Numerik Baru.xlsx
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A + B --> C C + B --> D A --> E
rR1 = k1 CA CB rR2 = k2 CB CC rR3 = k3 CA
k1 k2 CA0 V v
2,1 * 10 ^-2 1,5 * 10^-2 0.5 1000 0.1
k3 CB0
0.00012 1
rA = -r1 - r3 rA = -(k1 CA CB) - (k3 CA) rA = - (k1 CA0( 1-XA)) (CB0 (1 - XB)) - (k3 CA - k3 CA XA) rA = -( 2,1* 10 ^-2 * 0,5 ) (1-XA)) ( 1(1 - XB )) - (0,00012 * 0,5 - 0,00012 * 0,5 * XA) rA = -( 0,0105)( 1 - XA) (1 ( 1-XB)) - ( 0,00006 - 0,00006 XA) rA = - (0,0105)(1 - XA) ((1 - XB) - ( 0,00006 - 0,00006 XA) rA = -(0,0105) ( 1 - XB - XA + XAXB) - ( 0,00006 - 0,00006 XA) V = (FA0 * XA) / -rA XA =( V( -rA))/ FA0 XA = (1000(0,0105) ( 1 - XB - XA + XAXB) - ( 0,00006 - 0,00006 XA)) / (0,5 * 0,1) XA = 1000( 0,0105 - 0, 0105 XB - 0,0105 XA + 0,0105 XAXB) - (0,00006 - 0,00006 XA) / 0,05 XA = 10,5 - 10,5 XB - 10,5 XA + 10,5 XAXB - 0,00006 + 0,00006 XA / 0,05 XA * 0,05 = 10,5 - 10,5 XB - 10,5 XA + 10,5 XAXB - 0,00006 + 0,00006 XA 0,05 XA + 10,5 XA - 10,5 XAXB - 0,00006 XA = 10,5 -10,5 XB - 0,00006 10,55 XA - 10,5 XAXB = 10,5 - 10,5XB XA = (10,5 - 10,5 XB)/ (10,55-10,5XB)
k2 CA0 V v
1,5 * 10^-2 0.5 1000 0.1
k1 CB0
2,1 * 10 ^-2 1
rB = -r1-r2 rB = -(k1CACB)-(k2C3Cc) rB = -(k1(CA0(1-XA)) (CB0(1-XB)) - (-k2(CB0(1-XB)Cc))) rB = -(2.1*10^-2*(0.5(1-XA))(1(1-XB))-(-1.5*10^-2(1(1-XB)Cc))) rB = -(0.0105(1-XA))(1-XB))+ (0.015(1-XB)Cc) rB = -(0.0105(1-XB-XA+XAXB)+0.015Cc-XBCc V = (FB0 *XB)/-rB XB = (V(-rB))/CB0*v XB = 1000*(0.0105(1-XB-XA+XAXB)+0.015Cc-XBCc)/1*0.1 xB = (10.5 - 10.5XB -10.5XA + 10.5XAXB + 0.015Cc - XBCc)/0.1 0.1 XB = 10.5 - 10.5XB - 10.5XA + 10.5 XAXB + 0.015 Cc - XBCc 10.5 XA - 10.5XAXB = 10.5 - 10.5 XB + 0.015 Cc - XBCc - 0.1 XB xA = (10.5 -10.5 XB + 0.015 Cc - XBCc - 0.1 XB)/10.5 - 10.5 XB
k3
0.00012
k2 CA0 V v
1,5 * 10^-2 0.5 1000 0.1
k1 CB0
2,1 * 10 ^-2 1
rC = r1-r2 rC = (k1CACB)-(k2C3Cc) rC = (k1(CA0(1-XA)) (CB0(1-XB)) - (-k2(CB0(1-XB)Cc))) rC = (2.1*10^-2*(0.5(1-XA))(1(1-XB))-(-1.5*10^-2(1(1-XB)Cc))) rC = (0.0105(1-XA))(1-XB))+ (0.015(1-XB)Cc) rC = (0.0105(1-XB-XA+XAXB)+0.015Cc-XBCc V = (FC0 *XC)/-Rc XC = (V(-rC))/CB0*v XC = 1000*(0.0105(1-XB-XA+XAXB)+0.015Cc-XBCc)/1*0.1 xB = (10.5 - 10.5XB -10.5XA + 10.5XAXB + 0.015Cc - XBCc)/0.1 0.1 XB = 10.5 - 10.5XB - 10.5XA + 10.5 XAXB + 0.015 Cc - XBCc 10.5 XA - 10.5XAXB = 10.5 - 10.5 XB + 0.015 Cc - XBCc - 0.1 XB xA = (10.5 -10.5 XB + 0.015 Cc - XBCc - 0.1 XB)/10.5 - 10.5 XB
k3
0.00012
rR1 = k1 CA CB rR2 = k2 CB CC rR3 = k3 CA
k1 k2 CA0 V v
2,1 * 10 ^-2 1,5 * 10^-2 0.5 1000 0.1
k3 CB0
0.00012 1
rA = -r1 - r3 rA = -(k1 CA CB) - (k3 CA) rA = - (k1 CA0( 1-XA)) (CB0 (1 - XB)) - (k3 CA - k3 CA XA) rA = -( 2,1* 10 ^-2 * 0,5 ) (1-XA)) ( 1(1 - XB )) - (0,00012 * 0,5 - 0,00012 * 0,5 * XA) rA = -( 0,0105)( 1 - XA) (1 ( 1-XB)) - ( 0,00006 - 0,00006 XA) rA = - (0,0105)(1 - XA) ((1 - XB) - ( 0,00006 - 0,00006 XA) rA = -(0,0105) ( 1 - XB - XA + XAXB) - ( 0,00006 - 0,00006 XA) V = (FA0 * XA) / -rA XA =( V( -rA))/ FA0 XA = (1000(0,0105) ( 1 - XB - XA + XAXB) - ( 0,00006 - 0,00006 XA)) / (0,5 * 0,1) XA = 1000( 0,0105 - 0, 0105 XB - 0,0105 XA + 0,0105 XAXB) - (0,00006 - 0,00006 XA) / 0,05 XA = 10,5 - 10,5 XB - 10,5 XA + 10,5 XAXB - 0,00006 + 0,00006 XA / 0,05 XA * 0,05 = 10,5 - 10,5 XB - 10,5 XA + 10,5 XAXB - 0,00006 + 0,00006 XA 0,05 XA + 10,5 XA - 10,5 XAXB - 0,00006 XA = 10,5 -10,5 XB - 0,00006 10,55 XA - 10,5 XAXB = 10,5 - 10,5XB XA = (10,5 - 10,5 XB)/ (10,55-10,5XB)
k2 CA0 V v
1,5 * 10^-2 0.5 1000 0.1
k1 CB0
2,1 * 10 ^-2 1
rB = -r1-r2 rB = -(k1CACB)-(k2C3Cc) rB = -(k1(CA0(1-XA)) (CB0(1-XB)) - (-k2(CB0(1-XB)Cc))) rB = -(2.1*10^-2*(0.5(1-XA))(1(1-XB))-(-1.5*10^-2(1(1-XB)Cc))) rB = -(0.0105(1-XA))(1-XB))+ (0.015(1-XB)Cc) rB = -(0.0105(1-XB-XA+XAXB)+0.015Cc-XBCc V = (FB0 *XB)/-rB XB = (V(-rB))/CB0*v XB = 1000*(0.0105(1-XB-XA+XAXB)+0.015Cc-XBCc)/1*0.1 xB = (10.5 - 10.5XB -10.5XA + 10.5XAXB + 0.015Cc - XBCc)/0.1 0.1 XB = 10.5 - 10.5XB - 10.5XA + 10.5 XAXB + 0.015 Cc - XBCc 10.5 XA - 10.5XAXB = 10.5 - 10.5 XB + 0.015 Cc - XBCc - 0.1 XB xA = (10.5 -10.5 XB + 0.015 Cc - XBCc - 0.1 XB)/10.5 - 10.5 XB
k3
0.00012
k2 CA0 V v
1,5 * 10^-2 0.5 1000 0.1
k1 CB0
2,1 * 10 ^-2 1
rC = r1-r2 rC = (k1CACB)-(k2C3Cc) rC = (k1(CA0(1-XA)) (CB0(1-XB)) - (-k2(CB0(1-XB)Cc))) rC = (2.1*10^-2*(0.5(1-XA))(1(1-XB))-(-1.5*10^-2(1(1-XB)Cc))) rC = (0.0105(1-XA))(1-XB))+ (0.015(1-XB)Cc) rC = (0.0105(1-XB-XA+XAXB)+0.015Cc-XBCc V = (FC0 *XC)/-Rc XC = (V(-rC))/CB0*v XC = 1000*(0.0105(1-XB-XA+XAXB)+0.015Cc-XBCc)/1*0.1 xB = (10.5 - 10.5XB -10.5XA + 10.5XAXB + 0.015Cc - XBCc)/0.1 0.1 XB = 10.5 - 10.5XB - 10.5XA + 10.5 XAXB + 0.015 Cc - XBCc 10.5 XA - 10.5XAXB = 10.5 - 10.5 XB + 0.015 Cc - XBCc - 0.1 XB xA = (10.5 -10.5 XB + 0.015 Cc - XBCc - 0.1 XB)/10.5 - 10.5 XB
k3
0.00012
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