Ejerc 1 Tp3.xlsx

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RM 1:1 Xa

S 0.1 0.2 0.3 0.4 0.5 0.6 0.7

0.6661 0.4788 0.3229 0.1984 0.1055 0.0440 0.0141

PC

FFA=FRA (lbmol/h) FB (lbmol/h) RA (lbmol/h) 12402.798 1378.09 13780.89 7669.814 1917.45 9587.27 6634.455 2843.34 9477.79 6939.125 4626.08 11565.21 8701.422 8701.42 17402.84 13896.458 20844.69 34741.14 27982.117 65291.61 93273.72

FA (lbmol/h) 13780.89 9587.27 9477.79 11565.21 17402.84 34741.14 93273.72

918

a b c

Cp 17.07 20.22 22.94

F1 C3 A n-C4

1.574 -2.346 0.885

0.08 0.8 0.12 F2

RM

1

ΔH1 ΔH2

COMPUESTO Propano C3 Isobutano B Buteno (A) Butano C4 Isooctano C Dodecano D

C3 B n-C4

Cp 17.073 22.385 22.943

0.12 0.73 0.15

-27440 BTU/lbmol -25180 BTU/lbmol

A

B 28.277 6.772 2.49E+01 20.056

C 1.16E-01 3.41E-01 2.06E-01 2.82E-01

D 1.959700E-04 -1.03E-04 5.98E-05 -1.31E-05

E -2.33E-07 -3.68E-08 -1.42E-07 -9.46E-08

6.87E-11 2.04E-11 4.71E-11 3.41E-11

PD (lbmol/h) 230.04 499.73 962.67 1854.04 3891.71 9963.34 32186.80

PC (lbmol/h) 918 918 918 918 918 918 918

FRB (lbmol/h) 1148.04 1417.73 1880.67 2772.04 4809.71 10881.34 33104.80

RB (lbmol/h) F1 (lbmol/h) F2 (lbmol/h) R (lbmol/h) 12632.84 1722.61 1572.66 25035.64 8169.54 2396.82 1942.09 15839.35 7597.12 3554.17 2576.26 14231.58 8793.17 5782.60 3797.32 15732.29 12593.13 10876.78 6588.65 21294.55 23859.80 26055.86 14905.95 37756.26 60168.92 81614.51 45349.05 88151.04

Cp F1

T in

20.30

P

Cp F2 21.83

T (K) 280.2 280.2 2.80E+02 280.2

CP J/mol . K

CP BTU/lbmol . R 71.5 17.07 93.7 22.38 8.46E+01 20.22 96.0 22.94

45 F 7.2 ºC 280.2 K 504.36 R 90 psia 6.12 atm

F (lbmol/h) F Cp (BTU/hr R) 28330.92 6.03E+05 20178.26 4.29E+05 20362.01 4.33E+05 25312.21 5.37E+05 38759.98 8.22E+05 78718.07 1.67E+06 215114.59 4.56E+06

R

Q1 (BTU/hr) Q2 (BTU/hr) Qtotal (BTU/hr) Tout (R ) -2.52E+07 -5.79E+06 -3.10E+07 555.8 -2.52E+07 -1.26E+07 -3.78E+07 592.4 -2.52E+07 -2.42E+07 -4.94E+07 618.6 -2.52E+07 -4.67E+07 -7.19E+07 638.1 -2.52E+07 -9.80E+07 -1.23E+08 654.1 -2.52E+07 -2.51E+08 -2.76E+08 669.7 -2.52E+07 -8.10E+08 -8.36E+08 687.7

10.73 pie3 psia/lbmol R

K1

95600000000000 -28000

K2

2.439E+017 -35000

Cao

0.0072

RM 1:1 Tout PROMEDIO 530.1 548.4 561.5 571.2 579.3 587.0 596.0

lbmol/pie3

K1 6.96E+11 8.20E+11 9.16E+11 9.92E+11 1.06E+12 1.12E+12 1.20E+12

K2 Vol molar (pie3/lbmol) ρ molar (lbmol/pie3) 5.18E+14 63.19 0.0158 6.37E+14 65.38 0.0153 7.32E+14 66.94 0.0149 8.08E+14 68.10 0.0147 8.74E+14 69.06 0.0145 9.42E+14 69.99 0.0143 1.02E+15 71.06 0.0141 0.0148

CA CB CC Ccomb

4.4 $/lbmol 5.63 $/lbmol 36.54 $/lbmol 0.000004 $/BTU

Vreactor (pie3) C reactor($/año) 4.09841592E-10 0.0182 5.22293556E-10 0.0208 7.70400008E-10 0.0259 1.32447547E-09 0.0350 2.76237347E-09 0.0528 7.67567921E-09 0.0934 2.94887116E-08 0.1979

Pc3 326.53 424.80 593.48 918.29 1660.78 3873.18 11971.05

P n-c4 Qtotal 442.61 858714316 578.93 1120994268 812.94 1571229260 1263.51 2438135177 2293.51 4419873104 5362.60 10324847473 16596.10 31938304078

PE2 199279704 176114170 136347754 59779423.7 -115254984 -636804115 -2.546E+09

953,913.3 BTU/ lbmol 1,236,372.8 BTU/ lbmol

ΔHc C3 ΔHc C4

PE3 vs Xa 5.00E+08 0.00E+00

PE3

-5.00E+08

0

0.1

0.2

0.3

-1.00E+09

0.4

0.5

0.6

0.7

0.8

PE3

-1.50E+09 -2.00E+09 -2.50E+09 -3.00E+09 Xa

PE3 199279703.5238 176114170.1670 136347753.8742 59779423.6331 -115254984.4640 -636804115.4436 -2545784375.8196

RM 1:3 S FA (lbmol/h) RA (lbmol/h) FFA=FRA (lbmol/h) FB (lbmol/h) PD (lbmol/h) PC (lbmol/h) 0.9728 9436.80 8493.123 943.68 28310.41 12.84 918 0.9500 4831.44 3865.149 966.29 14494.31 24.14 918 0.9285 3295.56 2306.890 988.67 9886.67 35.33 918 0.9083 2526.78 1516.066 1010.71 7580.33 46.36 918 0.8893 2064.60 1032.302 1032.30 6193.81 57.15 918 0.8715 1755.53 702.212 1053.32 5266.59 67.66 918 0.8550 1533.76 460.127 1073.63 4601.27 77.82 918

Xa 0.1 0.2 0.3 0.4 0.5 0.6 0.7

PC

918

a b c

Cp 17.07 20.22 22.94

F1 C3 A n-C4

0.0627 -0.2464 0.9968

0.08 0.8 0.12 F2

RM

3

ΔH1 ΔH2

C3 B n-C4

Cp F1 20.30

Cp 17.073 22.385 22.943

0.12 0.73 0.15

Cp F2 21.83

-27440 BTU/lbmol -25180 BTU/lbmol

COMPUESTOA B Propano C3 28.277 Isobutano B 6.772 Buteno (A) 2.49E+01 Butano C4 20.056 Isooctano C

C 1.16E-01 3.41E-01 2.06E-01 2.82E-01

D 1.959700E-04 -1.03E-04 5.98E-05 -1.31E-05

E -2.33E-07 -3.68E-08 -1.42E-07 -9.46E-08

T (K) 6.87E-11 2.04E-11 4.71E-11 3.41E-11

CP J/mol . K 280.2 71.5 280.2 93.7 2.80E+02 8.46E+01 280.2 96.0

Dodecano D

RM 1

RM 3

Xa 199279704 176114170 136347754 59779423.6 -115254984

PE3 vs Xa

217937394 216966434 216005236 215058475 214131143

500000000 0 -500000000 PE3

0.1 0.2 0.3 0.4 0.5

-1000000000 -1500000000 -2000000000

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

500000000 0

0.6 -636804115 213228512 0.7 -2.546E+09 212356092

PE3

-500000000

0

0.1

0.2

0.3

-1000000000 -1500000000 -2000000000 -2500000000 -3000000000 Xa

0.4

0.5

0.6

0.7

0.8

FRB (lbmol/h) 930.84 942.14 953.33 964.36 975.15 985.66 995.82

RB (lbmol/h) F1 (lbmol/h) F2 (lbmol/h) R (lbmol/h) F (lbmol/h) F Cp (BTU/hr R) Q1 (BTU/hr) 27379.57 1179.60 1275.12 35872.69 38327.42 8.36E+05 -2.52E+07 13552.17 1207.86 1290.61 17417.32 19915.78 4.34E+05 -2.52E+07 8933.34 1235.83 1305.94 11240.23 13782.00 3.00E+05 -2.52E+07 6615.97 1263.39 1321.03 8132.04 10716.46 2.33E+05 -2.52E+07 5218.66 1290.38 1335.82 6250.96 8877.16 1.93E+05 -2.52E+07 4280.93 1316.65 1350.22 4983.14 7650.01 1.66E+05 -2.52E+07 3605.46 1342.04 1364.13 4065.58 6771.75 1.47E+05 -2.52E+07

T in

P

90 psia 6.12 atm

CP BTU/lbmol . R 17.07 22.38 20.22 22.94

s Xa

0.4

0.5

0.6

0.7

45 F 7.2 ºC 280.2 K 504.36 R

0.8 RM 1 RM 3

R

10.73 pie3 psia/lbmol R

K1

9.56E+13 -28000

K2

2.439E+017 -35000

0.4

0.5

0.6

0.7

0.8 RM 1 RM 3

RM 1:1 Q2 (BTU/hr) Qtotal (BTU/hr) Tout (R ) Tout PROMEDIO -3.23E+05 -2.55E+07 534.9 519.6 -6.08E+05 -2.58E+07 563.8 534.1 -8.90E+05 -2.61E+07 591.2 547.8 -1.17E+06 -2.64E+07 617.4 560.9 -1.44E+06 -2.66E+07 642.3 573.3 -1.70E+06 -2.69E+07 666.2 585.3 -1.96E+06 -2.71E+07 689.0 596.7

ie3 psia/lbmol R

Cao

0.0037 lbmol/pie3

K1 6.30E+11 7.22E+11 8.16E+11 9.12E+11 1.01E+12 1.11E+12 1.21E+12

K2 Vol molar (pie3/lbmol) ρ molar (lbmol/pie3) 4.58E+14 61.95 0.0161 5.43E+14 63.67 0.0157 6.33E+14 65.31 0.0153 7.27E+14 66.87 0.0150 8.25E+14 68.35 0.0146 9.26E+14 69.78 0.0143 1.03E+15 71.14 0.0141 0.0150

CA CB CC Ccomb

4.4 $/lbmol 5.63 $/lbmol 36.54 $/lbmol 0.000004 $/BTU

Vreactor (pie3)C reactor($/año) 6.1818E-10 0.0229 6.0087E-10 0.0225 6.0292E-10 0.0226 6.2595E-10 0.0231 6.7607E-10 0.0241 7.6794E-10 0.0258 9.3799E-10 0.0289

ΔHc C3 ΔHc C4

Pc3 247.38 251.50 255.58 259.60 263.53 267.36 271.06

P n-c4 332.82 338.53 344.19 349.76 355.22 360.53 365.66

Qtotal 647472117 658465320 669347994 680067212 690566461 700786037 710663565

PE2 217937394 216966434 216005236 215058475 214131143 213228512 212356092

953,913.3 BTU/ lbmol 1,236,372.8 BTU/ lbmol

PE3 vs X 2.00E+08

PE3

1.50E+08 1.00E+08 5.00E+07 0.00E+00

0

0.1

0.2

0.3

0.4 Xa

0.5

0.6

0.7

0.8

PE3 2.18E+08 2.17E+08 2.16E+08 2.15E+08 2.14E+08 2.13E+08 2.12E+08

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