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7
7
"
7 !
!
) &
& *!
7 " 0 * " 6 8 0 ; "" " ' 6U ' '
8 ; "" " + '
' < * '
7 7 7 7
# * < P # P
!
9 ; + 6' 8 . * " * * * " + " ' 4* " :
+ " # P 4' ' " ' ' " K # "" " ' "P # "" " + ' "P
? !@A 7 Æ@ A # @AP # * P # * P @ ; < < " 7 / ; @A ' " < # 4' ' B
7 " 0 2 ; "" "' F
D
% @A 7 % # ' ' < " P ' ' " ' ' ' # ' ' < '
7
+ F"F * "' + * 8 I < " 6< A 5 ' " 8 "8 " 4' ' " 7 7 G ' G # "" ' P 6U ' + 8
77
7
7 " * " ; "" " ' 6U ' '
8 ; "" " + '
!
- $ *
" " ' ' $ # ' + ) !* , # " "' / " ' ( & !
! AA @ -
# > .( ' 6 ? ? 78 ( % ( ' ( M @A
@A
7
F % @A 7 @A
@
M
% A
@A 7
; % ' + 7
@A 7 F -
# " " ' @A 7 @+A F - @+A
# " '
* % " + " ; '
. 7 '
@A 7 F -
' " 4 ' ' H 4 ' ' ) AA
# ' % % @A 7
(
F%
*
!!
; " " % ' ' "
7 " - !7 C ; * @A 7 F +7
M
4 ' Æ " 7 6) " " 8 ; ¼ @A 7 '
+ 7
@
M
% A
64 " ' ¼ 8
Energy e ikx
+ Re-ikx
Te ik’x
E V0 transmitted
incident wave
V(x)
reflected
0 0
x
& Æ ' ' ' " " " $ # ' ( * ' " ' + '
" * 6 " ' ' ! ' 8 - % - 7 F 7'
( 7 (
!'
- !% % - %- 7 ¼ I"+ "+ J 7 I"+ ' J
. ' ( " # "
+ @ A 7 + @ F A
@+ F + A 7 @+ + A
Æ 7 ' 7F 7
+
+
+ F + + + F +
# ' - @A 7
( F
¼
¼ ¼
¼
*
' " + 6 4 1 . J! " 7
7
+
+
+ F +
64 ' Æ " Æ 7 " C ' " 8 - ' ' '
# 7 " 7
!++ @+ F + A
#2 ' C Æ "" C 6 B @ 78 " "" 7 + 7 + 6 8 "" + 7 6 ! *8 AA $
# " ' ' ' % ) % @A 7
* +
%
* **
!*
4" @A 7 F
¼ ¼ @A 7 F -
@A 7 '
' - !7 ! - - ! % ! - *
Aeik’x + Be-ik’x ikx
e
-ikx
+ Re
Energy
transmitted
reflected
0
Teikx E
incident wave
x V(x)
-V 0 0
- & Æ # ' ' + ' " # , '! C 6 B @ 8
7 "
'
7
@+ + A @ + A
F + A @ + A "@+
++ @ + A ++
@
+ A
++
"@+ F + A @ + A
( J ! ' . % * ! ! " $ "" " "" " C J * < - *A + 7
!
+ 7 7
@
% A
M
F
%
M
&
* ; & * '
AA# :! $
# ' '! ' ' " % * * ! ! 4 - @A 7 F -
'
.7
M
' " " ' " " F ' * " 7 , @A 7 , @A
- '2
@A 7 @+A F - @+A +7
@ F % A
' ' 9 ( 9 ! ' Æ
M
!&
Energy
0
Aeikx + Be-ikx
C1eκx
C3e −κx
x E
V(x)
-V 0 0
6 B @ 8 ' - " * % ! !! # % 6( * 8
. 7 @+A+
@ F % A
@ F % A 7 M M M
@ F % A 7 F% M
!!
. 7 @+A+
@ F % A M
F %
7
( ' ' "' ( ( E$ F # 6 8 ' ' 7 ' - ' ' '
!)
f(E)
Potential Well Bound States 5 4 3 2 1 0 -1 -2 -3 -4 -5
sqrt tan "-cot"
-20
-15
-10
-5
0
E (hbar**2/2ma**2)
7 - ' AA' :
# / " ' ,
*
)* % @ A 7 + F%
* **
4" @A 7 F
@A 7 F - @A 7 '
' " + ' ; " +7
M
'
- " .7
@%
M
A
Energy
e
ikx
Aeκx +Be−κx
-ikx
+ Re
Te ikx
V(x)
V0
transmitted
reflected
E
incident wave
0
0
x
6 " 8 ' " ' " +
".
! ! ' 7
+. +. @ .A "@+
. A @ .A
# "" " ' 7
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3 '
7
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"
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'
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7
F +
' ! )!* +, - * * M
F + 7
4 " * + ' " - (
+
< '
7
+
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F 7
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F
M
7 " + " ' , * * #
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M
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M
M
'
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M
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*
3 >
! % ! - ! " % @A 7
% Æ
@A
' * @A 7
(
' .7
*
M
' " "' # 2 ' " 7 = ' ' # ' 7 " Æ "
Energy
e
0
e−κx
κx
0 x
E V(x)
'
# ' " + 7 5 ! ' + 6 @ @ 8
7
%
7
7
.
M
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@A
%
M
%
M
.
M
7
7
%
M
%
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*
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%
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A
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M " " 7 "
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%
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*
%
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*
/ 2 " * ' ' ' % ' ! " ' + "' ' '
u(x)
1D Molecule
-4
-2
0
2
V(x) 4 u0(x) u1(x)
x
' < " ' @9 % / : " 6 ' 8 " 9 : G - ' " " ' % 7 @ 'A@ A@ *A G
' 7 9B G ' !! + (
%
.M
7 F @.A
%
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.*
%
M
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''
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> N $
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Æ @ A
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+7
M
/ " ( "" " ' + 6 B @ ?8 ( * " @!A 7 @+A F
@!A
%
M +
@+A
! "' $7 7 ! ! -
!
+
! *
"' ' @+A F
@+A + - "' $7 7 + '
'*
Energy Bands 2
cos(phi)
1 cos(phi) E
0 -1 -2 0
5
10
k (/A)
" ' + "
'
' + " " 6 8 "
*' 8 6 - * C - * " ( # ' %" 0 ' ! % - ! ! 7 7
( - ' 7 ! " ' - - "! 7 0 % ' '
7 (
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7
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7
7 M 7
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A A 23 -
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@ A 7
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#
#
# #
# & " % 6 "! C 8 7
M "
7
M "
,,
'&
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I@ F A@"+ "+ A ,, J
7
7
7 I J
"
"M + "
I F J F ,, M+
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+ M 7 '
"" " C " C !+ + !++ M+
7 7 '
M + @+ F + A + @+ F + A
' A A * - $
)* % @ A 7 +
%
* **
4" F
@A 7
¼ ¼ @A 7 F -
@A 7 '
' ' 6" ' ' ' 8 # ' ' + ' " 9 ( 2 ' 9 7 ' ( ' ' ¼ ¼ ' 7 F - ¼
¼
"+' 7 "+ "+ - ¼ ¼ + ' 7 -
+ ¼ + 7 ' F + ¼ - 7 '
+
+
')
7 ' ( ' ' " ' ' " " ¼ "+ 7 "+
+ F + + + 7 ' + F + + "+
+
¼ ¼ F 7 F -
F 7 '
¼
7 '
+
¼ "+ -
+
¼
F
¼
+
¼
F
+ + +
+
¼
¼
# (
+ + F F + + + + 7 ' F + + + + + + 7 ' F F F + + + + + + F 7
'
¼
+
F
@
+ A
@ + A
+
¼ "
¼ F
@ + A ++
++ @ + A " @+ F + A @ + A
# " (
F + + + + + + " @ + A F " @ + A 7 ' ! + + + + " 7 ' @ + A + + % &
7 '
+
¼
' 7
¼
! 7 ' ! @ + A "
' 7
¼
¼
¼
+
+
¼
¼
+
¼
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@ + A ¼ ++ @ + A " @+ F + A @ + A " + + @ + A 7 ++ @ + A " @+ F + A @ + A 7
# " ( + C
7 "
'
7
@+ + A @ + A ++ @ + A "@+ F + A @ + A ++
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M
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