Termo Equilibrio De Fases.xlsx

T(acetona)=56C T(benceno)=80C Nº benceno (ml) acetona (ml) IR para la mezcla(promedio) C (acetona) IR 1 0 2 1.3571 1 2 0.2 1.8 1.3724 0.9 3 0.4 1.4 1.3858 Y vs X acetona 0.8 4 0.6 1.6 1.3991 0.7 1.2 5 0.8 1.8 1.4133 0.6 1 6 1 1 1.4283 0.5 7 1.2 0.8 1.4426 0.4 0.8 8 1.4 0.6 1.456 0.3 9 1.6 0.4 1.4718 0.2 0.6 10 1.8 0.2 1.4854 0.1 11 2 0 1.499 0 0.4

1.3571 1.3724 1.3858 1.3991 1.4133 1.4283 1.4426 1.456 1.4718 1.4854 1.499

C(benceno) 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0 0 1.3571 0 0.2 0.1 1.3724 0.2 1.3858 0.3 1.3991 IR vs C(acetona) 0.4 1.4133 1.55 0.5 1.4283 0.6 1.4426 1.5 f(x) = 0.1420545455x + 1.4992818182 0.7 R² = 0.9998376653 1.456 1.45 0.8 1.4718 0.9 1.4854 1.4 1 1.499

0.4

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1.2

IR vs C (benceno) 1.55 1.5 1.45

Axis Title

Axis Title

0.2

1.35 1.3

f(x) = 0.1420545455x + 1.3572272727 R² = 0.9998376653

1.4 1.35 1.3

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IR vapor

liquido

1.4955 1.4915 1.4751 1.4731 1.4643 1.4164 1.3989 1.3866 1.3665

Xacetona 0 0.0267 0.0549 0.1703 0.1844 0.2463 0.5834 0.7062 0.7928 0.9342 1

1.4612 1.44 1.4304 1.4153 1.4049 1.3948 1.3864 1.3764 1.3668

C (benceno)

.3572272727

4

0.6

Axis Title

0.8

1

1.2

Xbenceno

0.9733 0.9451 0.8297 0.8156 0.7537 0.4166 0.2938 0.2072 0.0658

Yacetona 0 0.2681 0.4173 0.4849 0.5911 0.6643 0.7351 0.7942 0.8645 0.9321 1

Ybenceno

0.7319 0.5827 0.5151 0.4089 0.3357 0.2649 0.2058 0.1355 0.0679

Xacetona 0 0 0.0267 0.0549 0.1703 0.1844 0.2463 0.5834 0.7062 0.7928 0.9342 1

Yacetona 0 0 0.2681 0.4173 0.4849 0.5911 0.6643 0.7351 0.7942 0.8645 0.9321 1

T(C) ecuacion de Antoine log(P)=A-(B/(T+C)) BENCENO A=3,98523 B=1184,240 C=217,572 T eb=80 C T eb a 495 mmhg= 66,708 ACETONA A=4,21840 B=1197,010 C=228,060 T eb=56 C Teb a 495mmhg=44,05

Pt=0,6599 bar

P benceno(baP acetona(bar) X benceno 44.05 0.28754072 0.6597918486 -0.0002905 45.05 0.29918187 0.6847215293 0.06438126 46.05 0.3112006 0.7104008928 0.12650515 47.05 0.3236058 0.7368460724 0.18620178 48.05 0.33640648 0.7640733801 0.24358532 49.05 0.34961175 0.7920993057 0.2987639 50.05 0.36323085 0.8209405153 0.35183989 51.05 0.37727313 0.8506138496 0.40291029 52.05 0.39174802 0.881136323 0.45206705 53.05 0.40666511 0.9125251218 0.4993973 1.2 54.05 0.42203407 0.9447976029 0.5449837 1 55.05 0.43786469 0.9779712921 0.58890466 56.05 0.45416686 1.0120638826 0.63123456 0.8 57.05 0.47095058 1.0470932333 0.67204404 0.6 58.05 0.48822597 1.0830773673 0.71140014 59.05 0.50600324 1.12003447 0.74936656 0.4 60.05 0.52429271 1.1579828876 0.7860038 61.05 0.54310481 1.196941125 0.82136938 0.2 62.05 0.56245008 1.2369278442 0.85551796 0 -0.2 0 63.05 0.58233914 1.2779618624 0.88850154 64.05 0.60278272 1.3200621502 0.92036956 -0.2 65.05 0.62379167 1.3632478296 0.95116907 66.05 0.64537691 1.4075381718 0.98094486 66.7 0.65972158 1.4369284622 0.99977044 67 0.66642674 1.4506548763 1.0083225 0.03485381 0.0932690101 Xacetona -0.2 45.2 0.30096039 0.6885252494 0 46.2 0.31303652 0.7143184524 0.0267 47.2 0.32550047 0.7408799069 0.0549 48.2 0.33836125 0.7682259518 0.1703 1.6 50 0.36253993 0.8194788325 0.1844 1.4 50.2 0.36530999 0.8253380536 0.2463 51.9 0.38954883 0.8765031457 0.5834 1.2 54.2 0.424379 0.9497157738 0.7062 1 56.5 0.46165934 1.0277100921 0.7928 0.8 60.4 0.53081696 1.1715024517 0.9342 65.6 0.63559153 1.3874695776 1 0.6

1.6 1.4 1.2 1

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0.8 0.6 0.4 0.2 0

0

0.4 0.2

Xacetona 0 0.68852525 0.0267 0.71431845 0.0549 0.74087991

y acetona 0 0.68852525 0.2681 0.71431845 0.4173 0.74087991

Xacetona 0 0 0 0.0267 0.0549

0.2

0.1703 0.1844 0.2463 0.5834 0.7062 0.7928 0.9342 1

0.76822595 0.81947883 0.82533805 0.87650315 0.94971577 1.02771009 1.17150245 1.38746958

0.4849 0.5911 0.6643 0.7351 0.7942 0.8645 0.9321 1

0.76822595 0.81947883 0.82533805 0.87650315 0.94971577 1.02771009 1.17150245 1.38746958

0.1703 0.1844 0.2463 0.5834 0.7062 0.7928 0.9342 1

Y benceno X acetona Y acetona -0.0001266 1.00029053 1.0001266 0.02918883 0.93561874 0.97081117 0.05965825 0.87349485 0.94034175 0.09131077 0.81379822 0.90868923 0.12417591 0.75641468 0.87582409 0.15828363 0.7012361 0.84171637 0.19366435 0.64816011 0.80633565 0.23034888 0.59708971 0.76965112 Y vs X acetona 0.2683685 0.54793295 0.7316315 1.2 0.3077549 0.5006027 0.6922451 0.34854022 0.4550163 0.65145978 1 0.39075702 0.41109534 0.60924298 0.8 0.43443827 0.36876544 0.56556173 0.47961741 0.32795596 P0.52038259 vs X Y acetona 0.6 0.52632826 0.28859986 0.47367174 1.6 0.5746051 0.25063344 0.4253949 0.4 1.4 0.62448259 0.2139962 0.37551741 0.2 0.67599585 0.17863062 0.32400415 1.2 0.7291804 0.14448204 0.2708196 0 1 -0.2 0 0.2 0.40.21592784 0.6 0.8 0.78407216 0.11149846 -0.2 0.8 0.84070748 0.07963044 0.15929252 0.89912311 0.04883093 0.10087689 0.6 0.95935621 0.01905514 0.04064379 0.4 0.99950013 0.00022956 0.00049987 0.2 1.01829531 -0.0083225 -0.0182953 X benceno y acetona Y benceno 0 -0.2 0 0.2 0.4 1 0 1 0.6 0.9733 0.2681 0.7319 0.9451 0.4173 0.5827 0.8297 0.4849 Chart 0.5151 Title 1.6 0.8156 0.5911 0.4089 1.4 0.7537 0.6643 0.3357 0.4166 0.7351 0.2649 1.2 0.2938 0.7942 0.2058 1 0.2072 0.8645 0.1355 0.8 0.0658 0.9321 0.0679 0 1 0 0.6

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T 80 70 60 50 40 30 20

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P vs X Y acetona

1.6 1.4 1.2

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X acetona P acetona(barY acetona 1.00029053 0.65979185 1.0001266 0.93561874 0.68472153 0.97081117 0.87349485 0.71040089 0.94034175 0.81379822 0.73684607 0.90868923 0.75641468 0.76407338 0.87582409 0.7012361 0.79209931 0.84171637 0.64816011 0.82094052 0.80633565 0.59708971 0.85061385 0.76965112 0.54793295 0.88113632 0.7316315 0.5006027 0.91252512 0.6922451 0.4550163 0.9447976 0.65145978 0.41109534 0.97797129 0.60924298 0.36876544 1.01206388 0.56556173 0.32795596 1.04709323 0.52038259 0.28859986 1.08307737 0.47367174 0.25063344 1.12003447 0.4253949 0.2139962 1.15798289 0.37551741 0.17863062 1.19694112 0.32400415 0.14448204 1.23692784 0.2708196 1.2 0.11149846 1.27796186 0.21592784 0.07963044 1.32006215 0.15929252 70 0.04883093 1.36324783 0.10087689 -0.2 0.01905514 1.40753817 0.04064379 60 0.00022956 1.43692846 0.00049987 50 -0.0083225 1.45065488 -0.0182953

0

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45.2 46.2 47.2

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0 0.6 0.2681 0.4173 0.4849

45.2 0.8 46.2 47.2 48.2

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48.2 50 50.2 51.9 54.2 56.5 60.4 65.6

0.5911 0.6643 0.7351 0.7942 0.8645 0.9321 1

50 50.2 51.9 54.2 56.5 60.4 65.6

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P acetona(bar) 0.65979185 0.68472153 0.71040089 0.73684607 0.76407338 0.79209931 0.82094052 0.85061385 0.88113632 0.91252512 0.9447976 80 0.97797129 70 1.01206388 1.04709323 60 1.08307737 50 1.12003447 40 1.15798289 30 1.19694112 1.23692784 20 1.27796186 10 1.32006215 0 1.36324783 0 0.2 1.40753817 1.43692846 1.45065488

X acetona T(C) Y acetona T(C) 1.00029053 44.05 1.0001266 0.93561874 45.05 0.97081117 0.87349485 46.05 0.94034175 0.81379822 47.05 0.90868923 0.75641468 48.05 0.87582409 0.7012361 49.05 0.84171637 0.64816011 50.05 0.80633565 0.59708971 51.05 0.76965112 0.54793295 52.05 0.7316315 0.5006027 53.05 0.6922451 T vs X Y acetona 0.4550163 54.05 0.65145978 0.41109534 55.05 0.60924298 0.36876544 56.05 0.56556173 0.32795596 57.05 0.52038259 0.28859986 58.05 0.47367174 0.25063344 59.05 0.4253949 0.2139962 60.05 0.37551741 0.17863062 61.05 0.32400415 0.14448204 62.05 0.2708196 0.11149846 63.05 0.21592784 T vs X Y acetona 0.07963044 64.05 0.15929252 0.04883093 65.05 0.10087689 0.4 0.6 0.8 1 1.2 0.01905514 66.05 0.04064379 0.00022956 66.7 0.00049987 -0.0083225 67 -0.0182953

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X Y acetona

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44.05 45.05 46.05 47.05 48.05 49.05 50.05 51.05 52.05 53.05 54.05 55.05 56.05 57.05 58.05 59.05 60.05 61.05 62.05 63.05 64.05 65.05 66.05 66.7 67

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% acetona % bencenno T (C) 100 0 90 10 80 20 70 30 60 40 50 50 40 60 30 70 20 80 10 90 0 100

Xbenceno 0.9733 0.9451 0.8297 0.8156 0.7537

Ybenceno 0.7319 0.5827 0.5151 0.4089 0.3357

T(C) 45.2 46.2 47.2 48.2 50 50.2 51.9 54.2 56.5 60.4 65.6

T (C) 50.2 51.9 54.2 56.5 60.4

0.9733 0.9451 0.8297 0.8156 0.7537

50.2 51.9 54.2 56.5 60.4

Chart Title 70 60

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50 70 40 60 30 50 20 40 10 30 0 0.7 20

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