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MATERIAL SAFETY DATA SHEET 1. - Communicate your employees, agents and contractors or any other person who could use this material, the information contained in this sheet as well as any other information related to the risks and security measures. 2. - Provide a copy for each of its customers for this product and, 3. - Provide this same information for each of its customers for this product, besides asking its customers to notify its employees, customers and other users the product with this information. SECURITY PRODUCTS DATA SHEET OF PRODUCTS Revision date: July 2009 _____________________________________________________________________ Section 1: Identification of the chemical substance and the provider _____________________________________________________________________ Name of the chemical substance : UFC – 85 Internal Code of the chemical substance: ---Provider : OXIQUIM S.A. Address : Cañaveral 901, Quilicura, Santiago, Chile. Phone: 02-4788200 Fax: 02-4788201 Emergency telephones in Chile : Quilicura: 02-4788111 Coronel: 041-2866523 Emergency cell 1: 97995292 Emergency cell 2: 97995285 CITUC (Chemical emergencies): 2-2473600 e-mail : [email protected] _____________________________________________________________________ Section 2: Information about the substance or mixture _____________________________________________________________________ Chemical name (IUPAC) : Mixture Chemical formula : H-CHO (product in higher concentration) Synomym : Formaldehyde, Methyle oxide, Methanal, Oxometane, Metaldehyde, Formol. No. CAS : 50-00-0 (formalin) No. NU : 3082
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Section 3: Identification of risks _____________________________________________________________________ Mark of label : MISCELLANEOUS DANGEROUS Classification of risks of the chemical product: Health: 2 Flammability: 1
Reactivity: 0
a) Risks for health of people : The probable lethal dose for human beings is 0.5-5 g/kg. The following table gives the probable reaction of the body to several concentrations: >1 ppm odor perceptible for most of the people. 2-3 ppm slight itching of the eyes. 4-5 ppm higher disturbance, slight tears. 10 ppm Strong tears, it can only be stand for a few minutes. 10-20 ppm difficult to breath, cough, serious irritation of nose and throat. 50-100 ppm acute irritation of respiratory tract, very probable serious injury. Effects of an acute overexposure (once): When absorbed by the organism, formaldehyde produces depression in the central nervous system and a similar reaction to an alcoholic intoxication: vertigo, depression and comma. It also cause a reduction of corporal temperature. Inhalation : The irritant effect will be noted in the respiratory tract, producing cough, bronchial spasm and lung irritation. Contact with skin : Produces strong primary irritation, in some cases it gets to chemical burnings. In some people with higher susceptibility it can produce dermatitis. Contact with eyes : The solutions that have got straight to the eyes have produced from lower pain up to such injuries like the permanent opacity of the cornea or the loss of sight. Swallowing : Produces strong pain, vomiting and diarrhea. Effect of chronic overexposure (long term): Dermatitis has produced by sensitivity. The effects in women include menstrual disorders and secondary sterilization. Formaldehyde is classified as carcinogenic for laboratory animals. Medical conditions that will worsen with the exposure to the product: Any lung illness will worsen due to the irritation of the mucous produced by the product. Besides, in people with sensitivity to the action of formaldehyde a delayed asthmatic reaction is produced with short expositions to concentrations of up to 3 ppm. b) Risks for environment: It is toxic for aquatic in concentrations of 25 ppm. c) Special risks of the product: Higher danger of formaldehyde it is its irritating character that produces unbearable disturbances to the people exposed.
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_____________________________________________________________________ Section 4: First Aid Measures _____________________________________________________________________ In case of accidental contact with the product, proceed according to: Inhalation: Take the person to open air. Help her to breathe if necessary. Ask for medical attention. Contact with skin : Wash the affected zone with abundant running water. Ask for medical help. Contact with the eyes : Wash immediately with abundant running water for at least 15 minutes. Contact a doctor urgently. Swallowing : If the person is conscious, DO NOT INDUCE VOMITING. Give to drink 250 cc (one cup) of water, milk or water with coal activated. If the person is unconscious, don´t do anything, except keep him hot. In both cases: ask for urgent medical attention. Notes for treating doctor: Treat according to the present symptoms. Consider making a gastric wash, with the habitual cautions to avoid the inhalation of the gastric content. Doctors who work in emergency attention must be ready as in case of UFC swallowing it can be produced 85: convulsions, hypotension, metabolic acidosis and high levels of methanol in the blood. _____________________________________________________________________ Section 5: Measures for fighting against fire _____________________________________________________________________ Extinction Agents : In small fires, use dry chemical powder, carbon dioxide water (fog) or foam. In bigger fires, use water fog or foam. Special Procedures to fight against fire: Cool the containers exposed to fire. Take them out of the area if possible without danger. Get out of the area if you notice an increasing leak of gases. Equipment of personal protection to attack fire: Use an autonomous respiratory equipment, helmet, neoprene gloves and PVC clothes.
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_____________________________________________________________________ Section 6: Measures to control spills or leaks ___________________________________________________________________ Emergency measures to be taken if there is a Material spilling: Keep the product away from ignition sources (open flames). Do not allow that it gets into the sewage. Make dikes to control the spilling. Pick up all the remaining material you can without danger to the people. Over the rest spread an absorbing material so as to pick it up and make it available. Personal protecting equipment to attack the emergency: Use autonomous respiratory equipment. Protect with PVC suit, gloves and neoprene boots. Cautions to be taken to avoid damages to environment: Prevent that products get in rivers and water sources. Try to recover the spread material only if it is possible without danger for people. Cleaning Methods: The contaminated material must be incinerated in an authorized installation. Method of waste disposal: Dispose of remain in an authorized incinerator or in special places inside the rubbish dump. _____________________________________________________________________ Section 7: Handling and Storing ________________________________________________________________ Technical Recommendations: It is recommended to store in stainless steel tanks. If the quantity in use does not justify the tanks, the containers must be in a ventilated place, separated from other products. Cautions to be taken: When handling the product, try to keep the wind always at the back. Use respiratory protection. Recommendations about secure handling, specifics: Take from the container only the exact quantity needed, so as to expose the minimum time to vapors. Storing conditions: Keep away from oxidants and reducers, with which UFC - 85 can get a violent reaction. Recommended and non adequate packing: Only metal containers must be used. Due to the possible generation of static electricity no drums or plastic recipients must be used.
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_____________________________________________________________________ Section 8: Control of exposure/environmental protection ____________________________________________________________________ Measures to reduce the possibility of exposure: Use only the needed quantity for the process. Always use the necessary protection. Try that the UFC-85 handling places there is always good ventilation, either natural of forced. Adjusted permissible limits (APL), absolute (APA) and temporary (APT): Permissible absolute limit: 0, 3 ppm (0, 37 mg/m3). Respiratory protection : Respiratory trunk with filter for organic vapors. Protecting gloves : Neoprene gloves, long fist. View protection : Chemical protecting goggles. Other protecting equipment: Neoprene apron to protect the body. Ventilation : There must be good natural ventilation, at least in the places of handling of UFC - 85. ____________________________________________________________________ Section 9 : Physical and Chemical Properties _____________________________________________________________________ Physical State : Liquid similar to water. Appearance and odour : Colorless, bitter smell, irritating. Concentration : 60 % (Formalin) pH : Slightly basic Specific temperatures and/or temperature intervals: Datum not available. Point of flammability : 60 ºC Limits of flammability : Datum not available. Autoignition Temperature: 430 ºC Dangers of Fire or Explosion: When heating UFC - 85 over its point of flammability, there is a potential for an explosion. It reacts with nitrogen oxides. Near 82 ºC the reaction can become explosive. It reacts violently with per chlorate acid, aniline, performic acid, nitro methane, magnesium carbonate and hydrogen peroxide. The product polymerizes with active organic materials such as phenol. Polimerizes violently in presence of nitrides. It produces exothermic reactions with: amines, azo compounds, ditiocarbamates, and alkaline metals and alkaline-earthy. Vapor pressure to 20ºC : Information not available. Density of vapor :>1 Density to 20ºC :>1 Solubility in water : Soluble in any proportion.
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_____________________________________________________________________ Section 10: Stability and Reactivity __________________________________________________________________ Stability: Stable. Conditions to be avoided: Avoid to heat containers to avoid generation of vapors. Incompatibility (materials to be avoided): Incompatible with amines, azo compounds, ditiocarbamates, alkaline metals and alkaline-earthy, nitrides, nitro compounds, sulphides, none saturated aliphatic, organic peroxides, oxidizing agents and reducers. Dangerous products of decomposition: Not pertinent. Dangerous products of combustion: Monoxide toxic gases are formed and carbon oxides. Dangerous polymerization: Will not occur. _____________________________________________________________________ Section 11: Toxicological information ___________________________________________________________________ Toxicity in short term : The most important effect is due to the irritation of skin and mucous it produces. In more sensitive people there can be allergy. Toxicity in long term: There can be effects like chronic dermatitis in people with higher sensitivity. Local or systemic effects : Irritation and tears. Allergic Sensitivity : It can cause sensitivity in people presenting allergy to UFC - 85. _____________________________________________________________________ Section 12: Ecological Information _____________________________________________________________________ Instability : In middle term UFC - 85 is degraded by absorption in different organic processes. Persistency/Degradability : Degradable. Bio-accumulation : Will not be produced Effects in the environment : Toxic for aquatic life. Dangerous in high concentrations in the air. If goes over 100 ppm it can be lethal for human life (Formalin). _____________________________________________________________________ Section 13: Considerations over final disposition _____________________________________________________________________ Methods recommended and approved by Chilean standard to have available the substances, remaining, wastes: Have available the product in an authorized incinerator or in special places inside the rubbish dumps. Methods recommended and approved by Chilean standard to eliminate containers / contaminated packages: Incinerate containers in an installation specially designed for that effect.
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_____________________________________________________________________ Section 14: Information about transport ________________________________________________________________ Terrestrial by road or railway : CLASS 9, NU 3082 Marine way : CLASS 9, NU 3082 Air way : CLASS 9, NU 3082 Fluvial way / lake : CLASS 9, NU 3082 Distinctive applicable NCh 2190: MISCELLANEOUS DANGEROUS No. NU : 3082 _____________________________________________________________________ Section 15: Current Standards _____________________________________________________________________ Applicable International Standards : IMO / NU : Class 9 /3082 Applicable National Standards : N Ch 382; N Ch 2190; Decree 298; D.S.148 Mark of label : MISCELLANEOUS DANGEROUS _____________________________________________________________________ Section 16: Other information _____________________________________________________________________ No information. _____________________________________________________________________ Consigned data in this data sheet were obtained from reliable sources. Nevertheless, they are given without expressed or implicit guarantee respect to its accuracy or correction. The opinions expressed in this application form belong to trained professionals of OXIQUIM S.A. The information given in it is currently known about the topic. Considering that the use of this information and of the products is out of control of OXIQUIM S.A., the company assumes no responsibility for this concept. Determining the conditions of a safe use of the product is user´s obligation. JYG/
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Section 3: Identification of risks _____________________________________________________________________ Mark of label : MISCELLANEOUS DANGEROUS Classification of risks of the chemical product: Health: 2 Flammability: 1
Reactivity: 0
a) Risks for health of people : The probable lethal dose for human beings is 0.5-5 g/kg. The following table gives the probable reaction of the body to several concentrations: >1 ppm odor perceptible for most of the people. 2-3 ppm slight itching of the eyes. 4-5 ppm higher disturbance, slight tears. 10 ppm Strong tears, it can only be stand for a few minutes. 10-20 ppm difficult to breath, cough, serious irritation of nose and throat. 50-100 ppm acute irritation of respiratory tract, very probable serious injury. Effects of an acute overexposure (once): When absorbed by the organism, formaldehyde produces depression in the central nervous system and a similar reaction to an alcoholic intoxication: vertigo, depression and comma. It also cause a reduction of corporal temperature. Inhalation : The irritant effect will be noted in the respiratory tract, producing cough, bronchial spasm and lung irritation. Contact with skin : Produces strong primary irritation, in some cases it gets to chemical burnings. In some people with higher susceptibility it can produce dermatitis. Contact with eyes : The solutions that have got straight to the eyes have produced from lower pain up to such injuries like the permanent opacity of the cornea or the loss of sight. Swallowing : Produces strong pain, vomiting and diarrhea. Effect of chronic overexposure (long term): Dermatitis has produced by sensitivity. The effects in women include menstrual disorders and secondary sterilization. Formaldehyde is classified as carcinogenic for laboratory animals. Medical conditions that will worsen with the exposure to the product: Any lung illness will worsen due to the irritation of the mucous produced by the product. Besides, in people with sensitivity to the action of formaldehyde a delayed asthmatic reaction is produced with short expositions to concentrations of up to 3 ppm. b) Risks for environment: It is toxic for aquatic in concentrations of 25 ppm. c) Special risks of the product: Higher danger of formaldehyde it is its irritating character that produces unbearable disturbances to the people exposed.
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_____________________________________________________________________ Section 4: First Aid Measures _____________________________________________________________________ In case of accidental contact with the product, proceed according to: Inhalation: Take the person to open air. Help her to breathe if necessary. Ask for medical attention. Contact with skin : Wash the affected zone with abundant running water. Ask for medical help. Contact with the eyes : Wash immediately with abundant running water for at least 15 minutes. Contact a doctor urgently. Swallowing : If the person is conscious, DO NOT INDUCE VOMITING. Give to drink 250 cc (one cup) of water, milk or water with coal activated. If the person is unconscious, don´t do anything, except keep him hot. In both cases: ask for urgent medical attention. Notes for treating doctor: Treat according to the present symptoms. Consider making a gastric wash, with the habitual cautions to avoid the inhalation of the gastric content. Doctors who work in emergency attention must be ready as in case of UFC swallowing it can be produced 85: convulsions, hypotension, metabolic acidosis and high levels of methanol in the blood. _____________________________________________________________________ Section 5: Measures for fighting against fire _____________________________________________________________________ Extinction Agents : In small fires, use dry chemical powder, carbon dioxide water (fog) or foam. In bigger fires, use water fog or foam. Special Procedures to fight against fire: Cool the containers exposed to fire. Take them out of the area if possible without danger. Get out of the area if you notice an increasing leak of gases. Equipment of personal protection to attack fire: Use an autonomous respiratory equipment, helmet, neoprene gloves and PVC clothes.
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_____________________________________________________________________ Section 6: Measures to control spills or leaks ___________________________________________________________________ Emergency measures to be taken if there is a Material spilling: Keep the product away from ignition sources (open flames). Do not allow that it gets into the sewage. Make dikes to control the spilling. Pick up all the remaining material you can without danger to the people. Over the rest spread an absorbing material so as to pick it up and make it available. Personal protecting equipment to attack the emergency: Use autonomous respiratory equipment. Protect with PVC suit, gloves and neoprene boots. Cautions to be taken to avoid damages to environment: Prevent that products get in rivers and water sources. Try to recover the spread material only if it is possible without danger for people. Cleaning Methods: The contaminated material must be incinerated in an authorized installation. Method of waste disposal: Dispose of remain in an authorized incinerator or in special places inside the rubbish dump. _____________________________________________________________________ Section 7: Handling and Storing ________________________________________________________________ Technical Recommendations: It is recommended to store in stainless steel tanks. If the quantity in use does not justify the tanks, the containers must be in a ventilated place, separated from other products. Cautions to be taken: When handling the product, try to keep the wind always at the back. Use respiratory protection. Recommendations about secure handling, specifics: Take from the container only the exact quantity needed, so as to expose the minimum time to vapors. Storing conditions: Keep away from oxidants and reducers, with which UFC - 85 can get a violent reaction. Recommended and non adequate packing: Only metal containers must be used. Due to the possible generation of static electricity no drums or plastic recipients must be used.
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_____________________________________________________________________ Section 8: Control of exposure/environmental protection ____________________________________________________________________ Measures to reduce the possibility of exposure: Use only the needed quantity for the process. Always use the necessary protection. Try that the UFC-85 handling places there is always good ventilation, either natural of forced. Adjusted permissible limits (APL), absolute (APA) and temporary (APT): Permissible absolute limit: 0, 3 ppm (0, 37 mg/m3). Respiratory protection : Respiratory trunk with filter for organic vapors. Protecting gloves : Neoprene gloves, long fist. View protection : Chemical protecting goggles. Other protecting equipment: Neoprene apron to protect the body. Ventilation : There must be good natural ventilation, at least in the places of handling of UFC - 85. ____________________________________________________________________ Section 9 : Physical and Chemical Properties _____________________________________________________________________ Physical State : Liquid similar to water. Appearance and odour : Colorless, bitter smell, irritating. Concentration : 60 % (Formalin) pH : Slightly basic Specific temperatures and/or temperature intervals: Datum not available. Point of flammability : 60 ºC Limits of flammability : Datum not available. Autoignition Temperature: 430 ºC Dangers of Fire or Explosion: When heating UFC - 85 over its point of flammability, there is a potential for an explosion. It reacts with nitrogen oxides. Near 82 ºC the reaction can become explosive. It reacts violently with per chlorate acid, aniline, performic acid, nitro methane, magnesium carbonate and hydrogen peroxide. The product polymerizes with active organic materials such as phenol. Polimerizes violently in presence of nitrides. It produces exothermic reactions with: amines, azo compounds, ditiocarbamates, and alkaline metals and alkaline-earthy. Vapor pressure to 20ºC : Information not available. Density of vapor :>1 Density to 20ºC :>1 Solubility in water : Soluble in any proportion.
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_____________________________________________________________________ Section 10: Stability and Reactivity __________________________________________________________________ Stability: Stable. Conditions to be avoided: Avoid to heat containers to avoid generation of vapors. Incompatibility (materials to be avoided): Incompatible with amines, azo compounds, ditiocarbamates, alkaline metals and alkaline-earthy, nitrides, nitro compounds, sulphides, none saturated aliphatic, organic peroxides, oxidizing agents and reducers. Dangerous products of decomposition: Not pertinent. Dangerous products of combustion: Monoxide toxic gases are formed and carbon oxides. Dangerous polymerization: Will not occur. _____________________________________________________________________ Section 11: Toxicological information ___________________________________________________________________ Toxicity in short term : The most important effect is due to the irritation of skin and mucous it produces. In more sensitive people there can be allergy. Toxicity in long term: There can be effects like chronic dermatitis in people with higher sensitivity. Local or systemic effects : Irritation and tears. Allergic Sensitivity : It can cause sensitivity in people presenting allergy to UFC - 85. _____________________________________________________________________ Section 12: Ecological Information _____________________________________________________________________ Instability : In middle term UFC - 85 is degraded by absorption in different organic processes. Persistency/Degradability : Degradable. Bio-accumulation : Will not be produced Effects in the environment : Toxic for aquatic life. Dangerous in high concentrations in the air. If goes over 100 ppm it can be lethal for human life (Formalin). _____________________________________________________________________ Section 13: Considerations over final disposition _____________________________________________________________________ Methods recommended and approved by Chilean standard to have available the substances, remaining, wastes: Have available the product in an authorized incinerator or in special places inside the rubbish dumps. Methods recommended and approved by Chilean standard to eliminate containers / contaminated packages: Incinerate containers in an installation specially designed for that effect.
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_____________________________________________________________________ Section 14: Information about transport ________________________________________________________________ Terrestrial by road or railway : CLASS 9, NU 3082 Marine way : CLASS 9, NU 3082 Air way : CLASS 9, NU 3082 Fluvial way / lake : CLASS 9, NU 3082 Distinctive applicable NCh 2190: MISCELLANEOUS DANGEROUS No. NU : 3082 _____________________________________________________________________ Section 15: Current Standards _____________________________________________________________________ Applicable International Standards : IMO / NU : Class 9 /3082 Applicable National Standards : N Ch 382; N Ch 2190; Decree 298; D.S.148 Mark of label : MISCELLANEOUS DANGEROUS _____________________________________________________________________ Section 16: Other information _____________________________________________________________________ No information. _____________________________________________________________________ Consigned data in this data sheet were obtained from reliable sources. Nevertheless, they are given without expressed or implicit guarantee respect to its accuracy or correction. The opinions expressed in this application form belong to trained professionals of OXIQUIM S.A. The information given in it is currently known about the topic. Considering that the use of this information and of the products is out of control of OXIQUIM S.A., the company assumes no responsibility for this concept. Determining the conditions of a safe use of the product is user´s obligation. JYG/
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