2002 HKCEE Chemistry paper I marking scheme Marks (1)
(a)
Nitrogen is required for the formation of amino acids / proteins / chlorophyll /
1
chloroplast.
(b)
Nitrogen, hydrogen, phosphorus and oxygen
1/0
or N, H, P and O (c)(i)
Formula mass of (NH4)2SO4 = (14+4) × 2 + 32 + 16×4 = 132
% by mass of N =
(ii)
14 × 2 132
1
× 100% = 21.2 % (Accept 21, 21.2 and 21.21 )
Calcium hydroxide / calcium oxide / calcium carbonate
1
1
( slaked lime / lime water / quick lime / limestone / marble / calcite ) Calcium hydroxide / calcium oxide / calcium carbonate reacts with H+ in soil
1
( neutralizes acid in soil ) or Ca(OH)2 / CaO / CaCO3 is not very soluble in water. It will not make the soil too alkaline. or Ammonia solution / NH3(aq)
(1)
+
Ammonia reacts with H in soil ( neutralizes acid in soil )
(1)
or Ammonia is a weak alkali. It will not increase the soil pH to a great extent.
6 marks (2)
(a) Magnesium burns with a brilliant flame / white or bright light.
1
A white solid (MgO) or a yellow solid (Mg 3N2) is formed.
(1)
2 Mg
+
O2
à
2 MgO ( white )
1
or 3 Mg
+
N2
à
Mg3N2 ( yellow )
(1)
(b) The colour of the potassium permanganate solution changes from purple to yellow
5 Fe2+
+
MnO4−
+
8 H+
à
5 Fe3+
+
Mn2+
+
1
1
4 H2O
10 FeSO4 + 2 KMnO4 + 8 H2SO4 à 5 Fe2(SO4)3 + 2 MnSO4 + K2SO4 + 8 H2O
(1)
2002 - CE-CHEM p.1
(c) The solution changes from colourless to brown / orange / yellow ( NOT GAS )
1
Cl2
+
2 Br−
à
2 Cl−
+
Br2
1
or Cl2
+
2 NaBr
à
2 NaCl +
Br2
(1)
à
H2O
or 2 H+
+
OCl−
+
2 Br−
+
Cl−
+
(1)
Br2
6 marks
(3) (a) Sodium nitrite
1
It is toxic to micro-organisms / bacteria
1
(b) Manganese(IV) oxide
1
It acts as an oxidizing agent / It reacts with ( removes ) H 2(g) produced at the cathode.
(c) Sodium dichromate
1
1
It changes from orange to green
1
6 marks Chemical Knowledge ( 6 marks ) + Effective Communication ( 3 marks )
4.
• Position of ion in the electrochemical series
1
( 1 mark for stating the factor and 1 mark for explanation in terms of comparison of two discharging processes. ) − If carbon / platinum / copper ( any appropriate material ) is used as the cathode, Cu2+ ions instead of H+ ions will be discharged because Cu2+ ion occupies a lower position on the 2+
1
+
e.c.s. ( Cu ion is more easily to be reduced / has a stronger oxidizing power than H ) OR − In the electrolysis of dilute CuCl2(aq) using carbon / platinum as anode ( any appropriate material ), OH− ions instead of Cl− ions will be discharged because OH − occupies a higher
(1)
position in the e.c.s. ( OH− ion is more easily to be oxidized / has a stronger reducing power than Cl − )
• Concentration of ion
1
( 1 mark for stating the factor and 1 mark for explanation in terms of comparison of two discharging processes. ) − In the electrolysis of very dilute / dilute CuCl 2(aq) using carbon / platinum as anode, OH − ions will be discharged / O2 is liberated at the anode.
2002 - CE-CHEM p.2
1
ions will be discharged / O2 is liberated at the anode. −
− If concentrated CuCl2(aq) is used, Cl ions will be discharged / chlorine gas will be liberated instead. • Nature of electrode
1
( 1 mark for stating the factor and 1 mark for explanation in terms of comparison of two discharging processes. ) − If carbon / platinum is used as the anode, Cl 2 / O2 ( conc. / dilute ) will be liberated at the
1
anode. − If copper is used as the anode, the anode will dissolve / oxidize. 6 marks Chemical Knowledge ( 6 marks ) + Effective Communication ( 3 marks )
5.
( Award 2 marks for characteristic related to structure / formula ; 2 marks for physical property ; 2 marks for chemical property )
2 marks for characteristic related to structure / formula − Members of a homologous series can be represented by the same general formula
1
− General formula of alkenes : CnH2n or (CH2)n
1
OR − Successive members of a homologous series differ in their structure by one CH 2 unit
(1)
− Molecular Formulae :
(1)
ethene ( C2H4 ) , propene ( C 3H6 ) etc.
OR − Members of a homologous series have the same functional group
(1)
− Functional group of alkenes : C=C
(1)
OR − Alkenes possess the C=C functionality. − Structures ( structural formula ) of alkenes
(1) : ethene ( CH2=CH2 ) ; propene ( CH 3CH=CH2 )
(1)
2 marks for physical property − Their physical properties change gradually from one member to the next.
1
− The melting point / boiling point of alkene increases with increase in relative molecular mass
1
OR − The volatility / flammability of alkenes decreases with increase in relative molecular mass. (1) 2 marks for chemical property − Members of a homologous series have similar ( BUT NOT SAME ) chemical properties. − ONE example of the reaction of alkenes which is characteristic of unsaturated
1
hydrocarbons
1 2002 - CE-CHEM p.3
( accept a description of the reaction or a chemical equation. ) e.g. CH2 CH2
+
CH2 CH2
Cl2
Cl CH2 CH2
+ +
KMnO4 / H
Cl
+
H2O
CH2 CH2
( O )
OH
(1)
OH
(1)
( Accept other reactions : e.g. addition polymerization )
6 marks Calcium hydroxide / Ca(OH)2
6(a)(i)
(ii) Mg(OH)2 (s) + 2 HCl (g)
1 à
MgCl2 (s) + 2 H2O (g/ l )
1+1
( 1 mark for a balanced equation ; 1 mark for state symbols if the formulae are correct )
(iii) molten magnesium chlorides contains mobile ions / ( movable ions ) / ( freely moving ions )
1
BUT NOT ACCEPT free ions )
(iv) duralumin
1
5 marks 6(b)(i)
Isotopes are atoms with the same atomic number but different mass number /
1
the same number of protons but different number of neutrons.
(ii) relative atomic mass
= 24 × 0.786 + 25 × 0.101 + 26 × 0.113
1
= 24.3 ( or 24.33 or 24.327 ) ( NO g unit !)
1
(iii) No, because isotopes of an element have the same chemical properties ( NOT similar )
1
4 marks 6(c) (i)
concentrated sulphuric acid / conc. H 2SO4 / H2SO4 (l)
(ii)
Diagram :
1
2 2002 - CE-CHEM p.4
open water out
water in
mixture of ethanol, ethanoic acid and conc. H2SO4
heat
( 1 mark for safe and appropriate set-up diagram , e.g. open but not close system ) ( 1 mark for direction of water flow in the condenser ) ( 0 mark for wrong set−up : e.g. closed system or distillation ) (iii) • Iodine has a simple molecular structure / Attraction between I 2 molecule is weak van der
1
Waals’ forces. • Sodium iodide has an ionic structure / Attraction between Na + and I− ions is strong ionic
1
bonds. • Strength of inter-particle attraction in ethyl ethanoate is comparable to that in iodine.
1
( Indication of an understanding of the idea of ‘like dissolve like’ in terms of the strength of attraction between particles. )
(iv)
Flammable / inflammable / C
7(a)(i) CaCO3
+
2 HNO3
+
2 H+
à
1
Ca(NO3)2
+
H2O
+
H2O
+
CO2
CO2
1
OR CaCO3
à
Ca2+
+
Evolution of CO2 stops ; Test the pH of the solution using pH paper, the pH should be less than 7.
(1)
1 (1)
(ii) Diagram :
2
2002 - CE-CHEM p.5
filter paper
filter funnel
( 1 mark for the diagram ; 1 mark for labeling the funnel and filter paper )
(iii) Ca2+
+
SO42−
à
1
CaSO4
(iv) To remove any soluble impurities ( or appropriate example : Na 2SO4 ; NaNO3 ; HNO3 )
1
(v) (1)
1
no. of mole of CaSO4
= 10.52 / ( 40 + 32 + 16× 4 ) = 0.0774
(1) = 0.077 × ( 40 + 12 + 16 × 3 )
mass of CaCO3 in the sample of calcite
1*
= 7.74 g = ( 7.74 / 7.98 ) × 100
% by mass of CaCO3
= 97.0 %
1
( Also accept answers from 96.5 to 97.0 ) The sample does not contain ions which form insoluble sulphate, e.g. Ba 2+ , Sr2+, Pb2+
(2)
2+
1
OR
There is no loss of Ca ions during the experiment
(1)
OR
CaCO3 is the only calcium−containing compound present in the sample.
(1)
10 marks 7(b)(i)
Cl2
−
à
+
2 OH
+
2 NaOH à
−
OCl
−
+
Cl
+
1
H2O
OR Cl2
NaOCl
+
NaCl
+
H2O
(1)
(ii) both oxidizing agent and reducing agent.
1
O.N. of Cl decreases from 0 to −1 ( Cl2 acts as an oxidizing agent )
1
O.N. of Cl increases from 0 to +1 ( Cl 2 acts as a reducing agent )
1
(iii) Sterilizing agent / making solvents ( CHCl=CCl2 ) / production of insecticides /
1
production of vinyl chloride ( CH2=CHCl ) / used as chemical weapons / making HCl(aq)
2002 - CE-CHEM p.6
7(c)(i)
3 Cl2
+
8 NH3
à
6 NH4Cl
+
N2
1+1
( 1 mark for the correct formulae ; 1 mark for balancing the equation )
(ii) ammonium chloride / NH4Cl
1 8 marks
8(a)(i) no. of moles of SO2 released = no. of mole of S = ( 1000 × 0.015 ) / 32 = 15 / 32
1
( or 0.46875 )
= (15 / 32 ) × 24
volume of SO2 released
= 11.25 dm
1*
3
1 3
( Accept 11 to 11.3 dm )
1 (ii)
acid rain / high incidence of respiratory illnesses / corrosion of buildings / lower crop yield ( NOT ACCEPT : affect … cause cancer )
(iii)
installation of scrubbers / installation of desulphurization system /
1
use coal of lower sulphur content.
(iv)
(1) high incidence of respiration illnesses / causing cancer / darkening of building walls /
1
reduce visibility / smog.
(2) installation of electrostatic precipitator.
1
7 marks 8(b)(i) O
C
O
1
(ii) Carbon dioxide is denser than air It can exclude air (oxygen ) from the fuel / can blanket the fire from air.
1 1
2002 - CE-CHEM p.7
(iii) Silicon dioxide has a covalent network structure / giant covalent structure .
1
Attraction between CO2 molecules is van der Waals’ forces.
1
The attraction between CO2 molecules is weak while the attraction between atoms in SiO2 is
1
strong covalent bond. ( 1 mark for the structure of SiO 2 ; 1 mark for the attraction between CO 2 molecules ; 1 mark for comparing the strength of inter−particle attractions. )
(iv) (1) or
(2)
SiO2
+
2C
à
Si
+
2 CO
1
SiO2
+
C
à
Si
+
CO2
(1)
1
making computer chips / electronic parts / alloys / semi−conductors / silicone ( accept other uses of silicon : Integrated Circuit )
8 marks (v)
Any ONE of the following : 1+1 O
O H
C
O
CH2
H
CH3
C
CH2
CH3 O
CH3
CH CH3
methylethyl methanoate ( iso-propyl methanoate )
propyl methanoate
CH2
C
O
CH3
O
methyl propanoate
( 1 mark for structure ; 1 mark for name ) 9 marks 8 (c)(i) A reaction in which monomer molecules join together to form polymer molecules, with the
1
elimination of small molecules.
(ii) Cl
HO
CH3 O
O
O
C
C
O
O
C
C
O
O
C
C
Cl
OH
O
HOCH2CH2OH
1+1
CH3
2002 - CE-CHEM p.8
3 marks +
9 (a) (i) (1)
+
NH4
(2)
H2O
à
+
+
NH4
OH
−
1
Oils react with alkalis ( undergoes hydrolysis ) to give soaps ( soapy detergent ) /
1
water soluble substances.
(ii) The glass cleaner should be used in a well−ventilated environment because ammonia has a pungent smell / is toxic.
1 1
OR Wear gloves because alkaline solutions can attack skin / cause skin allergy / it is corrosive.
(1) + (1)
OR Wear safety spectacles / safety glasses / goggles because ammonia solution attack eyes / it is
(1) + (1)
corrosive. 9(b)(i) (1)
distilled water / deionized water
1
(2)
distilled water / deionized water
1
(ii) pipette (iii) NH3
1 +
à
HCl
NH4+
No. of moles of HCl(aq) used
+
Cl− = 0.23 × 28.7 × 10−3 = 6.60 × 10
Concentration of NH3 in glass cleaner
−3
1
( 0.00660 )
= 6.60 × 10−3 / ( 25×10−3 ) × ( 250 / 25 )
1*
= 2.64 mol dm−3
1
( Also accept 2.6, 2.64, 2.640 and 2.6404 mol dm
−3
)
6 marks (9)(c) (1) violet / purple / blue
1
(i) 2 H+
2 e−
à
H2
1
∴ OH concentration increases around carbon rod A /
1
+
−
concentration of OH −(aq) is higher than that of H +(aq).
(2) oxygen / O2
1
OH− is discharged at carbon rod B ( anode ) / +ve pole OR
(ii)
4 OH
−
(1)
à
O2
pencils / zinc−carbon cells.
+
2 H2O
+
4e
−
1 (1)
1 2002 - CE-CHEM p.9
(iii)
Any TWO of the following : • save chemicals / reduce the cost of chemicals ( or laboratory equipment ) used
2
• reduce chance of chemical hazards • reduce chemical wastes produced / environmental problems • shorten the time required for conducting an experiment • require less working space for carrying out an experiment • easy to set−up / convenient to set up
8 marks
2002 - CE-CHEM p.10