Alkanes and Aromatic Hydrocarbons Organic Compounds Bonding in Hydrocarbons Naming Alkanes Properties of Alkanes Timberlake LecturePLUS
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“The most important hypothesis in all of
biology…is that everything that animals do, atoms do. In other words, there is nothing that living things do that cannot be understood from the point of view that they are made of atoms acting according to the laws of physics.” Richard Feynman (1918-1988)
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Organic Compounds Contain
carbon
Have
covalent bonds
Have
low melting points
Have
low boiling points
Burn
in air (oxygen)
Are
soluble in nonpolar solvents
Form
large molecules Timberlake LecturePLUS
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Alkanes
Contain
C and H only
Contain
single bonds C-C
Have Are
4 bonds to every carbon (C) atom
nonpolar
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Complete Structural Formulas Show the bonds between each of the atoms H H H: C: H ••
H
C
H
••
H
H CH4 , methane Timberlake LecturePLUS
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More Alkanes H
H
H
HCondensed Structural Formulas
C
C
H
HEthane
H CH3
CH3
H
H
H
C
C
C
H
H
H Propane
H
CH3 CH2 CH3
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IUPAC Names Name
# carbons
Structural Formula
Methane 1
CH4
Ethane
CH3CH3
2
Propane 3
CH3CH2CH3
Butane
CH3CH2CH2CH3
4
Pentane 5
CH3CH2CH2CH2CH3
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IUPAC NAMES Name # carbons
Structural Formula
Hexane 6
CH3CH2CH2CH2CH2CH3
Heptane 7
CH3CH2CH2CH2CH2CH2CH3
Octane
8
CH3CH2CH2CH2CH2CH2CH2CH3
Nonane 9
CH3 CH2 CH2CH2CH2CH2CH2CH2CH3
Decane 10 CH3CH2CH2CH2CH2CH2CH2CH2CH2CH3
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Learning Check Alk1 A. What is the condensed formula for H H H H H
C
C
C
C
H
H
H H
H
B. What is its molecular formula? C. What is its name?
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Solution Alk1 A.
CH3CH2CH2CH3
B.
C4H10
C.
butane
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Reactions of Alkanes Combustion
alkane + O2
CO2 + H2O + heat
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Combustion In the Cell Metabolic oxidation is combustion C6H12 O6 + 6O2
6CO2 + 6H2O + heat
glucose
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Learning Check Alk2 Complete the combustion reaction for C 3H 8 + O 2
+
Balance your equation
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Solution Alk2 Step 1 C3H8 + O2
CO2 + H2O
Step 2 C3H8 + O2
3 CO2 + 4 H2O
Step 3 C3H8 + 5 O2
3 CO2 + 4 H2O
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Learning Check Alk3 Complete and balance the reaction for the complete combustion of C7H16
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Solution Alk3 Step 1 C7H16 + O2
CO2 + H2O
Step 2 C7H16 + O2
7 CO2 + 8 H2O
Step 3 C7H16 + 11 O2
7 CO2 + 8 H2O
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