Pengarah Ortho Meta Para

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REAKSI-REAKSI PADA BENZENA. 1.

Reaksi Klorinasi : + Cl2

Fe

Benzena

2.

Reaksi Friedel Craft : + CH3Cl AlCl3 Benzena

Cl + HCl Kloro Benzena CH3 + HCl Toluena

Lanjutan Reaksi Benzena 3. Reaksi Nitrasi : + HNO3

H SO 2 4

Benzena 4. Reaksi Sulfonasi : + H2SO4 HCl Benzena

-NO2 + H2O Nitro Benzena

-SO3H + Benzena Sulfonat

Gugus Pengarah Ortho, Meta dan Para . 

Pengarah Ortho, Para 1. -CH3; -CH2-CH3; (-R)



2. -F ; -Cl ; -Br ; -I 3. -OH ; -OCH3 ; -OR

2. - C=O ; - C=O R OH 3. - C=O 4. -C≡N OR

4. -NH2 ; -NH-R ; -NR2 Contoh : 1. -Cl + Cl2

FeCl

3

Disimpulkan Gugus –Cl disebut pengarah Ortho-para.

Pengarah Meta 1. –NO2 ; -SO3H

-Cl + ClCl

(75%)

+

-Cl (23%)

-Cl (2%)

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