Anotec 0307 Testing & Removal Efficiency
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1
© Anotec Pty Limited 2001
Furniture Manufacturing FactoryEfficacy Testing for Anotec Odour Control COMPOUND (ppb)
STACK
ANOTEC
carbonylsulphide sulphurdioxide dimethylsulphide carbondisulphide acetaldehyde 2-methylpropanal methanol ethanol i-propanol propanol t-butanol i-butanol butanol 3-methylbutanol acetone 2-butanone 3-buten-2-one 2,3-butandione methylisobutylketone ethylacetate butylacetate freon 11 freon 113 dichloromethane 1,2-dichloroethane chloroform 1,1,1-trichloroethane carbontetrachloride trichloroethylene i-pentane pentane 2-methylpentane 3-methylpentane hexane benzene methylhexanes heptane methylcyclopentane cyclohexane methylcyclohexane octane toluene ethylbenzene m,p-xylenes o-xylenes nonane decane undecane TOTAL
9.96 4.49 0.68 13.92 71.27 1.73 128.5 5,836 4,356 1.97 4.16 2,319 644 140 642 4,140 1.79 0.44 6.73 1,586 49.5 0.92 0.15 48.5 8.8 22.5 22.3 0.24 30.5 7.89 1.11 21.1 23.2 98.1 65.9 291 453 103 434 1,329 325 2,998 703 324 70.6 49.2 3.7 1.56 27394.41
0.2 0.12 <0.01 0.57 22.13 0.16 83.28 64.06 17.12 <0.02 0.79 7.14 1.96 0.5 13.86 13.67 0.04 0.08 0.04 1.77 0.15 0.52 0.14 8.27 0.22 1.47 1.82 0.09 0.63 2.1 0.65 2.65 5.83 8.29 6.85 2.11 1.07 2.68 2.08 3.4 0.29 0.35 0.6 0.65 0.17 0.06 0.07 0.05 296.53
Dr. David Stone, ANSTO
2
© Anotec Pty Limited 2001
Industrial Emissions - Efficacy Testing for Anotec Odour Control
COMPONENT (ppb) 1-chloro-1, 1 difluroethane Dimethyl sulfide Dimethyl disulfide Carbon disulfide Sulfur dioxide Carbonyl sulfide Acetaldehyde Methanol Ethanol i-propanol t-butanol Acetone 2-butanone 3-buten-2-one Ethyl acetate 2-methyl propanol Butanal Hexanal Pyrrolidine Propane Methyl propane Butane Methyl butane Pentane 2-methyl pentane 3-methyl pentane Hexane Benzene Methyl cyclopentane Cyclo hexane Methyl hexane Heptane
RAW ODOUR 2314.9 0.3 0.2 6.2 6.6 11.3 249.1 40 85.6 8.2 22.8 121.3 93.7 5.1 3.9 1.3 40.6 19 43.3 47.9 85.1 10.4 5.58 25.9 5.23 280.3 174.9 4.1 7.84 17.25 261.8 73.8
ANOTEC
% REMOVAL
109.3 0.1 0.1 0.47 0.9 3.7 5 9.2 19.8 1.7 4.5 14.5 17.1 1 1 0.05 6.3 2 5 12.1 22.1 0.9 0.57 1.1 0.57 52.1 2.2 0.32 0.8 0.7 25.31 11.5
95.28 66.00 50.00 92.42 86.36 67.26 97.99 77.00 76.87 79.27 80.26 88.05 81.75 80.39 74.36 96.15 84.48 89.47 88.45 74.74 74.03 91.35 89.78 95.75 89.10 81.41 98.74 92.20 89.80 95.94 90.33 84.42
* Average removal efficiency >84.35% Dr. David Stone, ANSTO
3
© Anotec Pty Limited 2001
Jewellery Manufacture / Solvents Efficacy Testing for Anotec Odour Component (ppb)
Direct Spray
ethyl acrylate
Ambient 112
2.2
11
0.4
acetone
1301
16.1
hexane
120
3.2
ethanol
66
4.9
i-butanol
1367
8.5
butanol
1160
5.5
2-butanone
234
22.3
methyl isobutylketone
160
0.7
methylfuran
2.39
0
28
8
toluene
1179
21.5
ethyl benzene
2464
3
m- and p- xylene
7238
6.7
o-xylene
2983
2.1
chloroform
1824
22.5
1,1,1-trichloroethane
11.64
0.2
tetrachloromethane
7.89
2.1
trichloroethane
4283
375
381
3.5
24932.92
508.4
methyl methacrylate
benzene
tetrachloroethane TOTAL
Dr. David Stone, ANSTO
4
© Anotec Pty Limited 2001
MEK - Efficacy Testing for Anotec Odour Control COMPONENT (ppb) acetaldehyde methanol ethanol i-propanol t-butanol acetone 2-butanone 3-buten-2-one ethyl acetate 2-methyl propanol butanal hexanal benzene toluene ethyl benzene m-and p- xylene o-xylene dichloro methane trichlorofluoromethane 11,2-trichloro-a,2,2trichloroethane bromodichloromethane
RAW 480.5 35 93.2 15.6 25.4 132.2 103.8 10.2 8.1 6.9 52 41 6.2 18.3 4.25 5.9 0.32 8.7 0.59 0.45
TREATED with ANOTEC 0307 7.9 2 11.3 0.1 3.1 10.3 12 0.1 0.1 0.2 3.3 1 0.1 0.8 0.1 0.72 0 0.05 0.01 0.09
0.6
0.02
Dr. David Stone, ANSTO
5
© Anotec Pty Limited 2001
Phosphate Plant - Efficacy Testing for Anotec Odour Control
COMPONENT (ppm) Sulfur dioxide Carbonyl sulfide Carbon disulfide Dimethyl sulfide Methyl ethyl disulfide Methyl propyl disulfide Methyl mercaptan Methyl ethyl sulfide Methyl isopropyl sulfide Methyl propyl sulfide Difluoro dimethyl silane Iodomethane 2-methyl propanol 2-methyl 2-propenal Butanal Furan 2-methyl furan Acetone 3-buten-2-one 2,3-butanedione 2-butanone Methanol Ethanol i-propanol Propanol 2-methyl pentane 3-methyl pentane Hexane Methyl cyclopentane 2-methyl hexane Heptane Methyl cyclohexane Toluene Ethyl benzene m,p xylenes o xylenes Trimethyl cyclohexanes Octane Nonane C8-11 alkanes
RAW ODOUR 1.1 2.2 0.05 1.9 0.01 0.02 0.26 0.7 0.2 0.01 0.7 0.04 0.3 2.6 0.06 2.1 0.6 9 4.7 0.5 1.7 32 9.1 2.8 0.4 3.8 2.5 4.7 1.5 0.5 1.9 1.6 1.3 0.3 0.7 1.3 0.4 0.2 0.3 1.3
ANOTEC
% REMOVAL
0.25 1 0.008 0.6 0.002 0.003 0.04 0.009 0.003 0.001 0.3 0.01 0.06 0.9 0.04 0.9 0.07 2.8 0.1 0.04 0.3 2 1 0.9 0.2 0.9 1.03 0.9 0.8 0.09 0.3 0.5 0.3 0.1 0.004 0.6 0.2 0.2 0.1 0.9
77.27 54.55 84 68.42 80 85 85 98.71 98.5 90 57 75 80 65.38 33.33 57.14 88.33 68.89 97.87 92 82.35 93.75 89.01 67.86 50 76.31 58.8 80.85 46.67 82 84.21 68.75 76.92 66.67 99.42 53.84 50 66.67 30.77
Dr. David Stone, ANSTO
6
© Anotec Pty Limited 2001
Plastic Moulding Factory -Efficacy Testing for Anotec Odour Control COMPOUND
RAW
TREATED
2314.9
652.6
dimethyl sulfide
0.3
0.1
dimethyl disulfide
0.2
0.1
carbondisulphide
6.2
4.7
sulfur dioxide
6.6
0.9
carbonyl sulfide
11.3
3.7
acetaldehyde
249.1
10
40
20.2
ethanol
85.6
36.7
i-propanol
8.2
2.7
t-butanol
22.8
4.5
acetone
121.3
37.2
2-butanone
93.7
17.1
3-buten-2-one
5.1
1
ethylacetate
3.9
1
2-methylpropanal
1.3
0.7
butanal
40.6
11.8
hexanal
19
9
pyrrolidine
43.3
8
propane
47.9
16.7
methylpropane
85.1
35.5
butane
10.4
3.8
methylbutane
5.58
0.57
pentane
25.9
3.21
1-chloro-1,1-difluoroethane
methanol
2-methylpentane
5.23
3.28
3-methylpentane
280.3
102.1
hexane
174.9
50.5
benzene
4.1
1.14
methylcyclopentane
7.84
2.93
cyclohexane
17.25
5.46
methylhexanes
261.8
63.6
heptane
73.8
15.4
methylcyclohexane
1.86
0.96
branched C7 alkanes
29.5
5.9
branched C8 alkanes
158.9
33.2
octane
34
6.18
nonane
3.29
0.25
branched C9 alkanes
164.1
34.9
toluene
10.1
2.92
ethylbenzene
3.46
0.88
m-and p-xylene
2.26
0.69
o-xylene
0.64
0.14
7
© Anotec Pty Limited 2001
Plastic Moulding Factory -Efficacy Testing for Anotec Odour Control
COMPOUND
RAW
TREATED
dichloromethane
4.3
2.78
trichlorofluoromethane
0.86
0.33
1,1,2-trichloro-1,2,2-trifluoroeth
0.34
0.11
bromodichloromethane
0.13
0.03
1,1-dichloroethane
0.65
0.64
1,2-dichloroethene
0.04
0.03
chloroform
3.08
2.81
tetrachloromethane
0.27
0.21
tetrachloroethene
0.06
0.02
2314.9
652.6
dimethyl sulfide
0.3
0.1
dimethyl disulfide
0.2
0.1
carbon disulfide
6.2
4.7
sulfur dioxide
6.6
0.9
carbonyl sulfide
11.3
3.7
acetaldehyde
249.1
10
40
20.2
85.6
36.7
1-chloro-1, 1 difluroethane
methanol ethanol i-propanol
8.2
2.7
t-butanol
22.8
4.5
acetone
121.3
37.2
2-butanone
93.7
17.1
3-buten-2-one
5.1
1
ethyl acetate
3.9
1
2-methyl propanol
1.3
0.7
butanal
40.6
11.8
hexanal
19
9
pyrrolidine
43.3
8
propane
47.9
16.7
methyl propane
85.1
35.5
butane
10.4
3.8
methyl butane
5.58
0.57
pentane
25.9
3.21
2-methyl pentane
5.23
3.28
3-methyl pentane
280.3
102.1
hexane
174.9
50.5
benzene
4.1
1.14
methyl cyclopentane
7.84
2.93
cyclo hexane
17.25
5.46
methylhexanes
261.8
63.6
8
© Anotec Pty Limited 2001
heptane
73.8
15.4
methylcyclohexane
1.86
0.96
branched C7 alkanes
29.5
5.9
branched C8 alkanes
158.9
33.2
octane
34
6.18
nonane
3.29
0.25
branched C9 alkanes
164.1
34.9
10
2.92
toluene ethyl benzene
3.46
0.88
m-and p- xylene
2.26
0.69
o-xylene
0.64
0.14
dichloro methane
4.3
2.78
trichlorofluoromethane
0.86
0.33
11,2-trichloro-a,2,2trichloroethane bromodichloromethane
0.34
0.11
0.13
0.03
1,1-dichloroethane
0.65
0.64
1,2-dichloroethene
0.04
0.03
chloroform
3.08
2.81
tetrachloromethane
0.27
0.21
tetrachloroethene
0.06
0.02
4491.2
1219.17
TOTAL
Dr. David Stone, ANSTO
9
© Anotec Pty Limited 2001
Poultry Farm - Efficacy Testing for Anotec Odour Control COMPONENT (ppm) Hydrogen sulfide Methyl mercaptan Carbonylsulfide Sulfur dioxide Dimethyl sulfide Acetaldehyde Butanal Methanol Ethanol i-propanol Acetone Ethylacetate Methylamine Trimethylamine & Ammonia Urea Benzene C8-C9 alkanes Cyclohexane Valeryl acetates Pinenes
RAW ODOUR <0.02 0.2 37.96 <0.01 2.24 26.32 3.12 2.42 128.63 116.25 396.12 1.85 3.2 2.96 23.62 11.12 0.51 1.65 52.48 52.48
ANOTEC
% REMOVAL
<0.001 <0.001 0.52 <0.001 <0.001 0.98 0.23 0.05 2.3 1.98 3.45 0.75 <0.05 <0.05 1.32 0.98 <0.001 <0.05 3.56 3.56
95 99.86 98.63 90 99.95 96.27 92.62 97.93 98.21 98.29 98.12 59.62 98.43 98.31 94.41 91.18 99.83 96.96 95.71 93.21
Dr. David Stone, ANSTO
10
© Anotec Pty Limited 2001
SEWAGE PUMPING STATION - STACK EMISSIONS ODOUR ANALYSIS
Anotec Pty Ltd. Component (ppb) Hydrogen Sulfide Sulfur dioxide Methyl mercaptan Dimethyl sulfide Ethyl mercaptan Carbon disulfide Carbonyl sulfide Propyl mercaptan Calculated Odour Strength (ODU) Component
Hydrogen Sulfide Sulfur dioxide Methyl mercaptan Dimethyl sulfide Ethyl mercaptan Carbon disulfide Propyl mercaptan
Raw Odour 1316 2 625.5 179.3 0.4 27.1 66 1.7
Odour Threshold (ppb) 0.3 0.1 0.9 0.2 20 100 0.2
Treated with Anotec 0307 1.8 0 0.3 1.6 0 3.9 9.1 0
Odour Removal Efficiency (%) 99.86 99.96 99.10 85.60 86.60
Raw Odour (Untreated)
Anotec 0307 (Treated)
4387 6255 199 2 1 <0.5 9
6 3 2 0 <0.5 <0.5 0
Dr. David Stone, ANSTO
11
© Anotec Pty Limited 2001
Sewage Stack Testing - Efficacy Testing for Anotec Odour Control
COMPONENT (ppm) 1,1,1 trichloroethane 2-methyl pentane 2-methylbutane 3-methyl pentane Acetone Benzene C3-alkylbenzenes C7-C11 alkanes Carbon disulfide Carbonyl sulfide Chloroform Cyclohexane Dimethyl sulfide Heptane Hexane Hydrogen sulfide Limonene Methylamine Ammonia *Kitagawa m,p xylene Methyl cyclohexane Methyl cyclopentane Methyl hexanes Methyl mercaptan Nonane o-xylene
RAW ODOUR 1 2 0.7 9 3 2 4.2 58.26 1.07 3 3.67 1 7 2 7 31 0.7 4.2 7 5 3 5 13 13 3 2
ANOTEC
% REMOVAL
<0.001 <0.001 0.03 <0.001 <0.001 <0.001 0.015 9.2 0.02 <0.001 0.65 <0.001 0.06 <0.001 0.95 2.4 <0.001 <0.05 1 0.2 <0.001 <0.001 0.96 1.09 <0.001 <0.001
99.9 99.95 95.71 99.99 99.97 99.95 99.64 84.20 98.13 99.96 82.29 99.9 99.14 99.95 86.43 92.26 99.86 98.81 85.71 96 99.97 99.98 92.62 91.62 99.97 99.95
Dr. David Stone, ANSTO
12
© Anotec Pty Limited 2001
Taree Sewage Treatment- Pipe Efficacy Testing for Anotec Odour
Components (ppb) Hydrogen sulfide Sulfur dioxide Methyl mercaptan di-methyl sulfide carbon disulfide carbonyl sulfide di-methyl di-sulfide i-propylmercaptan propylmercaptan s-butyl mercaptan i-butylmercaptan
PVC PIPE INTO AIRVAC 1536 9.8 1254.2 384.9 49.3 124.3 70.9 6.6 1.6 49.7 11.5
Anotec 79.9 1 2.6 101.6 9.2 13.7 17.9 0.2 0.2 1.7 0.1
Dr. David Stone, ANSTO
13
© Anotec Pty Limited 2001
Efficacy Testing for Anotec Odour Control
COMPONENT (ppb)
RAW
1-chloro-1, 1 difluroethane dimethyl sulfide dimethyl disulfide carbon disulfide sulfur dioxide carbonyl sulfide acetaldehyde methanol ethanol i-propanol t-butanol acetone 2-butanone 3-buten-2-one ethyl acetate 2-methyl propanol butanal hexanal pyrrolidine propane methyl propane butane methyl butane pentane 2-methyl pentane 3-methyl pentane hexane benzene methyl cyclopentane cyclo hexane methylhexanes heptane methylcyclohexane branched C7 alkanes branched C8 alkanes octane nonane branched C9 alkanes toluene ethyl benzene m-and p- xylene o-xylene dichloro methane trichlorofluoromethane 11,2-trichloro-a,2,2-trichloroethane bromodichloromethane 1,1-dichloroethane 1,2-dichloroethene chloroform tetrachloromethane tetrachloroethene
2314.9 0.3 0.2 6.2 6.6 11.3 249.1 40 85.6 8.2 22.8 121.3 93.7 5.1 3.9 1.3 40.6 19 43.3 47.9 85.1 10.4 5.58 25.9 5.23 280.3 174.9 4.1 7.84 17.25 261.8 73.8 1.86 29.5 158.9 34 3.29 164.1 10 3.46 2.26 0.64 4.3 0.86 0.34 0.13 0.65 0.04 3.08 0.27 0.06
14
TREATED with ANOTEC 0307 109.3 0.1 0.1 4.7 0.9 3.7 5 9.2 19.8 1.7 4.5 14.5 17.1 1 1 0.7 6.3 2 5 12.1 22.1 0.9 0.57 1.1 0.57 52.1 22 0.32 0.8 0.7 25.31 11.5 0.32 5.9 33.2 4.18 0.25 14.9 1.92 0.88 0.69 0.14 0.078 0.33 0.11 0.03 0.04 0.02 0.81 0.01 0.02 Dr. David Stone, ANSTO
© Anotec Pty Limited 2001
SIMULATED WIND TUNNEL ANALYSIS FOR SEWAGE GAS ODOURS
.
Anotec Pty Ltd. Component (ppm)
Raw Odour
Treated with Anotec 0307
Treated with Anotec 0307 + Fragrant Signature 0.000 0.000 <0.05 0.26 0.32
Hydrogen Sulfide Acetaldehyde Methylamine 2-butenal Butanol
0.566 9.181 3 5.63 40.54
0.000 0.000 <0.05 0.77 0.79
ODOUR (OU) Hydrogen Sulfide Acetaldehyde Methylamine 2-butenal Butanol
2832.35 1636.36 300 938.29 506.76
0 0 0 128.37 9.84
0 0 0 43.91 4.02
TOTAL ODOUR
6214
139
48
Dr. David Stone, ANSTO
15
© Anotec Pty Limited 2001
CLIENT:
Anotec Pty Limited (Contact: Ms. Victoria Zavras) _______________________________________
LOCATION: McCains Furniture - Lewisham _______________________________________ ODOUR SOURCE
ODOUR DILUTION UNIT (ODU)*
Exhaust Stack Solvent Emissions - Raw Odour: Inlet
55,000
Exhaust Stack Solvent Emissions - Treated with Anotec Odour Control
2050
T.J. Schulz. Manager
16
© Anotec Pty Limited 2001
CLIENT:
Anotec Pty Limited (Contact: Chief Chemist) _______________________________________
LOCATION: Plastics Factory - St. Peters _______________________________________ ODOUR SOURCE
ODOUR DILUTION UNIT (ODU)*
Oven - Raw Odour: Inlet
43,228
Oven - Treated with Anotec Odour Control
1,236
T.J. Schulz. Manager
17
© Anotec Pty Limited 2001
CLIENT:
Anotec Pty Limited (Contact: Victoria - Director) _______________________________________
LOCATION: Taree Sewage Treatment Plant _______________________________________ ODOUR SOURCE
ODOUR DILUTION UNIT (ODU)*
Digester - Raw Odour: Inlet
94,235
Digester - Treated with Anotec Odour Control
1284
T.J. Schulz. Manager
18
© Anotec Pty Limited 2001
CLIENT:
Anotec Pty Limited (Contact: Ms. Victoria Zavras Director) _______________________________________
LOCATION: Poultry Shed – Wollondilly Council _______________________________________ ODOUR SOURCE
ODOUR DILUTION UNIT (ODU)*
Raw Odour: Inlet
22,569
Outlet - Treated with Anotec Odour Control
894
T.J. Schulz. Manager
19
© Anotec Pty Limited 2001
CLIENT:
Anotec Pty Limited (Contact: Ms. Victoria Zavras) _______________________________________
LOCATION: Laboratory Testing _______________________________________ ODOUR SOURCE
ODOUR DILUTION UNIT (ODU)*
Sewage Stack - Raw Odour: Inlet
18227
Sewage Stack - Treated with WATER only
4092
Sewage Stack - Treated with Anotec Odour Control
1736
T.J. Schulz. Manager
20
© Anotec Pty Limited 2001
CONFIDENTIAL & PRIVATE - NOT FOR DISTRIBUTION ALL INFORMATION CONTAINED HEREIN REMAINS THE PROPERTY OF ANOTEC PTY LIMITED © 2001
21
© Anotec Pty Limited 2001
© Anotec Pty Limited 2001
Furniture Manufacturing FactoryEfficacy Testing for Anotec Odour Control COMPOUND (ppb)
STACK
ANOTEC
carbonylsulphide sulphurdioxide dimethylsulphide carbondisulphide acetaldehyde 2-methylpropanal methanol ethanol i-propanol propanol t-butanol i-butanol butanol 3-methylbutanol acetone 2-butanone 3-buten-2-one 2,3-butandione methylisobutylketone ethylacetate butylacetate freon 11 freon 113 dichloromethane 1,2-dichloroethane chloroform 1,1,1-trichloroethane carbontetrachloride trichloroethylene i-pentane pentane 2-methylpentane 3-methylpentane hexane benzene methylhexanes heptane methylcyclopentane cyclohexane methylcyclohexane octane toluene ethylbenzene m,p-xylenes o-xylenes nonane decane undecane TOTAL
9.96 4.49 0.68 13.92 71.27 1.73 128.5 5,836 4,356 1.97 4.16 2,319 644 140 642 4,140 1.79 0.44 6.73 1,586 49.5 0.92 0.15 48.5 8.8 22.5 22.3 0.24 30.5 7.89 1.11 21.1 23.2 98.1 65.9 291 453 103 434 1,329 325 2,998 703 324 70.6 49.2 3.7 1.56 27394.41
0.2 0.12 <0.01 0.57 22.13 0.16 83.28 64.06 17.12 <0.02 0.79 7.14 1.96 0.5 13.86 13.67 0.04 0.08 0.04 1.77 0.15 0.52 0.14 8.27 0.22 1.47 1.82 0.09 0.63 2.1 0.65 2.65 5.83 8.29 6.85 2.11 1.07 2.68 2.08 3.4 0.29 0.35 0.6 0.65 0.17 0.06 0.07 0.05 296.53
Dr. David Stone, ANSTO
2
© Anotec Pty Limited 2001
Industrial Emissions - Efficacy Testing for Anotec Odour Control
COMPONENT (ppb) 1-chloro-1, 1 difluroethane Dimethyl sulfide Dimethyl disulfide Carbon disulfide Sulfur dioxide Carbonyl sulfide Acetaldehyde Methanol Ethanol i-propanol t-butanol Acetone 2-butanone 3-buten-2-one Ethyl acetate 2-methyl propanol Butanal Hexanal Pyrrolidine Propane Methyl propane Butane Methyl butane Pentane 2-methyl pentane 3-methyl pentane Hexane Benzene Methyl cyclopentane Cyclo hexane Methyl hexane Heptane
RAW ODOUR 2314.9 0.3 0.2 6.2 6.6 11.3 249.1 40 85.6 8.2 22.8 121.3 93.7 5.1 3.9 1.3 40.6 19 43.3 47.9 85.1 10.4 5.58 25.9 5.23 280.3 174.9 4.1 7.84 17.25 261.8 73.8
ANOTEC
% REMOVAL
109.3 0.1 0.1 0.47 0.9 3.7 5 9.2 19.8 1.7 4.5 14.5 17.1 1 1 0.05 6.3 2 5 12.1 22.1 0.9 0.57 1.1 0.57 52.1 2.2 0.32 0.8 0.7 25.31 11.5
95.28 66.00 50.00 92.42 86.36 67.26 97.99 77.00 76.87 79.27 80.26 88.05 81.75 80.39 74.36 96.15 84.48 89.47 88.45 74.74 74.03 91.35 89.78 95.75 89.10 81.41 98.74 92.20 89.80 95.94 90.33 84.42
* Average removal efficiency >84.35% Dr. David Stone, ANSTO
3
© Anotec Pty Limited 2001
Jewellery Manufacture / Solvents Efficacy Testing for Anotec Odour Component (ppb)
Direct Spray
ethyl acrylate
Ambient 112
2.2
11
0.4
acetone
1301
16.1
hexane
120
3.2
ethanol
66
4.9
i-butanol
1367
8.5
butanol
1160
5.5
2-butanone
234
22.3
methyl isobutylketone
160
0.7
methylfuran
2.39
0
28
8
toluene
1179
21.5
ethyl benzene
2464
3
m- and p- xylene
7238
6.7
o-xylene
2983
2.1
chloroform
1824
22.5
1,1,1-trichloroethane
11.64
0.2
tetrachloromethane
7.89
2.1
trichloroethane
4283
375
381
3.5
24932.92
508.4
methyl methacrylate
benzene
tetrachloroethane TOTAL
Dr. David Stone, ANSTO
4
© Anotec Pty Limited 2001
MEK - Efficacy Testing for Anotec Odour Control COMPONENT (ppb) acetaldehyde methanol ethanol i-propanol t-butanol acetone 2-butanone 3-buten-2-one ethyl acetate 2-methyl propanol butanal hexanal benzene toluene ethyl benzene m-and p- xylene o-xylene dichloro methane trichlorofluoromethane 11,2-trichloro-a,2,2trichloroethane bromodichloromethane
RAW 480.5 35 93.2 15.6 25.4 132.2 103.8 10.2 8.1 6.9 52 41 6.2 18.3 4.25 5.9 0.32 8.7 0.59 0.45
TREATED with ANOTEC 0307 7.9 2 11.3 0.1 3.1 10.3 12 0.1 0.1 0.2 3.3 1 0.1 0.8 0.1 0.72 0 0.05 0.01 0.09
0.6
0.02
Dr. David Stone, ANSTO
5
© Anotec Pty Limited 2001
Phosphate Plant - Efficacy Testing for Anotec Odour Control
COMPONENT (ppm) Sulfur dioxide Carbonyl sulfide Carbon disulfide Dimethyl sulfide Methyl ethyl disulfide Methyl propyl disulfide Methyl mercaptan Methyl ethyl sulfide Methyl isopropyl sulfide Methyl propyl sulfide Difluoro dimethyl silane Iodomethane 2-methyl propanol 2-methyl 2-propenal Butanal Furan 2-methyl furan Acetone 3-buten-2-one 2,3-butanedione 2-butanone Methanol Ethanol i-propanol Propanol 2-methyl pentane 3-methyl pentane Hexane Methyl cyclopentane 2-methyl hexane Heptane Methyl cyclohexane Toluene Ethyl benzene m,p xylenes o xylenes Trimethyl cyclohexanes Octane Nonane C8-11 alkanes
RAW ODOUR 1.1 2.2 0.05 1.9 0.01 0.02 0.26 0.7 0.2 0.01 0.7 0.04 0.3 2.6 0.06 2.1 0.6 9 4.7 0.5 1.7 32 9.1 2.8 0.4 3.8 2.5 4.7 1.5 0.5 1.9 1.6 1.3 0.3 0.7 1.3 0.4 0.2 0.3 1.3
ANOTEC
% REMOVAL
0.25 1 0.008 0.6 0.002 0.003 0.04 0.009 0.003 0.001 0.3 0.01 0.06 0.9 0.04 0.9 0.07 2.8 0.1 0.04 0.3 2 1 0.9 0.2 0.9 1.03 0.9 0.8 0.09 0.3 0.5 0.3 0.1 0.004 0.6 0.2 0.2 0.1 0.9
77.27 54.55 84 68.42 80 85 85 98.71 98.5 90 57 75 80 65.38 33.33 57.14 88.33 68.89 97.87 92 82.35 93.75 89.01 67.86 50 76.31 58.8 80.85 46.67 82 84.21 68.75 76.92 66.67 99.42 53.84 50 66.67 30.77
Dr. David Stone, ANSTO
6
© Anotec Pty Limited 2001
Plastic Moulding Factory -Efficacy Testing for Anotec Odour Control COMPOUND
RAW
TREATED
2314.9
652.6
dimethyl sulfide
0.3
0.1
dimethyl disulfide
0.2
0.1
carbondisulphide
6.2
4.7
sulfur dioxide
6.6
0.9
carbonyl sulfide
11.3
3.7
acetaldehyde
249.1
10
40
20.2
ethanol
85.6
36.7
i-propanol
8.2
2.7
t-butanol
22.8
4.5
acetone
121.3
37.2
2-butanone
93.7
17.1
3-buten-2-one
5.1
1
ethylacetate
3.9
1
2-methylpropanal
1.3
0.7
butanal
40.6
11.8
hexanal
19
9
pyrrolidine
43.3
8
propane
47.9
16.7
methylpropane
85.1
35.5
butane
10.4
3.8
methylbutane
5.58
0.57
pentane
25.9
3.21
1-chloro-1,1-difluoroethane
methanol
2-methylpentane
5.23
3.28
3-methylpentane
280.3
102.1
hexane
174.9
50.5
benzene
4.1
1.14
methylcyclopentane
7.84
2.93
cyclohexane
17.25
5.46
methylhexanes
261.8
63.6
heptane
73.8
15.4
methylcyclohexane
1.86
0.96
branched C7 alkanes
29.5
5.9
branched C8 alkanes
158.9
33.2
octane
34
6.18
nonane
3.29
0.25
branched C9 alkanes
164.1
34.9
toluene
10.1
2.92
ethylbenzene
3.46
0.88
m-and p-xylene
2.26
0.69
o-xylene
0.64
0.14
7
© Anotec Pty Limited 2001
Plastic Moulding Factory -Efficacy Testing for Anotec Odour Control
COMPOUND
RAW
TREATED
dichloromethane
4.3
2.78
trichlorofluoromethane
0.86
0.33
1,1,2-trichloro-1,2,2-trifluoroeth
0.34
0.11
bromodichloromethane
0.13
0.03
1,1-dichloroethane
0.65
0.64
1,2-dichloroethene
0.04
0.03
chloroform
3.08
2.81
tetrachloromethane
0.27
0.21
tetrachloroethene
0.06
0.02
2314.9
652.6
dimethyl sulfide
0.3
0.1
dimethyl disulfide
0.2
0.1
carbon disulfide
6.2
4.7
sulfur dioxide
6.6
0.9
carbonyl sulfide
11.3
3.7
acetaldehyde
249.1
10
40
20.2
85.6
36.7
1-chloro-1, 1 difluroethane
methanol ethanol i-propanol
8.2
2.7
t-butanol
22.8
4.5
acetone
121.3
37.2
2-butanone
93.7
17.1
3-buten-2-one
5.1
1
ethyl acetate
3.9
1
2-methyl propanol
1.3
0.7
butanal
40.6
11.8
hexanal
19
9
pyrrolidine
43.3
8
propane
47.9
16.7
methyl propane
85.1
35.5
butane
10.4
3.8
methyl butane
5.58
0.57
pentane
25.9
3.21
2-methyl pentane
5.23
3.28
3-methyl pentane
280.3
102.1
hexane
174.9
50.5
benzene
4.1
1.14
methyl cyclopentane
7.84
2.93
cyclo hexane
17.25
5.46
methylhexanes
261.8
63.6
8
© Anotec Pty Limited 2001
heptane
73.8
15.4
methylcyclohexane
1.86
0.96
branched C7 alkanes
29.5
5.9
branched C8 alkanes
158.9
33.2
octane
34
6.18
nonane
3.29
0.25
branched C9 alkanes
164.1
34.9
10
2.92
toluene ethyl benzene
3.46
0.88
m-and p- xylene
2.26
0.69
o-xylene
0.64
0.14
dichloro methane
4.3
2.78
trichlorofluoromethane
0.86
0.33
11,2-trichloro-a,2,2trichloroethane bromodichloromethane
0.34
0.11
0.13
0.03
1,1-dichloroethane
0.65
0.64
1,2-dichloroethene
0.04
0.03
chloroform
3.08
2.81
tetrachloromethane
0.27
0.21
tetrachloroethene
0.06
0.02
4491.2
1219.17
TOTAL
Dr. David Stone, ANSTO
9
© Anotec Pty Limited 2001
Poultry Farm - Efficacy Testing for Anotec Odour Control COMPONENT (ppm) Hydrogen sulfide Methyl mercaptan Carbonylsulfide Sulfur dioxide Dimethyl sulfide Acetaldehyde Butanal Methanol Ethanol i-propanol Acetone Ethylacetate Methylamine Trimethylamine & Ammonia Urea Benzene C8-C9 alkanes Cyclohexane Valeryl acetates Pinenes
RAW ODOUR <0.02 0.2 37.96 <0.01 2.24 26.32 3.12 2.42 128.63 116.25 396.12 1.85 3.2 2.96 23.62 11.12 0.51 1.65 52.48 52.48
ANOTEC
% REMOVAL
<0.001 <0.001 0.52 <0.001 <0.001 0.98 0.23 0.05 2.3 1.98 3.45 0.75 <0.05 <0.05 1.32 0.98 <0.001 <0.05 3.56 3.56
95 99.86 98.63 90 99.95 96.27 92.62 97.93 98.21 98.29 98.12 59.62 98.43 98.31 94.41 91.18 99.83 96.96 95.71 93.21
Dr. David Stone, ANSTO
10
© Anotec Pty Limited 2001
SEWAGE PUMPING STATION - STACK EMISSIONS ODOUR ANALYSIS
Anotec Pty Ltd. Component (ppb) Hydrogen Sulfide Sulfur dioxide Methyl mercaptan Dimethyl sulfide Ethyl mercaptan Carbon disulfide Carbonyl sulfide Propyl mercaptan Calculated Odour Strength (ODU) Component
Hydrogen Sulfide Sulfur dioxide Methyl mercaptan Dimethyl sulfide Ethyl mercaptan Carbon disulfide Propyl mercaptan
Raw Odour 1316 2 625.5 179.3 0.4 27.1 66 1.7
Odour Threshold (ppb) 0.3 0.1 0.9 0.2 20 100 0.2
Treated with Anotec 0307 1.8 0 0.3 1.6 0 3.9 9.1 0
Odour Removal Efficiency (%) 99.86 99.96 99.10 85.60 86.60
Raw Odour (Untreated)
Anotec 0307 (Treated)
4387 6255 199 2 1 <0.5 9
6 3 2 0 <0.5 <0.5 0
Dr. David Stone, ANSTO
11
© Anotec Pty Limited 2001
Sewage Stack Testing - Efficacy Testing for Anotec Odour Control
COMPONENT (ppm) 1,1,1 trichloroethane 2-methyl pentane 2-methylbutane 3-methyl pentane Acetone Benzene C3-alkylbenzenes C7-C11 alkanes Carbon disulfide Carbonyl sulfide Chloroform Cyclohexane Dimethyl sulfide Heptane Hexane Hydrogen sulfide Limonene Methylamine Ammonia *Kitagawa m,p xylene Methyl cyclohexane Methyl cyclopentane Methyl hexanes Methyl mercaptan Nonane o-xylene
RAW ODOUR 1 2 0.7 9 3 2 4.2 58.26 1.07 3 3.67 1 7 2 7 31 0.7 4.2 7 5 3 5 13 13 3 2
ANOTEC
% REMOVAL
<0.001 <0.001 0.03 <0.001 <0.001 <0.001 0.015 9.2 0.02 <0.001 0.65 <0.001 0.06 <0.001 0.95 2.4 <0.001 <0.05 1 0.2 <0.001 <0.001 0.96 1.09 <0.001 <0.001
99.9 99.95 95.71 99.99 99.97 99.95 99.64 84.20 98.13 99.96 82.29 99.9 99.14 99.95 86.43 92.26 99.86 98.81 85.71 96 99.97 99.98 92.62 91.62 99.97 99.95
Dr. David Stone, ANSTO
12
© Anotec Pty Limited 2001
Taree Sewage Treatment- Pipe Efficacy Testing for Anotec Odour
Components (ppb) Hydrogen sulfide Sulfur dioxide Methyl mercaptan di-methyl sulfide carbon disulfide carbonyl sulfide di-methyl di-sulfide i-propylmercaptan propylmercaptan s-butyl mercaptan i-butylmercaptan
PVC PIPE INTO AIRVAC 1536 9.8 1254.2 384.9 49.3 124.3 70.9 6.6 1.6 49.7 11.5
Anotec 79.9 1 2.6 101.6 9.2 13.7 17.9 0.2 0.2 1.7 0.1
Dr. David Stone, ANSTO
13
© Anotec Pty Limited 2001
Efficacy Testing for Anotec Odour Control
COMPONENT (ppb)
RAW
1-chloro-1, 1 difluroethane dimethyl sulfide dimethyl disulfide carbon disulfide sulfur dioxide carbonyl sulfide acetaldehyde methanol ethanol i-propanol t-butanol acetone 2-butanone 3-buten-2-one ethyl acetate 2-methyl propanol butanal hexanal pyrrolidine propane methyl propane butane methyl butane pentane 2-methyl pentane 3-methyl pentane hexane benzene methyl cyclopentane cyclo hexane methylhexanes heptane methylcyclohexane branched C7 alkanes branched C8 alkanes octane nonane branched C9 alkanes toluene ethyl benzene m-and p- xylene o-xylene dichloro methane trichlorofluoromethane 11,2-trichloro-a,2,2-trichloroethane bromodichloromethane 1,1-dichloroethane 1,2-dichloroethene chloroform tetrachloromethane tetrachloroethene
2314.9 0.3 0.2 6.2 6.6 11.3 249.1 40 85.6 8.2 22.8 121.3 93.7 5.1 3.9 1.3 40.6 19 43.3 47.9 85.1 10.4 5.58 25.9 5.23 280.3 174.9 4.1 7.84 17.25 261.8 73.8 1.86 29.5 158.9 34 3.29 164.1 10 3.46 2.26 0.64 4.3 0.86 0.34 0.13 0.65 0.04 3.08 0.27 0.06
14
TREATED with ANOTEC 0307 109.3 0.1 0.1 4.7 0.9 3.7 5 9.2 19.8 1.7 4.5 14.5 17.1 1 1 0.7 6.3 2 5 12.1 22.1 0.9 0.57 1.1 0.57 52.1 22 0.32 0.8 0.7 25.31 11.5 0.32 5.9 33.2 4.18 0.25 14.9 1.92 0.88 0.69 0.14 0.078 0.33 0.11 0.03 0.04 0.02 0.81 0.01 0.02 Dr. David Stone, ANSTO
© Anotec Pty Limited 2001
SIMULATED WIND TUNNEL ANALYSIS FOR SEWAGE GAS ODOURS
.
Anotec Pty Ltd. Component (ppm)
Raw Odour
Treated with Anotec 0307
Treated with Anotec 0307 + Fragrant Signature 0.000 0.000 <0.05 0.26 0.32
Hydrogen Sulfide Acetaldehyde Methylamine 2-butenal Butanol
0.566 9.181 3 5.63 40.54
0.000 0.000 <0.05 0.77 0.79
ODOUR (OU) Hydrogen Sulfide Acetaldehyde Methylamine 2-butenal Butanol
2832.35 1636.36 300 938.29 506.76
0 0 0 128.37 9.84
0 0 0 43.91 4.02
TOTAL ODOUR
6214
139
48
Dr. David Stone, ANSTO
15
© Anotec Pty Limited 2001
CLIENT:
Anotec Pty Limited (Contact: Ms. Victoria Zavras) _______________________________________
LOCATION: McCains Furniture - Lewisham _______________________________________ ODOUR SOURCE
ODOUR DILUTION UNIT (ODU)*
Exhaust Stack Solvent Emissions - Raw Odour: Inlet
55,000
Exhaust Stack Solvent Emissions - Treated with Anotec Odour Control
2050
T.J. Schulz. Manager
16
© Anotec Pty Limited 2001
CLIENT:
Anotec Pty Limited (Contact: Chief Chemist) _______________________________________
LOCATION: Plastics Factory - St. Peters _______________________________________ ODOUR SOURCE
ODOUR DILUTION UNIT (ODU)*
Oven - Raw Odour: Inlet
43,228
Oven - Treated with Anotec Odour Control
1,236
T.J. Schulz. Manager
17
© Anotec Pty Limited 2001
CLIENT:
Anotec Pty Limited (Contact: Victoria - Director) _______________________________________
LOCATION: Taree Sewage Treatment Plant _______________________________________ ODOUR SOURCE
ODOUR DILUTION UNIT (ODU)*
Digester - Raw Odour: Inlet
94,235
Digester - Treated with Anotec Odour Control
1284
T.J. Schulz. Manager
18
© Anotec Pty Limited 2001
CLIENT:
Anotec Pty Limited (Contact: Ms. Victoria Zavras Director) _______________________________________
LOCATION: Poultry Shed – Wollondilly Council _______________________________________ ODOUR SOURCE
ODOUR DILUTION UNIT (ODU)*
Raw Odour: Inlet
22,569
Outlet - Treated with Anotec Odour Control
894
T.J. Schulz. Manager
19
© Anotec Pty Limited 2001
CLIENT:
Anotec Pty Limited (Contact: Ms. Victoria Zavras) _______________________________________
LOCATION: Laboratory Testing _______________________________________ ODOUR SOURCE
ODOUR DILUTION UNIT (ODU)*
Sewage Stack - Raw Odour: Inlet
18227
Sewage Stack - Treated with WATER only
4092
Sewage Stack - Treated with Anotec Odour Control
1736
T.J. Schulz. Manager
20
© Anotec Pty Limited 2001
CONFIDENTIAL & PRIVATE - NOT FOR DISTRIBUTION ALL INFORMATION CONTAINED HEREIN REMAINS THE PROPERTY OF ANOTEC PTY LIMITED © 2001
21
© Anotec Pty Limited 2001
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