Hw4

  • October 2019
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QUANTUM THEORY OF MATTER Homework set #4: Time evolution of expectation values, Ehrenfest theorem

Problem # 4.1 : Show that d 2 1 hx i = (hxpx i + hpx xi) dt m for a three-dimensional wave-packet.

Problem # 4.2 : If hxi and hpi are the expectation values of x and p formed with the wave-function ψ(x) of a one-dimensional system, show that the expectation value of x and p formed with the wave-function φ(x) = exp[−(i/¯ h)hpix] ψ(x + hxi) vanishes, i.e. hxiφ = hpiφ = 0.

Problem # 4.3 : The Hamiltonian of a one-dimensional harmonic oscillator is given by p2 m H= + ω 2 x2 . 2m 2 (a) Find the time-dependence of the expectation value of x and p. What is the period of oscillation? (b) Show that the expectation values of x2 and p2 satisfy d 2 1 hx i = (hxpi + hpxi) dt m

and

d 2 hp i = −mω 2 (hxpi + hpxi) , dt

respectively. Compare with problem # 4.1. (c) Use these relations to show that the expectation value of the energy is conserved.

Hint: The equations of motion can be obtained either via partial integration (using Gauss’ divergence theorem) or using commutators with the Hamiltonian.

Problem # 4.4 : Virial theorem (a) Use the equation of motion for the expectation value of an operator O with the wavefunction ψ(t), i¯ h to show that

D∂ E d hOi = h[O, H]i + i¯ h O , dt ∂t D dV E d hxpi = 2hKEi − x , dt dx

where KE is the kinetic energy, V is the potential energy and H = KE + V . (b) Why is dhxpi/dt = 0 for a stationary state? In that case D dV E . 2hKEi = x dx This is called the virial theorem. (c) Use this result to prove that hKEi = hV i for stationary states of the harmonic oscillator.

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