)
75.757 kg
Environment factors not influenced by risk management Dilution Factor (River)
10
Other given operational conditions affecting environmental exposure Number of emission days per year
330
Emission or Release Factor: Water
0%
Conditions and measures related to municipal sewage treatment plant Type of Sewage Treatment Plant
Municipal sewage treatment plant
Flow rate of sewage treatment
2.000 m3/d
plant effluent Sludge Treatment
Can be landfilled or incinerated, when in compliance with local regulations.
Conditions and measures related to external treatment of waste for disposal Waste treatment
All contaminated waste water must be processed in an industrial or municipal wastewater treatment plant that incorporates both primary and secondary treatments.
Disposal methods
Effectiveness (of a measure): 100 %
2.4 Contributing scenario controlling worker exposure for: PROC15 Product characteristics Concentration of the Substance in
Covers the percentage of the substance in the product up to
Mixture/Article
40 %.
Physical Form (at time of use)
High volatile liquid
Frequency and duration of use Frequency of use
8 hours/day
Frequency of use
5 days/week
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 31 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Other operational conditions affecting workers exposure Outdoor / Indoor
Indoor with local exhaust ventilation (LEV)
Conditions and measures related to personal protection, hygiene and health evaluation Wear chemically resistant gloves (tested to EN374) in combination with specific activity training. Tightly fitting safety goggles
3. Exposure estimation and reference to its source Environment CS
Use descriptor
Msafe
Compartment
RCR
Exposure Assessment Method
2.1
ERC2
3030 t/day
Fresh water
1
EUSES
2.2
ERC6a
2424 t/day
Fresh water
1
EUSES
2.3
ERC6b
75 t/day
Marine water
1
EUSES
Use descriptor
Exposure duration, route, effect
RCR
Exposure Assessment Method
PROC15
longterm, inhalative, systemic
0,06
ECETOC TRA 3
longterm, dermal, systemic
< 0,01
ECETOC TRA 3
longterm, combined, systemic
0,06
Workers CS 2.4
longterm, inhalative, local
0,2
ECETOC TRA 3
The default parameters and -efficiencies of the applied exposure assessment model were used for the calculation (unless stated differently).
4. Guidance to Downstream User to evaluate whether he works inside the boundaries set by the Exposure Scenario The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 32 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Please refer to the following documents: ECHA Guidance on information requirements and chemical safety assessment Chapter R.12: Use descriptor system; ECHA Guidance for downstream users; ECHA Guidance on information requirements and chemical safety assessment Part D: Exposure Scenario Building, Part E: Risk Characterisation and Part G: Extending the SDS; VCI/Cefic REACH Practical Guides on Exposure Assessment and Communications in the Supply Chain; CEFIC Guidance Specific Environmental Release Categories (SPERCs). For scaling of worker exposure assessments performed with ECETOC TRA, please consult the Merck tool ScIDeEx® at www.merckmillipore.com/scideex.
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 33 of 33
Revision Date 13.03.2018
Version 18.3
SECTION 1. Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
REACH Registration Number This product is a mixture. REACH Registration Number see section 3.
1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses
Reagent for analysis, Chemical production In compliance with the conditions described in the annex to this safety data sheet.
1.3 Details of the supplier of the safety data sheet Company
Merck KGaA * 64271 Darmstadt * Germany * Phone:+49 6151 72-0
Responsible Department
LS-QHC * e-mail: [email protected]
1.4 Emergency telephone
Please contact the regional company representation in your country.
number
SECTION 2. Hazards identification 2.1 Classification of the substance or mixture Classification (REGULATION (EC) No 1272/2008)
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 1 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Corrosive to metals, Category 1, H290 Skin corrosion, Category 1B, H314 Specific target organ toxicity - single exposure, Category 3, Respiratory system, H335 Acute aquatic toxicity, Category 1, H400 For the full text of the H-Statements mentioned in this Section, see Section 16. 2.2 Label elements Labelling (REGULATION (EC) No 1272/2008)
Hazard pictograms
Signal word Danger
Hazard statements H290 May be corrosive to metals. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. H400 Very toxic to aquatic life.
Precautionary statements Prevention P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. Response P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P310 IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 2 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Reduced labelling (≤125 ml)
Hazard pictograms
Signal word Danger
Hazard statements H314 Causes severe skin burns and eye damage.
Precautionary statements P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P310 IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
2.3 Other hazards None known.
SECTION 3. Composition/information on ingredients Chemical nature
Aqueous ammoniacal solution.
3.1 Substance Not applicable 3.2 Mixture
Hazardous components (REGULATION (EC) No 1272/2008)
Chemical name (Concentration) CAS-No.
Registration number
Classification
ammonia solution (>= 25 % - < 50 % ) Substance does not meet the criteria for PBT or vPvB according to Regulation (EC) No 1907/2006, Annex XIII.
1336-21-6
01-2119488876-14xxxx
Corrosive to metals, Category 1, H290
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 3 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Skin corrosion, Category 1B, H314 Specific target organ toxicity - single exposure, Category 3, H335 Acute aquatic toxicity, Category 1, H400 For the full text of the H-Statements mentioned in this Section, see Section 16.
SECTION 4. First aid measures 4.1 Description of first aid measures
General advice First aider needs to protect himself. After inhalation: fresh air. Call in physician. In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately. After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses. After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise. 4.2 Most important symptoms and effects, both acute and delayed Irritation and corrosion, bronchitis, Cough, Shortness of breath, gastric pain, Unconsciousness, Bloody vomiting, Nausea, collapse, shock, Convulsions, Lung oedema, death Risk of blindness! 4.3 Indication of any immediate medical attention and special treatment needed No information available.
SECTION 5. Firefighting measures 5.1 Extinguishing media
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 4 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Unsuitable extinguishing media For this substance/mixture no limitations of extinguishing agents are given. 5.2 Special hazards arising from the substance or mixture Not combustible. Ammonia solution itself is not flammable, but can form an ignitable ammonia/air-mixture by outgassing. Ambient fire may liberate hazardous vapours. Fire may cause evolution of: nitrogen oxides 5.3 Advice for firefighters
Special protective equipment for firefighters Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
Further information Cool closed containers exposed to fire with water spray. Suppress (knock down) gases/vapours/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.
SECTION 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Advice for non-emergency personnel: Do not breathe vapours, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: Protective equipment see section 8. 6.2 Environmental precautions Do not empty into drains. 6.3 Methods and materials for containment and cleaning up The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 5 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up with liquid-absorbent and neutralising material (e.g. Chemizorb® OH⁻, Merck Art. No. 101596). Dispose of properly. Clean up affected area. 6.4 Reference to other sections Indications about waste treatment see section 13.
SECTION 7. Handling and storage 7.1 Precautions for safe handling
Advice on safe handling Observe label precautions.
Hygiene measures Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. 7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers No metal or light-weight-metal containers.
Storage conditions Tightly closed. Recommended storage temperature see product label. 7.3 Specific end use(s) See exposure scenario in the Annex to this MSDS.
SECTION 8. Exposure controls/personal protection 8.1 Control parameters
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 6 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Derived No Effect Level (DNEL)
ammonia solution (1336-21-6) Worker DNEL, acute
Systemic effects
dermal
6,8 mg/kg Body weight
Worker DNEL,
Systemic effects
dermal
6,8 mg/kg Body weight
Worker DNEL, acute
Systemic effects
inhalation
47,6 mg/m³
Worker DNEL, acute
Local effects
inhalation
36 mg/m³
Worker DNEL,
Systemic effects
inhalation
47,6 mg/m³
Local effects
inhalation
14 mg/m³
Systemic effects
dermal
68 mg/kg Body weight
Systemic effects
dermal
68 mg/kg Body weight
Systemic effects
inhalation
23,8 mg/m³
Local effects
inhalation
7,2 mg/m³
Systemic effects
inhalation
23,8 mg/m³
Local effects
inhalation
2,8 mg/m³
Systemic effects
oral
6,8 mg/kg Body weight
Systemic effects
oral
6,8 mg/kg Body weight
longterm
longterm Worker DNEL, longterm Consumer DNEL, acute Consumer DNEL, longterm Consumer DNEL, acute Consumer DNEL, acute Consumer DNEL, longterm Consumer DNEL, longterm Consumer DNEL, acute Consumer DNEL, longterm
Predicted No Effect Concentration (PNEC)
ammonia solution (1336-21-6) PNEC Fresh water
0,0011 mg/l
PNEC Aquatic intermittent release
0,0068 mg/l
PNEC Marine water
0,00011 mg/l
8.2 Exposure controls The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 7 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Engineering measures Technical measures and appropriate working operations should be given priority over the use of personal protective equipment. See section 7.1. Individual protection measures Protective clothing needs to be selected specifically for the workplace, depending on concentrations and quantities of the hazardous substances handled. The chemical resistance of the protective equipment should be enquired at the respective supplier.
Eye/face protection Tightly fitting safety goggles
Hand protection full contact: Glove material:
butyl-rubber
Glove thickness:
0,7 mm
Break through time:
> 480 min
Glove material:
Nitrile rubber
Glove thickness:
0,40 mm
Break through time:
> 240 min
splash contact:
The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the related standard EN374, for example KCL 898 Butoject® (full contact), KCL 730 Camatril® -Velours (splash contact). The breakthrough times stated above were determined by KCL in laboratory tests acc. to EN374 with samples of the recommended glove types. This recommendation applies only to the product stated in the safety data sheet<(>,<)> supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 8 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Other protective equipment protective clothing
Respiratory protection required when vapours/aerosols are generated. Recommended Filter type: Filter K (acc. to DIN 3181) for NH₃ The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
Environmental exposure controls Do not empty into drains.
SECTION 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Form
liquid
Colour
colourless
Odour
stinging
Odour Threshold
0,02 - 70,7 ppm Ammonia
pH
at 20 °C strongly alkaline
Melting point
-57,5 °C
Boiling point/boiling range
37,7 °C at 1.013 hPa
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 9 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Flash point
No information available.
Evaporation rate
No information available.
Flammability (solid, gas)
No information available.
Lower explosion limit
15,4 %(V)
Upper explosion limit
33,6 %(V)
Vapour pressure
483 hPa at 20 °C
Relative vapour density
No information available.
Density
0,903 g/cm3 at 20 °C
Relative density
No information available.
Water solubility
at 20 °C soluble
Partition coefficient: n-
log Pow: -1,38
octanol/water
(experimental) (anhydrous substance) (Lit.) Bioaccumulation is not expected.
Auto-ignition temperature
No information available.
Decomposition temperature
No information available.
Viscosity, dynamic
No information available.
Explosive properties
Not classified as explosive.
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 10 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Oxidizing properties
none
9.2 Other data Minimum ignition energy
380 - 680 mJ
Corrosion
May be corrosive to metals.
SECTION 10. Stability and reactivity 10.1 Reactivity See section 10.3 10.2 Chemical stability Ammonia solution itself is not flammable, but can form an ignitable ammonia/air-mixture by outgassing. 10.3 Possibility of hazardous reactions A risk of explosion and/or of toxic gas formation exists with the following substances: Oxidizing agents, Mercury, Oxygen, silver compounds, nitrogen trichloride, hydrogen peroxide, silver, antimony hydride, halogens, Acids, Calcium, Chlorine, Chlorites, auric salts, perchlorates, sodium hypochlorite, mercury compounds, halogen oxides Heavy metals, Heavy metal salts, Acid chlorides, Acid anhydrides Risk of ignition or formation of inflammable gases or vapours with: Boranes, Boron, Oxides of phosphorus, Nitric acid, silicon compounds, chromium(VI) oxide, chromyl chloride Exothermic reaction with: Acetaldehyde, Acrolein, Barium, boron compounds, Bromine, halogen-halogen compounds, hydrogen bromide, silane, Hydrogen chloride gas, halogen compounds, dimethylsulfate, nitrogen oxides, Fluorine, Hydrogen fluoride, chlorates, carbon dioxide Ethylene oxide, polymerisable 10.4 Conditions to avoid The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 11 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Heating. 10.5 Incompatible materials Aluminium, Lead, Nickel, silver, Zinc, Copper, metal alloys, various metals 10.6 Hazardous decomposition products in the event of fire: See section 5.
SECTION 11. Toxicological information 11.1 Information on toxicological effects Mixture
Acute oral toxicity LDLO human: 43 mg/kg (29% solution) (RTECS) Symptoms: gastric pain, Bloody vomiting, If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the oesophagus and the stomach.
Acute inhalation toxicity Symptoms: mucosal irritations, Cough, Shortness of breath, bronchitis, Possible damages:, damage of respiratory tract
Acute dermal toxicity This information is not available.
Skin irritation Rabbit Result: Severe irritations (29% solution) (RTECS) Dermatitis Necrosis Mixture causes burns.
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 12 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Eye irritation Rabbit Result: Severe irritations (29% solution) (RTECS) Mixture causes serious eye damage. Risk of blindness!
Sensitisation This information is not available.
Germ cell mutagenicity This information is not available.
Carcinogenicity This information is not available.
Reproductive toxicity This information is not available.
Teratogenicity This information is not available.
Specific target organ toxicity - single exposure Mixture may cause respiratory irritation. Target Organs: Respiratory system
Specific target organ toxicity - repeated exposure This information is not available.
Aspiration hazard This information is not available. 11.2 Further information Systemic effects: Nausea, collapse, shock, Unconsciousness, Convulsions Lung oedema, Possible effects: death Other dangerous properties can not be excluded. The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 13 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Handle in accordance with good industrial hygiene and safety practice. Components
ammonia solution No information available.
SECTION 12. Ecological information Mixture 12.1 Toxicity No information available. 12.2 Persistence and degradability
Biodegradability Not readily biodegradable. 12.3 Bioaccumulative potential
Partition coefficient: n-octanol/water log Pow: -1,38 (experimental) (anhydrous substance) (Lit.) Bioaccumulation is not expected. 12.4 Mobility in soil No information available. 12.5 Results of PBT and vPvB assessment Substance(s) in the mixture do(es) not meet the criteria for PBT or vPvB according to Regulation (EC) No 1907/2006, Annex XIII, or a PBT/vPvB assessment was not conducted. 12.6 Other adverse effects
Additional ecological information Biological effects: Harmful effect due to pH shift. Forms toxic and corrosive mixtures with water even if diluted. Discharge into the environment must be avoided.
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 14 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Components
ammonia solution
Substance does not meet the criteria for PBT or vPvB according to Regulation (EC) No 1907/2006, Annex XIII.
SECTION 13. Disposal considerations
Waste treatment methods See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.
SECTION 14. Transport information Land transport (ADR/RID) 14.1 UN number
UN 2672
14.2 Proper shipping name
AMMONIA SOLUTION
14.3 Class
8
14.4 Packing group
III
14.5 Environmentally hazardous
yes
14.6 Special precautions for
yes
user Tunnel restriction code
E
Inland waterway transport (ADN) Not relevant Air transport (IATA) 14.1 UN number
UN 2672
14.2 Proper shipping name
AMMONIA SOLUTION
14.3 Class
8
14.4 Packing group
III
14.5 Environmentally hazardous
yes
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 15 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
14.6 Special precautions for
no
user Sea transport (IMDG) 14.1 UN number
UN 2672
14.2 Proper shipping name
AMMONIA SOLUTION
14.3 Class
8
14.4 Packing group
III
14.5 Environmentally hazardous
yes
14.6 Special precautions for
yes
user EmS
F-A S-B
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not relevant
SECTION 15. Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations Major Accident Hazard
SEVESO III
Legislation
ENVIRONMENTAL HAZARDS E1 Quantity 1: 100 t Quantity 2: 200 t
Occupational restrictions
Take note of Dir 94/33/EC on the protection of young people at work.
Regulation (EC) No 1005/2009 on substances that
not regulated
deplete the ozone layer
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 16 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Regulation (EC) No 850/2004 of the European
not regulated
Parliament and of the Council of 29 April 2004 on persistent organic pollutants and amending Directive 79/117/EEC Substances of very high concern (SVHC)
This product does not contain substances of very high concern according to Regulation (EC) No 1907/2006 (REACH), Article 57 above the respective regulatory concentration limit of ≥ 0.1 % (w/w).
National legislation Storage class
8B
15.2 Chemical safety assessment For this product a chemical safety assessment was not carried out.
SECTION 16. Other information
Full text of H-Statements referred to under sections 2 and 3. H290
May be corrosive to metals.
H314
Causes severe skin burns and eye damage.
H335
May cause respiratory irritation.
H400
Very toxic to aquatic life.
Training advice Provide adequate information, instruction and training for operators. Labelling
Hazard pictograms
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 17 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Signal word Danger
Hazard statements H290 May be corrosive to metals. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. H400 Very toxic to aquatic life.
Precautionary statements Prevention P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. Response P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P310 IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
Key or legend to abbreviations and acronyms used in the safety data sheet Used abbreviations and acronyms can be looked up at www.wikipedia.org. Regional representation This information is given on the authorised Safety Data Sheet for your country.
The information contained herein is based on the present state of our knowledge. It characterises the product with regard to the appropriate safety precautions. It does not represent a guarantee of any properties of the product.
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 18 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
EXPOSURE SCENARIO 1 (Industrial use)
1. Industrial use Reagent for analysis, Chemical production)
Sectors of end-use
SU 3
Industrial uses: Uses of substances as such or in preparations at industrial sites
SU9
Manufacture of fine chemicals
SU 10
Formulation [mixing] of preparations and/ or re-packaging (excluding alloys)
Chemical product category
PC19
Intermediate
PC21
Laboratory chemicals
Process categories
PROC1
Use in closed process, no likelihood of exposure
PROC2
Use in closed, continuous process with occasional controlled exposure
PROC3
Use in closed batch process (synthesis or formulation)
PROC4
Use in batch and other process (synthesis) where opportunity for exposure arises
PROC5
Mixing or blending in batch processes for formulation of preparations and articles (multistage and/ or significant contact)
PROC8a
Transfer of substance or preparation (charging/ discharging) from/ to vessels/ large containers at non-dedicated facilities
PROC8b
Transfer of substance or preparation (charging/ discharging) from/ to vessels/ large containers at dedicated facilities
PROC9
Transfer of substance or preparation into small containers (dedicated filling line, including weighing)
PROC10
Roller application or brushing
PROC15
Use as laboratory reagent
Environmental Release Categories
ERC2
Formulation of preparations
ERC4
Industrial use of processing aids in processes and products, not becoming part of articles
ERC6a
Industrial use resulting in manufacture of another substance (use of intermediates)
ERC6b
Industrial use of reactive processing aids
ERC7
Industrial use of substances in closed systems
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 19 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
2. Contributing scenarios: Operational conditions and risk management measures 2.1 Contributing scenario controlling environmental exposure for: ERC2 Amount used Daily amount per site (Msafe)
3.030 t
Environment factors not influenced by risk management Dilution Factor (River)
10
Dilution Factor (Coastal Areas)
10
Other given operational conditions affecting environmental exposure Number of emission days per year
330
Emission or Release Factor: Water
0%
Conditions and measures related to municipal sewage treatment plant Type of Sewage Treatment Plant
Municipal sewage treatment plant
Flow rate of sewage treatment
2.000 m3/d
plant effluent Sludge Treatment
Can be landfilled or incinerated, when in compliance with local regulations.
Conditions and measures related to external treatment of waste for disposal Waste treatment
All contaminated waste water must be processed in an industrial or municipal wastewater treatment plant that incorporates both primary and secondary treatments.
Disposal methods
Effectiveness (of a measure): 100 %
2.2 Contributing scenario controlling environmental exposure for: ERC4 Amount used Daily amount per site (Msafe)
757.575,7 kg
Environment factors not influenced by risk management Dilution Factor (River)
10
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 20 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Other given operational conditions affecting environmental exposure Number of emission days per year
330
Emission or Release Factor: Water
0%
Conditions and measures related to municipal sewage treatment plant Type of Sewage Treatment Plant
Municipal sewage treatment plant
Flow rate of sewage treatment
2.000 m3/d
plant effluent Sludge Treatment
Can be landfilled or incinerated, when in compliance with local regulations.
Conditions and measures related to external treatment of waste for disposal Waste treatment
All contaminated waste water must be processed in an industrial or municipal wastewater treatment plant that incorporates both primary and secondary treatments.
Disposal methods
Effectiveness (of a measure): 100 %
2.3 Contributing scenario controlling environmental exposure for: ERC6a Amount used Daily amount per site (Msafe)
2.424.242 kg
Environment factors not influenced by risk management Dilution Factor (River)
10
Dilution Factor (Coastal Areas)
10
Other given operational conditions affecting environmental exposure Number of emission days per year
330
Emission or Release Factor: Water
0%
Conditions and measures related to municipal sewage treatment plant Type of Sewage Treatment Plant
Municipal sewage treatment plant
Flow rate of sewage treatment
2.000 m3/d
plant effluent Sludge Treatment
Can be landfilled or incinerated, when in compliance with local
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 21 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur® regulations.
Conditions and measures related to external treatment of waste for disposal Waste treatment
All contaminated waste water must be processed in an industrial or municipal wastewater treatment plant that incorporates both primary and secondary treatments.
Disposal methods
Effectiveness (of a measure): 100 %
2.4 Contributing scenario controlling environmental exposure for: ERC6b Amount used Daily amount per site (Msafe)
75.757 kg
Environment factors not influenced by risk management Dilution Factor (River)
10
Other given operational conditions affecting environmental exposure Number of emission days per year
330
Emission or Release Factor: Water
0%
Conditions and measures related to municipal sewage treatment plant Type of Sewage Treatment Plant
Municipal sewage treatment plant
Flow rate of sewage treatment
2.000 m3/d
plant effluent Sludge Treatment
Can be landfilled or incinerated, when in compliance with local regulations.
Conditions and measures related to external treatment of waste for disposal Waste treatment
All contaminated waste water must be processed in an industrial or municipal wastewater treatment plant that incorporates both primary and secondary treatments.
Disposal methods
Effectiveness (of a measure): 100 %
2.5 Contributing scenario controlling environmental exposure for: ERC7
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 22 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Amount used Daily amount per site (Msafe)
75.757,5 kg
Environment factors not influenced by risk management Dilution Factor (River)
10
Other given operational conditions affecting environmental exposure Number of emission days per year
330
Emission or Release Factor: Water
0%
Conditions and measures related to municipal sewage treatment plant Type of Sewage Treatment Plant
Municipal sewage treatment plant
Flow rate of sewage treatment
2.000 m3/d
plant effluent Sludge Treatment
Can be landfilled or incinerated, when in compliance with local regulations.
Conditions and measures related to external treatment of waste for disposal Waste treatment
All contaminated waste water must be processed in an industrial or municipal wastewater treatment plant that incorporates both primary and secondary treatments.
Disposal methods
Effectiveness (of a measure): 100 %
2.6 Contributing scenario controlling worker exposure for: PROC1, PROC2 Product characteristics Concentration of the Substance in
Covers the percentage of the substance in the product up to
Mixture/Article
40 %.
Physical Form (at time of use)
High volatile liquid
Frequency and duration of use Frequency of use
8 hours/day
Frequency of use
5 days/week
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 23 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Other operational conditions affecting workers exposure Outdoor / Indoor
Indoor without local exhaust ventilation (LEV)
Conditions and measures related to personal protection, hygiene and health evaluation Wear chemically resistant gloves (tested to EN374) in combination with specific activity training. Tightly fitting safety goggles
2.7 Contributing scenario controlling worker exposure for: PROC3, PROC4, PROC5, PROC8a, PROC8b, PROC9, PROC10, PROC15 Product characteristics Concentration of the Substance in
Covers the percentage of the substance in the product up to
Mixture/Article
40 %.
Physical Form (at time of use)
High volatile liquid
Frequency and duration of use Frequency of use
8 hours/day
Frequency of use
5 days/week
Other operational conditions affecting workers exposure Outdoor / Indoor
Indoor with local exhaust ventilation (LEV)
Conditions and measures related to personal protection, hygiene and health evaluation Wear chemically resistant gloves (tested to EN374) in combination with specific activity training. Tightly fitting safety goggles
3. Exposure estimation and reference to its source
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 24 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Environment CS
Use descriptor
Msafe
Compartment
RCR
Exposure Assessment Method
2.1
ERC2
3030 t/day
Fresh water
1
EUSES
2.2
ERC4
757 t/day
Fresh water
1
EUSES
2.3
ERC6a
2424 t/day
Fresh water
1
EUSES
2.4
ERC6b
75 t/day
Marine water
1
EUSES
2.5
ERC7
75,75 t/day
Fresh water
1
EUSES
Use descriptor
Exposure duration, route, effect
RCR
Exposure Assessment Method
PROC1
longterm, inhalative, systemic
< 0,01
ECETOC TRA 3
longterm, dermal, systemic
< 0,01
ECETOC TRA 3
longterm, combined, systemic
< 0,01
longterm, inhalative, local
< 0,01
ECETOC TRA 3
longterm, inhalative, systemic
0,15
ECETOC TRA 3
longterm, dermal, systemic
< 0,01
ECETOC TRA 3
longterm, combined, systemic
0,16
Workers CS 2.6
2.6
PROC2
longterm, inhalative, local
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
0,5
ECETOC TRA 3
Page 25 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
2.7
PROC3
longterm, inhalative, systemic
0,03
ECETOC TRA 3
longterm, dermal, systemic
< 0,01
ECETOC TRA 3
longterm, combined, systemic
0,03
longterm, inhalative, local 2.7
2.7
2.7
2.7
2.7
PROC4
PROC5
PROC8a
PROC8b
PROC9
0,1
ECETOC TRA 3
longterm, inhalative, systemic
0,06
ECETOC TRA 3
longterm, dermal, systemic
0,04
ECETOC TRA 3
longterm, combined, systemic
0,1
longterm, inhalative, local
0,2
ECETOC TRA 3
longterm, inhalative, systemic
0,15
ECETOC TRA 3
longterm, dermal, systemic
0,08
ECETOC TRA 3
longterm, combined, systemic
0,23
longterm, inhalative, local
0,51
ECETOC TRA 3
longterm, inhalative, systemic
0,15
ECETOC TRA 3
longterm, dermal, systemic
0,08
ECETOC TRA 3
longterm, combined, systemic
0,23
longterm, inhalative, local
0,51
ECETOC TRA 3
longterm, inhalative, systemic
0,04
ECETOC TRA 3
longterm, dermal, systemic
0,08
ECETOC TRA 3
longterm, combined, systemic
0,13
longterm, inhalative, local
0,15
ECETOC TRA 3
longterm, inhalative, systemic
0,12
ECETOC TRA 3
longterm, dermal, systemic
0,04
ECETOC TRA 3
longterm, combined, systemic
0,16
longterm, inhalative, local 2.7
2.7
PROC10
PROC15
0,4
ECETOC TRA 3
longterm, inhalative, systemic
0,15
ECETOC TRA 3
longterm, dermal, systemic
0,16
ECETOC TRA 3
longterm, combined, systemic
0,31
longterm, inhalative, local
0,51
ECETOC TRA 3
longterm, inhalative, systemic
0,03
ECETOC TRA 3
longterm, dermal, systemic
< 0,01
ECETOC TRA 3
longterm, combined, systemic
0,03
longterm, inhalative, local
0,1
ECETOC TRA 3
The default parameters and -efficiencies of the applied exposure assessment model were used for the calculation (unless stated differently).
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 26 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 27 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
4. Guidance to Downstream User to evaluate whether he works inside the boundaries set by the Exposure Scenario
Please refer to the following documents: ECHA Guidance on information requirements and chemical safety assessment Chapter R.12: Use descriptor system; ECHA Guidance for downstream users; ECHA Guidance on information requirements and chemical safety assessment Part D: Exposure Scenario Building, Part E: Risk Characterisation and Part G: Extending the SDS; VCI/Cefic REACH Practical Guides on Exposure Assessment and Communications in the Supply Chain; CEFIC Guidance Specific Environmental Release Categories (SPERCs). For scaling of worker exposure assessments performed with ECETOC TRA, please consult the Merck tool ScIDeEx® at www.merckmillipore.com/scideex.
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 28 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
EXPOSURE SCENARIO 2 (Professional use)
1. Professional use Reagent for analysis, Chemical production)
Sectors of end-use
SU 22
Professional uses: Public domain (administration, education, entertainment, services, craftsmen)
Chemical product category
PC21
Laboratory chemicals
Process categories
PROC15
Use as laboratory reagent
Environmental Release Categories
ERC2
Formulation of preparations
ERC6a
Industrial use resulting in manufacture of another substance (use of intermediates)
ERC6b
Industrial use of reactive processing aids
2. Contributing scenarios: Operational conditions and risk management measures 2.1 Contributing scenario controlling environmental exposure for: ERC2 Amount used Daily amount per site (Msafe)
3.030 t
Environment factors not influenced by risk management Dilution Factor (River)
10
Dilution Factor (Coastal Areas)
10
Other given operational conditions affecting environmental exposure Number of emission days per year
330
Emission or Release Factor: Water
0%
Conditions and measures related to municipal sewage treatment plant Type of Sewage Treatment Plant
Municipal sewage treatment plant
Flow rate of sewage treatment
2.000 m3/d
plant effluent The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 29 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Sludge Treatment
Can be landfilled or incinerated, when in compliance with local regulations.
Conditions and measures related to external treatment of waste for disposal Waste treatment
All contaminated waste water must be processed in an industrial or municipal wastewater treatment plant that incorporates both primary and secondary treatments.
Disposal methods
Effectiveness (of a measure): 100 %
2.2 Contributing scenario controlling environmental exposure for: ERC6a Amount used Daily amount per site (Msafe)
2.424.242 kg
Environment factors not influenced by risk management Dilution Factor (River)
10
Dilution Factor (Coastal Areas)
10
Other given operational conditions affecting environmental exposure Number of emission days per year
330
Emission or Release Factor: Water
0%
Conditions and measures related to municipal sewage treatment plant Type of Sewage Treatment Plant
Municipal sewage treatment plant
Flow rate of sewage treatment
2.000 m3/d
plant effluent Sludge Treatment
Can be landfilled or incinerated, when in compliance with local regulations.
Conditions and measures related to external treatment of waste for disposal Waste treatment
All contaminated waste water must be processed in an industrial or municipal wastewater treatment plant that incorporates both primary and secondary treatments.
Disposal methods
Effectiveness (of a measure): 100 %
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 30 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
2.3 Contributing scenario controlling environmental exposure for: ERC6b Amount used Daily amount per site (Msafe)
75.757 kg
Environment factors not influenced by risk management Dilution Factor (River)
10
Other given operational conditions affecting environmental exposure Number of emission days per year
330
Emission or Release Factor: Water
0%
Conditions and measures related to municipal sewage treatment plant Type of Sewage Treatment Plant
Municipal sewage treatment plant
Flow rate of sewage treatment
2.000 m3/d
plant effluent Sludge Treatment
Can be landfilled or incinerated, when in compliance with local regulations.
Conditions and measures related to external treatment of waste for disposal Waste treatment
All contaminated waste water must be processed in an industrial or municipal wastewater treatment plant that incorporates both primary and secondary treatments.
Disposal methods
Effectiveness (of a measure): 100 %
2.4 Contributing scenario controlling worker exposure for: PROC15 Product characteristics Concentration of the Substance in
Covers the percentage of the substance in the product up to
Mixture/Article
40 %.
Physical Form (at time of use)
High volatile liquid
Frequency and duration of use Frequency of use
8 hours/day
Frequency of use
5 days/week
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 31 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Other operational conditions affecting workers exposure Outdoor / Indoor
Indoor with local exhaust ventilation (LEV)
Conditions and measures related to personal protection, hygiene and health evaluation Wear chemically resistant gloves (tested to EN374) in combination with specific activity training. Tightly fitting safety goggles
3. Exposure estimation and reference to its source Environment CS
Use descriptor
Msafe
Compartment
RCR
Exposure Assessment Method
2.1
ERC2
3030 t/day
Fresh water
1
EUSES
2.2
ERC6a
2424 t/day
Fresh water
1
EUSES
2.3
ERC6b
75 t/day
Marine water
1
EUSES
Use descriptor
Exposure duration, route, effect
RCR
Exposure Assessment Method
PROC15
longterm, inhalative, systemic
0,06
ECETOC TRA 3
longterm, dermal, systemic
< 0,01
ECETOC TRA 3
longterm, combined, systemic
0,06
Workers CS 2.4
longterm, inhalative, local
0,2
ECETOC TRA 3
The default parameters and -efficiencies of the applied exposure assessment model were used for the calculation (unless stated differently).
4. Guidance to Downstream User to evaluate whether he works inside the boundaries set by the Exposure Scenario The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 32 of 33
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Catalogue No.
105428
Product name
Ammonia solution 25 % Suprapur®
Please refer to the following documents: ECHA Guidance on information requirements and chemical safety assessment Chapter R.12: Use descriptor system; ECHA Guidance for downstream users; ECHA Guidance on information requirements and chemical safety assessment Part D: Exposure Scenario Building, Part E: Risk Characterisation and Part G: Extending the SDS; VCI/Cefic REACH Practical Guides on Exposure Assessment and Communications in the Supply Chain; CEFIC Guidance Specific Environmental Release Categories (SPERCs). For scaling of worker exposure assessments performed with ECETOC TRA, please consult the Merck tool ScIDeEx® at www.merckmillipore.com/scideex.
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 33 of 33
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