Dodecan Simulation Data

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60.86% ester in 1.2 h REACTOR CHARACTERISTICS =======================

OPERATING MODE : ISOTHERMAL WITHOUT HEATING SYSTEM TEMPERATURE................................ PRESSURE................................... CLOCK: TIME ELAPSED = 1:00:00.0 EVENT REACHED: TIME ELAPSED SINCE THE BEGINNING OF STEP

60.0000 1.00000

(C) (ATM)

TEMPS =

1:00:00.0

1 TIME VOLUME FEED FLOWRATE SIDESTREAMS (KG/HR) (HHHH:MM:SS) (M3) (KG/HR) LIQUID VAPOR --------------------------------------------------------------------------0 2.323867E-03 0.200000 0.00000 0.00000 5:00 2.325265E-03 0.200000 0.00000 0.00000 10:00 2.326618E-03 0.200000 0.00000 0.00000 15:00 2.327960E-03 0.200000 0.00000 0.00000 20:00 2.329268E-03 0.200000 0.00000 0.00000 25:00 2.330612E-03 0.200000 0.00000 0.00000 30:00 2.331979E-03 0.200000 0.00000 0.00000 35:00 2.333307E-03 0.200000 0.00000 0.00000 40:00 2.334677E-03 0.200000 0.00000 0.00000 45:00 2.336052E-03 0.200000 0.00000 0.00000 50:00 2.337413E-03 0.200000 0.00000 0.00000 55:00 2.338795E-03 0.200000 0.00000 0.00000 1:00:00 2.340177E-03 0.200000 0.00000 0.00000 1 LIQUID MASS FRACTIONS TIME N-DODECANOIC METHANOL METHYL DODEC EAU (HHHH:MM:SS) --------------------------------------------------------------------------0 0.999879 0.00000 1.114791E-04 9.369323E-06 5:00 0.940066 0.00000 5.528699E-02 4.646605E-03 10:00 0.881088 0.00000 0.109692 9.219070E-03 15:00 0.823061 0.00000 0.163221 1.371781E-02 20:00 0.765946 0.00000 0.215908 1.814563E-02 25:00 0.709764 0.00000 0.267735 2.250131E-02 30:00 0.654486 0.00000 0.318727 2.678696E-02 35:00 0.600052 0.00000 0.368941 3.100702E-02 40:00 0.546493 0.00000 0.418347 3.515936E-02 45:00 0.493767 0.00000 0.466986 3.924717E-02 50:00 0.441842 0.00000 0.514885 4.327282E-02 55:00 0.390723 0.00000 0.562041 4.723605E-02 1:00:00 0.340378 0.00000 0.608482 5.113926E-02 1 MASS CONCENTRATIONS (G/L) TIME N-DODECANOIC METHANOL METHYL DODEC EAU (HHHH:MM:SS) --------------------------------------------------------------------------0 860.545 0.00000 9.594434E-02 8.063696E-03 5:00 815.304 0.00000 47.9495 4.02993 10:00 770.007 0.00000 95.8632 8.05680 15:00 724.757 0.00000 143.727 12.0794 20:00 679.544 0.00000 191.552 16.0987 25:00 634.398 0.00000 239.306 20.1120 30:00 589.317 0.00000 286.991 24.1197 35:00 544.268 0.00000 334.642 28.1244 40:00 499.293 0.00000 382.215 32.1227 45:00 454.374 0.00000 429.729 36.1160

50:00 55:00 1:00:00

409.499 364.690 319.934

0.00000 0.00000 0.00000

477.195 524.593 571.934

40.1052 44.0888 48.0676

1 >>> PROSIM BATCH BATCH PROCESSES SIMULATOR DODECANOIC ACID TRANSESTERIFICATION WITH METHANOL

V5.01.2118388

>>>>>> STEP : STEP1

MASS BALANCE AT THE END OF STEP ------------------------------STOP AT TIME : 1:00:00.0 STEP TIME : 1:00:00.0

-----------------------------------------------------------------------------COMPONENT ! INITIAL LOAD SIDESTREAMS ! (KG) FRACTION (KG) FRACTION ! N-DODECANOIC ACI ! 2.00000 1.00000 0.00000 METHANOL ! 0.00000 0.00000 0.00000 METHYL DODECANOA ! 0.00000 0.00000 0.00000 EAU ! 0.00000 0.00000 0.00000 ------------------------TOTAL (KG) 2.00000 0.00000 COMPONENT

! ! ! N-DODECANOIC ACI ! METHANOL ! METHYL DODECANOA ! EAU ! TOTAL (KG) COMPONENT

! ! ! N-DODECANOIC ACI ! METHANOL ! METHYL DODECANOA ! EAU ! TOTAL (KG)

+ (KG)

FEEDS

0.00000 0.200000 0.00000 0.00000 ------------0.200000

= FRACTION 0.00000 1.00000 0.00000 0.00000

TRANSFORMATION (KG) 1.25133 0.200000 -1.33838 -0.112483 ------------4.661218E-04

>>>>>> END OF STEP : STEP1 END OF RUN 1 TIMES ELAPSED INITIALIZATIONS...........

0.0

FINAL LOAD (KG) FRACTION 0.748674 3.695657E-17 1.33838 0.112483 ------------2.19962

0.340366 0.00000 0.608460 5.113737E-02

READING................... DATA REPORT............... EXECUTION................. OUTPUT REPORT.............

1.0 0.0 0.0 0.0

TOTAL...................

1.0

91.4% ester in 1.8h TIME VOLUME FEED FLOWRATE SIDESTREAMS (KG/HR) (HHHH:MM:SS) (M3) (KG/HR) LIQUID VAPOR --------------------------------------------------------------------------48:00 2.336868E-03 0.200000 0.00000 0.00000 53:00 2.288403E-03 0.200000 0.00000 0.00000 58:00 2.283356E-03 0.200000 0.00000 0.00000 1:03:00 2.283274E-03 0.200000 0.00000 0.00000 1:08:00 2.283888E-03 0.200000 0.00000 0.00000 1:13:00 2.284604E-03 0.200000 0.00000 0.00000 1:18:00 2.285329E-03 0.200000 0.00000 0.00000

1:23:00 1:28:00 1:33:00 1:38:00 1:42:00

2.286053E-03 2.286805E-03 2.287572E-03 2.288725E-03 2.299890E-03

0.200000 0.200000 0.200000 0.200000 0.200000

0.00000 0.00000 0.00000 0.00000 0.00000

0.00000 0.00000 0.00000 0.00000 0.00000

1 LIQUID MASS FRACTIONS TIME N-DODECANOIC METHANOL METHYL DODEC EAU (HHHH:MM:SS) --------------------------------------------------------------------------48:00 0.462516 0.00000 0.495814 4.166999E-02 53:00 0.411095 0.00000 0.543248 4.565666E-02 58:00 0.360456 0.00000 0.589961 4.958272E-02 1:03:00 0.310580 0.00000 0.635970 5.344955E-02 1:08:00 0.261452 0.00000 0.681290 5.725846E-02 1:13:00 0.213053 0.00000 0.725936 6.101080E-02 1:18:00 0.165353 0.00000 0.769938 6.470892E-02 1:23:00 0.118343 0.00000 0.813304 6.835360E-02 1:28:00 7.203162E-02 0.00000 0.856024 7.194408E-02 1:33:00 2.639701E-02 0.00000 0.898121 7.548212E-02 1:38:00 0.00000 2.972596E-03 0.919729 7.729821E-02 1:42:00 0.00000 8.654812E-03 0.914488 7.685767E-02 1 MASS CONCENTRATIONS (G/L) TIME N-DODECANOIC METHANOL METHYL DODEC EAU (HHHH:MM:SS) --------------------------------------------------------------------------48:00 427.443 0.00000 458.215 38.5101 53:00 390.961 0.00000 516.641 43.4205 58:00 346.190 0.00000 566.612 47.6204 1:03:00 300.566 0.00000 615.464 51.7261 1:08:00 254.862 0.00000 664.116 55.8151 1:13:00 209.172 0.00000 712.711 59.8993 1:18:00 163.494 0.00000 761.280 63.9813 1:23:00 117.837 0.00000 809.825 68.0612 1:28:00 72.2246 0.00000 858.318 72.1369 1:33:00 26.6512 0.00000 906.769 76.2089 1:38:00 0.00000 3.02135 934.815 78.5661 1:42:00 0.00000 8.80424 930.276 78.1846 1 *** DUTY SUPPLIED BY JACKET TEMPERATURES (C) TIME BOILER WALL UTILITIES LMTD (HHHH:MM:SS) --------------------------------------------------------------------------48:00 0.00000 0.00000 0.00000 0.00000 53:00 34.9583 29.8797 23.4951 -11.4632 58:00 31.8738 28.0049 22.6777 -9.19603 1:03:00 31.3832 27.7484 22.5642 -8.81892 1:08:00 31.2553 27.7155 22.5474 -8.70788

1:13:00 1:18:00 1:23:00 1:28:00 1:33:00 1:38:00 1:42:00

31.1820 31.1241 31.0724 31.0246 30.9799 27.0093 24.2125

27.7139 27.7192 27.7256 27.7318 27.7374 25.0878 23.1202

22.5437 22.5426 22.5421 22.5418 22.5415 21.5042 20.8526

-8.63832 -8.58148 -8.53026 -8.48283 -8.43837 -5.50514 -3.35989

1 *** DUTY SUPPLIED BY JACKET HEAT EXCHANGE COEFFICIENTS (KCAL/HR/M2/K) TIME OVERALL PROCESS SIDE UTILITY SIDE (HHHH:MM:SS) ----------------------------------------------------------48:00 0.00000 0.00000 0.00000 53:00 348.040 963.798 580.973 58:00 333.323 974.320 534.811 1:03:00 333.088 997.833 526.837 1:08:00 334.952 1022.45 524.632 1:13:00 337.009 1046.54 523.366 1:18:00 338.999 1069.95 522.341 1:23:00 340.879 1092.66 521.417 1:28:00 342.648 1114.68 520.562 1:33:00 344.314 1136.07 519.758 1:38:00 311.486 1130.08 444.788 1:42:00 288.458 1122.23 397.261 1

DESIGN DATA TIME OVERALL EXCHA LIQUID HEIGHT LIQUID VOLUME (HHHH:MM:SS) NGE AREA (M2) (M) (M3) ----------------------------------------------------------48:00 0.00000 0.00000 0.00000 53:00 8.758985E-02 0.202339 2.288403E-03 58:00 8.742162E-02 0.201893 2.283356E-03 1:03:00 8.741888E-02 0.201886 2.283274E-03 1:08:00 8.743933E-02 0.201940 2.283888E-03 1:13:00 8.746321E-02 0.202003 2.284604E-03 1:18:00 8.748737E-02 0.202067 2.285329E-03 1:23:00 8.751148E-02 0.202131 2.286053E-03 1:28:00 8.753656E-02 0.202198 2.286805E-03 1:33:00 8.756214E-02 0.202266 2.287572E-03 1:38:00 8.760056E-02 0.202368 2.288725E-03 1:42:00 8.797273E-02 0.203355 2.299890E-03 1

PHYSICAL PROPERTIES TIME DENSITY SPECIFIC HEAT VISCOSITY CONDUCTIVITY (HHHH:MM:SS) (G/L) (CAL/G/K) (PA.S) (W/M/K) ------------------------------------------------------------------------------

48:00 53:00 58:00 1:03:00 1:08:00 1:13:00 1:18:00 1:23:00 1:28:00 1:33:00 1:38:00 1:42:00

0.00000 951.023 960.423 967.756 974.793 981.782 988.756 995.723 1002.68 1009.63 1016.40 1017.26

0.00000 0.511601 0.510296 0.510526 0.510957 0.511413 0.511873 0.512330 0.512783 0.513233 0.512165 0.511599

0.00000 2.408878E-03 2.369566E-03 2.207272E-03 2.049032E-03 1.908399E-03 1.784153E-03 1.674113E-03 1.576262E-03 1.488840E-03 1.552749E-03 1.616301E-03

0.00000 0.129255 0.128424 0.127201 0.125973 0.124789 0.123652 0.122561 0.121515 0.120509 0.120746 0.121457

1 >>> PROSIM BATCH BATCH PROCESSES SIMULATOR DODECANOIC ACID TRANSESTERIFICATION WITH METHANOL

V5.01.2118388

>>>>>> STEP : STEP2

MASS BALANCE AT THE END OF STEP ------------------------------STOP AT TIME : 1:42:00.0 STEP TIME : 54:00.0

-----------------------------------------------------------------------------COMPONENT ! INITIAL LOAD SIDESTREAMS ! (KG) FRACTION (KG) FRACTION ! N-DODECANOIC ACI ! 0.998840 0.462516 0.00000 METHANOL ! 2.766112E-17 0.00000 0.00000 METHYL DODECANOA ! 1.07075 0.495814 0.00000 EAU ! 8.998957E-02 4.166999E-02 0.00000 ------------------------TOTAL (KG) 2.15958 0.00000 COMPONENT

! ! ! N-DODECANOIC ACI ! METHANOL ! METHYL DODECANOA ! EAU ! TOTAL (KG) COMPONENT

! ! ! N-DODECANOIC ACI ! METHANOL ! METHYL DODECANOA ! EAU !

+ (KG)

FEEDS

0.00000 0.180000 0.00000 0.00000 ------------0.180000

= FRACTION 0.00000 1.00000 0.00000 0.00000

TRANSFORMATION (KG) 0.998840 0.159752 -1.06872 -8.982101E-02 -------------

FINAL LOAD (KG) FRACTION 4.447232E-10 2.024816E-02 2.13947 0.179811 ------------2.33960

1.900854E-10 8.654552E-03 0.914460 7.685536E-02

TOTAL (KG)

5.058306E-05

>>>>>> END OF STEP : STEP2 END OF RUN 1 TIMES ELAPSED INITIALIZATIONS........... READING................... DATA REPORT............... EXECUTION................. OUTPUT REPORT.............

0.0 0.0 0.0 2.0 0.0

TOTAL...................

2.0

1 >>> PROSIM BATCH

BATCH PROCESSES SIMULATOR

V5.01.2118388

DODECANOIC ACID TRANSESTERIFICATION WITH METHANOL PROCESS MATRIX STREAM

FROM

TO

STRE1 STRE2 STRE3

>>>> >>>> >>>>

STEP1 STEP2 STEP3

1 >>> PROSIM BATCH

BATCH PROCESSES SIMULATOR

V5.01.2118388

DODECANOIC ACID TRANSESTERIFICATION WITH METHANOL INITIALIZED STREAMS STREAM NAME THERMO. PROFILE FROM TO

STRE1 *THE1 >>>> STEP1

STRE2 *THE1 >>>> STEP2

STRE3 *THE1 >>>> STEP3

PHASE

VAPOR

VAPOR

VAPOR

COMPONENTS N-DODECANOIC ACI METHANOL

0.00000 0.00000 0.00000 6.241769E-03 6.241769E-03 6.241769E-03

METHYL DODECANOA EAU

0.00000 0.00000

TOTAL FLOW (KMOL/HR) TEMPERATURE (C) PRESSURE (ATM) ENTHALPY (KCAL/HR) VAPOR FRACTION

0.00000 0.00000

0.00000 0.00000

6.241769E-03 6.241769E-03 6.241769E-03 90.0000 1.00000 4.29492 1.00000

90.0000 1.00000 4.29492 1.00000

90.0000 1.00000 4.29492 1.00000

1 >>> PROSIM BATCH

BATCH PROCESSES SIMULATOR

V5.01.2118388

PROSIM SA

STRATEGE BAT. A BP 2738 F-31312 LABEGE CEDEX FRANCE SIMULATION OF THE MATTER TRANSFORMATION PROCESSES DODECANOIC ACID TRANSESTERIFICATION WITH METHANOL

EXECUTION 1 >>> PROSIM BATCH BATCH PROCESSES SIMULATOR DODECANOIC ACID TRANSESTERIFICATION WITH METHANOL

V5.01.2118388

>>>>>> BEGINNING OF STEP : STEP1 1 INLET STREAM(S)

STRE1

THERMODYNAMIC MODEL : *THE1

REACTOR CHARACTERISTICS =======================

OPERATING MODE : ISOTHERMAL WITHOUT HEATING SYSTEM TEMPERATURE................................ PRESSURE...................................

60.0000 1.00000

(C) (ATM)

CLOCK: TIME ELAPSED = 42:00.0 EVENT REACHED: TIME ELAPSED SINCE THE BEGINNING OF RUN TEMPS = 42:00.0 1 TIME VOLUME FEED FLOWRATE SIDESTREAMS (KG/HR) (HHHH:MM:SS) (M3) (KG/HR) LIQUID VAPOR --------------------------------------------------------------------------0 2.323867E-03 0.200000 0.00000 0.00000 5:00 2.325268E-03 0.200000 0.00000 0.00000

10:00 15:00 20:00 25:00 30:00 35:00 40:00 42:00

2.326682E-03 2.328009E-03 2.329416E-03 2.330766E-03 2.332075E-03 2.333459E-03 2.334868E-03 2.335428E-03

0.200000 0.200000 0.200000 0.200000 0.200000 0.200000 0.200000 0.200000

0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000

0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000

1 LIQUID MASS FRACTIONS TIME N-DODECANOIC METHANOL METHYL DODEC EAU (HHHH:MM:SS) --------------------------------------------------------------------------0 0.999879 0.00000 1.114791E-04 9.369323E-06 5:00 0.940068 0.00000 5.528567E-02 4.646500E-03 10:00 0.881124 0.00000 0.109660 9.216406E-03 15:00 0.823091 0.00000 0.163194 1.371568E-02 20:00 0.766036 0.00000 0.215825 1.813911E-02 25:00 0.709860 0.00000 0.267646 2.249434E-02 30:00 0.654547 0.00000 0.318671 2.678250E-02 35:00 0.600150 0.00000 0.368850 3.099984E-02 40:00 0.546618 0.00000 0.418231 3.515012E-02 42:00 0.525438 0.00000 0.437770 3.679226E-02 1 MASS CONCENTRATIONS (G/L) TIME N-DODECANOIC METHANOL METHYL DODEC EAU (HHHH:MM:SS) --------------------------------------------------------------------------0 860.545 0.00000 9.594434E-02 8.063696E-03 5:00 815.305 0.00000 47.9484 4.02983 10:00 770.035 0.00000 95.8341 8.05443 15:00 724.781 0.00000 143.702 12.0775 20:00 679.615 0.00000 191.476 16.0927 25:00 634.476 0.00000 239.223 20.1055 30:00 589.367 0.00000 286.937 24.1155 35:00 544.349 0.00000 334.555 28.1175 40:00 499.399 0.00000 382.102 32.1137 42:00 481.432 0.00000 401.107 33.7109 1 >>> PROSIM BATCH BATCH PROCESSES SIMULATOR V5.01.2118388 DODECANOIC ACID TRANSESTERIFICATION WITH METHANOL

>>>>>> STEP : STEP1

MASS BALANCE AT THE END OF STEP ------------------------------STOP AT TIME : 42:00.0 STEP TIME : 42:00.0

-----------------------------------------------------------------------------COMPONENT ! INITIAL LOAD SIDESTREAMS ! (KG) FRACTION (KG) FRACTION ! N-DODECANOIC ACI ! 2.00000 1.00000 0.00000 METHANOL ! 0.00000 0.00000 0.00000 METHYL DODECANOA ! 0.00000 0.00000 0.00000 EAU ! 0.00000 0.00000 0.00000 ------------------------TOTAL (KG) 2.00000 0.00000 COMPONENT

! ! ! N-DODECANOIC ACI ! METHANOL ! METHYL DODECANOA ! EAU ! TOTAL (KG) COMPONENT

! ! ! N-DODECANOIC ACI ! METHANOL ! METHYL DODECANOA ! EAU ! TOTAL (KG)

+ (KG)

FEEDS

0.00000 0.140000 0.00000 0.00000 ------------0.140000

= FRACTION 0.00000 1.00000 0.00000 0.00000

FINAL LOAD (KG) FRACTION 1.12433 2.455984E-17 0.936741 7.872816E-02 ------------2.13984

0.525429 0.00000 0.437763 3.679168E-02

TRANSFORMATION (KG) 0.875667 0.140000 -0.936741 -7.872816E-02 ------------1.977103E-04

>>>>>> END OF STEP : STEP1 1 >>> PROSIM BATCH BATCH PROCESSES SIMULATOR DODECANOIC ACID TRANSESTERIFICATION WITH METHANOL

V5.01.2118388

>>>>>> BEGINNING OF STEP : STEP2 1 INLET STREAM(S)

STRE2

THERMODYNAMIC MODEL : *THE1

REACTOR CHARACTERISTICS =======================

OPERATING MODE : VARIABLE HEAT (CF. DESCRIPTION). PRESSURE................................... 1

1.00000

(ATM)

HEATING SYSTEM CHARACTERISTICS ============================== NUMBER OF DESCRIBED SYSTEMS................

1

VESSEL CHARACTERISTICS ---------------------VESSEL WITH FLAT BOTTOM VESSEL DIAMETER......................... 0.120000

(M)

MIXING CHARACTERISTICS ---------------------DIAMETER OF THE MIXING DEVICE........... ROTATIONAL SPEED........................ HEIGHT OF THE MIXING DEVICE (TO THE BOTTOM OF THE VESSEL)................... BAFFLES ON THE WALL..................... MIXING DEVICE...........................

4.500000E-02 (M) 1000.00 (TR/MIN) 7.999999E-03 (M) NO 6 FLAT-BLADES TURBINE IMPELLER

EXCHANGE AT THE WALL (DOUBLE JACKET) -----------------------------------DESIGN: DISPOSITION............................. HEIGHT BETWEEN THE BOTTOM OF THE VESSEL AND THE HEAD OF THE JACKET.............. THICKNESS OF THE JACKET................. DIMPLE JACKET........................... SPIRALY BAFFLED JACKET.................. NOZZLES.................................

JOINED SIDE AND BOTTOM 0.250000 (M) 1.000000E-02 (M) NO NO NO

UTILITIES (WATER): MASS FLOWRATE........................... 100.000 INLET TEMPERATURE....................... 20.0000 FLUID CIRCULATION....................... DOWNWARD

(KG/HR) (C)

EXCHANGE COEFFICIENTS: OVERALL................................. CALCULATED PROCESS SIDE............................ CALCULATED UTILITIES SIDE.......................... CALCULATED MATERIAL 1: THICKNESS............................... 4.000000E-03 (M) THERNAL CONDUCTIVITY.................... 19.0000 (W/M/K) FOULING OF THE MATERIALS................ NO

CLOCK: TIME ELAPSED = 1:36:00.0 EVENT REACHED: TIME ELAPSED SINCE THE BEGINNING OF STEP TEMPS = 54:00.0 1

TIME VOLUME FEED FLOWRATE SIDESTREAMS (KG/HR) (HHHH:MM:SS) (M3) (KG/HR) LIQUID VAPOR --------------------------------------------------------------------------42:00 2.335428E-03 0.200000 0.00000 0.00000 47:00 2.292856E-03 0.200000 0.00000 0.00000 52:00 2.281508E-03 0.200000 0.00000 0.00000 57:00 2.278097E-03 0.200000 0.00000 0.00000 1:02:00 2.277254E-03 0.200000 0.00000 0.00000 1:07:00 2.277325E-03 0.200000 0.00000 0.00000 1:12:00 2.277736E-03 0.200000 0.00000 0.00000 1:17:00 2.278272E-03 0.200000 0.00000 0.00000 1:22:00 2.278863E-03 0.200000 0.00000 0.00000 1:27:00 2.279460E-03 0.200000 0.00000 0.00000 1:32:00 2.280061E-03 0.200000 0.00000 0.00000 1:36:00 2.280694E-03 0.200000 0.00000 0.00000 1 LIQUID MASS FRACTIONS TIME N-DODECANOIC METHANOL METHYL DODEC EAU (HHHH:MM:SS) --------------------------------------------------------------------------42:00 0.525438 0.00000 0.437770 3.679226E-02 47:00 0.473059 0.00000 0.486088 4.085317E-02 52:00 0.421483 0.00000 0.533665 4.485180E-02 57:00 0.370693 0.00000 0.580517 4.878955E-02 1:02:00 0.320670 0.00000 0.626662 5.266781E-02 1:07:00 0.271397 0.00000 0.672115 5.648793E-02 1:12:00 0.222858 0.00000 0.716891 6.025117E-02 1:17:00 0.175035 0.00000 0.761006 6.395884E-02 1:22:00 0.127914 0.00000 0.804474 6.761211E-02 1:27:00 8.146534E-02 0.00000 0.847321 7.121324E-02 1:32:00 3.567651E-02 0.00000 0.889560 7.476319E-02 1:36:00 0.00000 7.447402E-05 0.922402 7.752339E-02 1 MASS CONCENTRATIONS (G/L) TIME N-DODECANOIC METHANOL METHYL DODEC EAU (HHHH:MM:SS) --------------------------------------------------------------------------42:00 481.432 0.00000 401.107 33.7109 47:00 444.926 0.00000 457.181 38.4237 52:00 401.469 0.00000 508.323 42.7219 57:00 356.331 0.00000 558.026 46.8992 1:02:00 310.707 0.00000 607.192 51.0314 1:07:00 264.943 0.00000 656.131 55.1445 1:12:00 219.149 0.00000 704.961 59.2485 1:17:00 173.362 0.00000 753.733 63.3476 1:22:00 127.594 0.00000 802.462 67.4430 1:27:00 81.8355 0.00000 851.172 71.5368 1:32:00 36.0896 0.00000 899.860 75.6288 1:36:00 0.00000 7.575066E-02 938.214 78.8523 1 *** DUTY SUPPLIED BY JACKET

TEMPERATURES (C) TIME BOILER WALL UTILITIES LMTD (HHHH:MM:SS) --------------------------------------------------------------------------42:00 0.00000 0.00000 0.00000 0.00000 47:00 37.7439 32.1460 24.4785 -13.2654 52:00 31.3272 27.9918 22.6419 -8.68526 57:00 29.0974 26.5292 22.0454 -7.05198 1:02:00 28.2323 25.9641 21.8241 -6.40820 1:07:00 27.8514 25.7220 21.7300 -6.12147 1:12:00 27.6508 25.5990 21.6825 -5.96828 1:17:00 27.5166 25.5187 21.6515 -5.86513 1:22:00 27.4126 25.4566 21.6276 -5.78500 1:27:00 27.3222 25.4013 21.6067 -5.71552 1:32:00 27.2422 25.3512 21.5877 -5.65457 1:36:00 27.1401 25.2835 21.5640 -5.57604 1 *** DUTY SUPPLIED BY JACKET HEAT EXCHANGE COEFFICIENTS (KCAL/HR/M2/K) TIME OVERALL PROCESS SIDE UTILITY SIDE (HHHH:MM:SS) ----------------------------------------------------------42:00 0.00000 0.00000 0.00000 47:00 384.419 1160.15 618.192 52:00 348.232 1153.38 525.467 57:00 332.785 1164.22 486.573 1:02:00 326.681 1179.57 470.007 1:07:00 324.383 1195.12 462.358 1:12:00 323.510 1209.30 458.225 1:17:00 323.069 1221.54 455.419 1:22:00 322.739 1231.66 453.222 1:27:00 322.369 1239.57 451.301 1:32:00 321.936 1245.25 449.589 1:36:00 321.051 1247.99 447.355 1

DESIGN DATA TIME OVERALL EXCHA LIQUID HEIGHT LIQUID VOLUME (HHHH:MM:SS) NGE AREA (M2) (M) (M3) ----------------------------------------------------------42:00 0.00000 0.00000 0.00000 47:00 8.773828E-02 0.202733 2.292856E-03 52:00 8.736000E-02 0.201730 2.281508E-03 57:00 8.724629E-02 0.201428 2.278097E-03 1:02:00 8.721821E-02 0.201353 2.277254E-03 1:07:00 8.722057E-02 0.201360 2.277325E-03 1:12:00 8.723428E-02 0.201396 2.277736E-03 1:17:00 8.725212E-02 0.201443 2.278272E-03 1:22:00 8.727183E-02 0.201496 2.278863E-03 1:27:00 8.729173E-02 0.201549 2.279460E-03

1:32:00 1:36:00

8.731177E-02 8.733287E-02

0.201602 0.201658

2.280061E-03 2.280694E-03

1

PHYSICAL PROPERTIES TIME DENSITY SPECIFIC HEAT VISCOSITY CONDUCTIVITY (HHHH:MM:SS) (G/L) (CAL/G/K) (PA.S) (W/M/K) -----------------------------------------------------------------------------42:00 0.00000 0.00000 0.00000 0.00000 47:00 940.531 0.950691 2.528543E-03 0.130509 52:00 952.514 0.947189 2.669179E-03 0.130177 57:00 961.256 0.928334 2.573214E-03 0.129184 1:02:00 968.930 0.903731 2.414323E-03 0.128016 1:07:00 976.218 0.876544 2.250450E-03 0.126821 1:12:00 983.359 0.847876 2.098447E-03 0.125649 1:17:00 990.443 0.818150 1.961977E-03 0.124517 1:22:00 997.499 0.787533 1.840268E-03 0.123427 1:27:00 1004.54 0.756114 1.731743E-03 0.122379 1:32:00 1011.58 0.723957 1.634608E-03 0.121370 1:36:00 1017.14 0.698142 1.566078E-03 0.120612 1 >>> PROSIM BATCH BATCH PROCESSES SIMULATOR V5.01.2118388 DODECANOIC ACID TRANSESTERIFICATION WITH METHANOL

>>>>>> STEP : STEP2

MASS BALANCE AT THE END OF STEP ------------------------------STOP AT TIME : 1:36:00.0 STEP TIME : 54:00.0

-----------------------------------------------------------------------------COMPONENT ! INITIAL LOAD SIDESTREAMS ! (KG) FRACTION (KG) FRACTION ! N-DODECANOIC ACI ! 1.12433 0.525438 0.00000 METHANOL ! 2.455984E-17 0.00000 0.00000 METHYL DODECANOA ! 0.936741 0.437770 0.00000 EAU ! 7.872816E-02 3.679226E-02 0.00000 ------------------------TOTAL (KG) 2.13980 0.00000 COMPONENT

! ! ! N-DODECANOIC ACI ! METHANOL ! METHYL DODECANOA ! EAU !

+ (KG) 0.00000 0.180000 0.00000 0.00000

FEEDS

= FRACTION 0.00000 1.00000 0.00000 0.00000

FINAL LOAD (KG) FRACTION 1.579871E-15 1.727618E-04 2.13975 0.179836

0.00000 7.447302E-05 0.922390 7.752235E-02

TOTAL (KG) COMPONENT

! ! ! N-DODECANOIC ACI ! METHANOL ! METHYL DODECANOA ! EAU ! TOTAL (KG)

------------0.180000

------------2.31979

TRANSFORMATION (KG) 1.12433 0.179827 -1.20301 -0.101107 ------------4.364546E-05

>>>>>> END OF STEP : STEP2 END OF RUN 1 TIMES ELAPSED INITIALIZATIONS........... READING................... DATA REPORT............... EXECUTION................. OUTPUT REPORT.............

0.0 0.0 0.0 3.0 0.0

TOTAL...................

3.0

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